Procedure / Data / Conclusions:
Unknown #1: I found solution 1 to be KI. While doing the precipitate reactions, I found that it precipitates only with BiCl3 to form BiI3 which is an inorganic compound. The precipitate reaction is shown below: 3KI(aq) + BiCl3(aq) ⇒ 3KCl(aq) + BiI3(s)
Since potassium is very soluble and bismuth reacts with iodine, I concluded that solution 1 is KI.
Unknown #2: I found solutions #2 to be H2SO4. While doing precipitate reactions for solution #2, I found that it fizzed with two other solutions; #6 and #8. This led me to believe that since there were two carbonates in our list of solutions, solutions 6 and 8 were the carbonate solutions. This was also one of the last three solutions that I found the name of. H2SO4 is a strong base, and a PH test revealed that it had a very low PH of 1. Also already knowing that solution 6 was NaHCO3 and solution 8 was Na2CO3, I was also able to confirm solution 2 was NaOH by the following reactions:
H2SO4(aq) + 2 NaHCO3(aq) ⇒ Na2SO4(aq) + 2 CO2(g) + 2 H2O(l)
H2SO4(aq) + Na2CO3(aq) ⇒ Na2SO4(aq) + CO2(g) + H2O(l)
These reactions show that the fizzing that occurred while performing precipitate reactions was the release of CO2 gas. All findings lead to the fact that unknown solution #2 is H2SO4.
Unknown #3: Solution 3 is Na2SO4. While doing the precipitate reactions, I found that solution 3 only precipitated with solution 9 (BaCl2). The precipitate can be seen in the double replacement reaction below: Na2SO4(aq) + BaCl2(aq) ⇒ 2NaCl(aq) + BaSO4(s)
The solid was formed with barium and sulfate.