Rate of input of Φ - Rate of output of Φ + Rate of generation of Φ = Rate of accumulation of Φ
Rate of input of Φ or rate of output of Φ = mass flow rate or mole flow rate or volumetric flow rate Rate of generation of Φ = generation rate or depletion rate per unit volume (r) x volume of the system Depletion rate = - generation rate
Where r is rate of reaction
Rate of accumulation of Φ = the time rate of change of that particular quantity within the volume of the system At steady state, the accumulation term become zero Steady state The term steady state means that at a particular location in space the dependent variable does not change as a function of time. If the dependent variable is Φ, then
(∂Φ/∂t)x,y,z = 0
A classical example of the use of these techniques is in the analysis of