To synthesize 4-methylcyclohexene from 4-methylcyclohexanol the starting material can be dehydrated resulting in the desired compound. For dehydration to be possible the OH group on the 4-methylcyclohexene must first be converted into H2O by means of an acid-base reaction using a strong acid catalyst such as phosphoric acid and sulfuric acid. The H2O will then become the favored leaving group and leave on its own resulting in the formation of a carbocation in excess water. The water will remove the acidic hydrogen on the carbocation producing the desired alkene as well as regenerating the acid catalyst (fig. 2). A time effective way to collect the 4-methylcyclohexene is to heat the reaction to reflux as it is taking place. This allows the product to be separated from the starting materials by means of the boiling point discrepancy between the isolated alkene (101-102C) and the starting alcohol (171-173C). After the distillate is collected any impurities of water and phosphoric acid can be extracted by adding sodium chloride, drying the resulting organic layer with an anhydrous solid, and filtration. IR of both the starting alcohol and the resulting alkene can be compared as a means of identification and characterization as well as a Br2…
5. In step 4, the four carbon compound releases a hydrogen atom to form another four-carbon compound.…
In the last step of the reaction, hydrogen peroxide with a hydroxyl group is then added to replace the BH¬2¬ with OH. This substitution doesn’t change the stereochemistry, as the OH ends…
Abstract: Using hypochlorous acid to convert secondary alcohol called cyclododecanol to the corresponding ketone which is cyclododecanone by oxidation.…
The goals of this experiment are to determine if the products derived from amide synthesis and Williamson Ether Synthesis are identical, and if one of the synthetic routes is more advantageous than the other.…
ChemActivity 10: Exercises 1. Draw a complete mechanism including the intermediate and most likely product for the reaction of each alkene below with H-X.…
When it comes to organic chemistry and the synthesis of specific products there is an abundant amount of routes that can be taken and still get you the same result. For the following experiment, the main focus is the use of a cycloaddition reaction, also known as Diels-Alder. According to the lab manual, this reaction consists of the addition of a diene and a dienophile and that the Diels-Alder reaction builds stereospecific ring compounds with ease (Weldegirma 80). The reaction takes place between the two pi electrons from the dienophile and the 4 pi electrons from the diene; what happens is the bonds react together in order to form new single bonds because they are more stable, in terms of energetics (Diels-Alder Reaction). In order for the…
In this experiment, the secondary alcohol is selected over the primary alcohol. In many cases the primary alcohol can be oxidized all the way to a carboxylic acid. In order to achieve selectivity, sodium hypochlorite is used. It is reacted with acetic acid to form HOCl.…
A correct IUPAC name for the following compound is: A) 3,6,7-trimethyl-4-bromo-1-octene B) 4-bromo-3-methyl-6-isopropyl-1-heptene C) 4-bromo-3,6,7-trimethyl-1-octene D) 4-bromo-6-isopropyl-3-methyl-1-heptene E) 4-bromo-6-isopropyl-3,6-dimethyl-1-hexene *5. Which alkene would yield 3-methylpentane when subjected to catalytic hydrogenation? A) B) C) D) E) *61. What product is formed on reaction of hydrogen chloride with 1-pentene? 1.…
As detailed in Pavia 's Organic Laboratory techniques the reaction is expected to proceed via the following reaction:…
E1 reactions are two-step unimolecular reactions. The first step of an E1 reaction occurs when a leaving group, which consists of a weak base, leaves an organic compound, leaving an intermediate carbocation. In the second step, a carbon on the organic compound is deprotonated by a Lewis base, resulting in the formation of an alkene. The dehydration reactions of 1- and 2-Butanol with sulfuric acid occur through an E1 mechanism, so they follow the steps previously…
- On monomer provides a hydroxyl group (-OH), while the other provides a hydrogen (-H). This reaction is…
No one likes you, Your fat or ugly, I hope you kill yourself. At least one person in this class has been told this once in their life, I know I have, on many occasions actually, and I bet you it probably felt as sucky for you as it did for me. Bullying is a world wide problem that affects a varying age of people and most of the inflicted feel as if they are all alone in this situation and as if they cannot talk to anyone about it.…
An organisation regardless of its size, business environment, industry or structure relies on the ability of its leaders to motivate and influence the workforce to achieve common goals, deal with complex challenges and deliver sustainable results. The study made by Bass (1990), one of the foremost scholars on leadership, showed that the decisions made by a leader on different factors can impact on up to 65% on the success or failure of an organisation.…
Does your child always seem to get in trouble for fighting? You’ve tried talking to him, but the aggressive behavior hasn’t stopped—he still roughhouses with his siblings at home to the point of injury, brawls with kids on the bus and gets into fistfights at school. In part 1 of this two-part series on aggressive child and teen behavior, James Lehman explains why kids get into fights in the first place—and tells you the three basic types of fighting that you need to address as a parent.…