Chemical Bond and Crystal Field Theory

TextBooks Sr No T-1 T-2 Title Engineering Chemistry Chemistry Reference Books Sr No R-1 Other Reading Sr No OR-1 OR-2 OR-3 OR-4 OR-5 OR-6 OR-7 Journals articles as Compulsary reading (specific articles, complete reference) http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1097-4601 , http://www.springer.com/chemistry/electrochemistry/journal/10800 , http://www.sciencedirect.com/science/journal/13882481 , http://www.springerlink.com/content/100224/ , http://www.sciencedirect.com/science/journal/00108545 , http://pubs.acs.org/journal/joceah , http://www.sciencedirect.com/science/journal/00323861 , Title Author Edition 1st Year 2011 Publisher Name Cengage Learning Chemistry-Concepts and Applications Steven S. Zumdahl Author Suba Ramesh,S.Vairam , P.Kalyani Raymond Chang Edition 1st 9th Year 2011 2008 Publisher Name Wiley Tata McGraw Hill

Relevant Websites Sr No RW-1 RW-2 RW-3 RW-4 RW-5 RW-6 (Web address) (only if relevant to the course) http://www.klte.hu/~lenteg/animate.html http://dwb4.unl.edu/chemAnime/atomic_orbits.htm http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/hybrv18.swf Salient Features Chemistry animation and videos Atomic orbital animations Hybridization animation

http://jchemed.chem.wisc.edu/JCEDLib/WebWare/collection/open/JCEWWOR019/mo Molecular orbital theory animations movies.html http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/activa2.swf http://dwb4.unl.edu/chemAnime/Electro.htm Activation energy animation Electrochemistry animations

RW-7 RW-8 RW-9

http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/galvan5.swf http://dwb4.unl.edu/chemAnime/acid_base.htm http://wwwchem.uwimona.edu.jm:1104/courses/CFT.html

Galvanic Cell animation Acid base animations Crystal field theory

Audio Visual Aids Sr No AV-1 AV-2 (AV aids) (only if relevant to the course) http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-2/ Salient Features video on Introduction-Atom and molecule

http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fallVideo lecture-wave particle duality 2008/video-lectures/lecture-3/ http://ocw.mit.edu/courses/chemistry/5-111-principlesof-chemical-science-fall-2008/video-lectures/lecture-4/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fallAV on wavefunction and orbitals Mulitelectron atoms and electron 2008/video-lectures/lecture-5/ , http://ocw.mit.edu/courses/chemistry/5-111-principles- configurations of-chemical-science-fall-2008/video-lectures/lecture-6/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-7/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-8/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-10/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-12/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-9/, http://ocw.mit.edu/courses/chemistry/5-111-principlesof-chemical-science-fall-2008/video-lectures/lecture-13/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-15/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-14/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-14/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-31/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-34/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-35/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-26/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-24 http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-25/ AV on wavefunction and orbitals Mulitelectron atoms and electron configurations AV on wavefunction and orbitals Mulitelectron atoms and electron configurations Covalent and Ionic bond Covalent and ionic bond Electronegativity concept AV

AV-3

AV-4 AV-5 AV-6 AV-7 AV-8

AV-9 AV-10 AV-11 AV-12 AV-13 AV-14 AV-15 AV-16 AV-17

Hybridization and Shapes of molecules MO theory AV on MO of homonuclear diatomic molecules Av on rate law Av on transition state theory AV on catalysis AV on concept of redox reaction Balancing redox reaction Electrochemical cell

AV-18 AV-19 AV-20 AV-21 AV-22 AV-23 AV-24

http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-21/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-22/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-23/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-27/ http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-28/ http://wwwchem.uwimona.edu.jm:1104/courses/CFT.html http://ocw.mit.edu/courses/chemistry/5-111-principles-of-chemical-science-fall2008/video-lectures/lecture-30/

Classification of acid -base Autoionization of Water, pH Function, Strength of Acids and Bases,Equilibrium Involving Weak Acids and bases pH of salt solutions,buffers, Common ion effect, Acid-base titration. Introduction of coordination compounds, Nomenclature, Crystal Field Theory in octahedral complexes CFT Application of crystal field theory in magnetic properties and colour of the complex

LTP week distribution: (LTP Weeks) Weeks before MTE Weeks After MTE Spill Over 7 6 2

Detailed Plan For Lectures
Week Number Lecture Number Broad Topic(Sub Topic) Chapters/Sections of Text/reference books Other Readings, Lecture Description Relevant Websites, Audio Visual Aids, software and Virtual Labs Introduction to syllabus and general discussion on chemical principles Discovery of electron and nucleus Introduction to syllabus and general discussion on chemical principles Discovery of electron and nucleus Learning Outcomes Pedagogical Tool Demonstration/ Case Study / Images / animation / ppt etc. Planned AV17

Week 1

Lecture 1

Atoms and Molecules(Importance T-1:Ch 1 Page 14-15 of chemical principles,Discovery and 25 section 1.6 of electron and nucleus,Waveand 1.9 particle duality of light and matter) R-1:Ch 1 Page 25-27 Section 1.5 Atoms and Molecules(Importance T-1:Ch 1 Page 14-15 of chemical principles,Discovery and 25 section 1.6 of electron and nucleus,Waveand 1.9 particle duality of light and matter) R-1:Ch 1 Page 25-27 Section 1.5

Making them aware about the syllabus and its importance

Lecture 2

Making them aware about the syllabus and its importance

AV17

Week 1

Lecture 2

Atoms and Molecules(Schrodinger T-1:Ch 1 Page 14-15 equation,Quantum and 25 section 1.6 numbers,Concept of wavefunction 1.9 and Ch 1 Page 32 and orbitals) -35 Section 1.11 T-2:Ch 7 Page 279283 Section 7.4and Ch 7 Page 286-287 Section 7.6 Atoms and Molecules(Schrodinger T-1:Ch 1 Page 14-15 equation,Quantum and 25 section 1.6 numbers,Concept of wavefunction 1.9 and Ch 1 Page 32 and orbitals) -35 Section 1.11 T-2:Ch 7 Page 279283 Section 7.4and Ch 7 Page 286-287 Section 7.6 Atoms and Molecules(Schrodinger T-1:Ch 1 Page 14-15 equation,Quantum and 25 section 1.6 numbers,Concept of wavefunction 1.9 and Ch 1 Page 32 and orbitals) -35 Section 1.11 T-2:Ch 7 Page 279283 Section 7.4and Ch 7 Page 286-287 Section 7.6 Atoms and Molecules (Mulitelectron atoms and electron configurations) T-1:Ch 1 Page 27-31 35-40 Section 1.10 1.12-1.13

De Broglie Equation, Limitation and numerical Schrodinger equation only and its Importance

To explain particle and AV18 wave nature of matter and concept of wavefunctions ,orbitals

Lecture 3

De Broglie Equation, Limitation and numerical Schrodinger equation only and its Importance

To explain particle and AV18 wave nature of matter and concept of wavefunctions ,orbitals

Week 2

Lecture 4

De Broglie Equation, Limitation and numerical Schrodinger equation only and its Importance

To explain particle and AV18 wave nature of matter and concept of wavefunctions ,orbitals

spd orbitals shapes orientations including s p and d orbitals shapes orientations including nodes Electronic configuration of elements up to 30 atomic number using three building up principles Aufbaus rule Pauli Exclusion principle Hunds rule of maximum multiplicity Only electronegativity Pauling Concepts of Electronegativity

To introduce the AV19 20 21 concept of orbital to define the arrangement of electrons at different energy level within an atom

Lecture 5

Atoms and Molecules(Electronegativity concepts,periodic properties)

T-1:Ch A Page 87-91 Section A.1 A.2 T-2:Ch 7 Page 358375

To provide how does a AV24 covalent bond develop HW1 allotment ionic character

Week 2

Lecture 5

Chemical Bonding(Covalent bonds, ionic bonds (Fajan's rule))

T-1:Ch A Page 87-88 Section A.1 A.2 and Ch 2 Page 49-54 Section 2.1-2.2 T-2:Ch 9 Page 366369 Section 9.4 T-1:Ch A Page 87-88 Section A.1 A.2 and Ch 2 Page 49-54 Section 2.1-2.2 T-2:Ch 9 Page 366369 Section 9.4 T-1:Ch A Page 87-91 Section A.1 A.2 T-2:Ch 7 Page 358375 T-1:Ch 2 Page 58-64 T-2:Ch 10 Page 417429 T-1:Ch 2 Page 64-67 Section 2.6 T-2:Ch 10 Page 429 -432 Section 10.6 T-1:Ch 2 Page 67-70 Section 2.6 T-2:Ch 10 Page 432437 Section 10.7 RW-3

Lewis dot symbols Ionic bond Polar Non polar Covalent bonds and Comparision of the properties of covalent and ionic compounds, Fajans Rule Lewis dot symbols Ionic bond Polar Non polar Covalent bonds and Comparision of the properties of covalent and ionic compounds, Fajans Rule Only electronegativity Pauling Concepts of Electronegativity

To provide what type of AV22 23 bonding exist between various atoms to form a molecule

Lecture 6

Chemical Bonding(Covalent bonds, ionic bonds (Fajan's rule))

To provide what type of AV22 23 bonding exist between various atoms to form a molecule

Atoms and Molecules(Electronegativity concepts,periodic properties)

To provide how does a AV24 covalent bond develop HW1 allotment ionic character

Week 3

Lecture 7

Chemical Bonding(hybridization and shapes of molecules)

sp sp2 and sp3 hybridization and their examples Concept BMO ABMO Bond Order Magnetic character

To determine how do AV25 various atoms combine to form a molecule To define the existence AV26 stability and property magnetic character of molecule To define the existence AV27 stability and property magnetic character of molecule

Lecture 8

Chemical Bonding(Molecular orbital theory)

RW-4

Lecture 9

Chemical Bonding(molecular orbital diagram for homonuclear diatomic molecules)

MO diagram Bond order and magnetic character of Homonuclear diatomic molecule only

Week 4

Lecture 10

Solid state(Idea of spatial T-1:Ch 3 Page 95-97 periodicity of lattices,band theory) Section 3.1-3.2

Amorphous and To define the nature of crystalline substance unit the substance formed cell Space Lattice due to arrangement of atoms or molecules Band theory Conduction To explain the electrical valence band Energy property of different Gap Application in substances Conductors Band theory Conduction To explain the electrical HW 1 submission valence band Energy property of different Gap Application in substances Semiconductor Types n and p , Insulators

Lecture 11

Solid state(Electrical properties of material like conductor)

T-1:Ch B Page 142144 Section B.3-B.4 T-2:Ch 20 Page 876878 Section 20.3 T-1:Ch B Page 145 Section B.4 T-2:Ch 20 Page 876878 Section 20.3

Lecture 12

Solid state(semiconductor and insulator)

Week 5

Lecture 13

Chemical dynamics and Catalysis (Rate laws,nuclear chemistry and elementary reactions)

T-1:Ch 6 Page 261268 Section 6.1-6.3 T-2:Ch 13 Page 546 – 564 567 Section 13.1-13.3 T-1:Ch 6 Page 287289 Section 6.6 T-2:Ch 13 Page 568571 Section 13.4 RW-5

Rate Order of reactions Units of Rate constant Rate law Integrated rate Law derivation amp numerical based on zero amp first Order reactions

To have the understanding of reaction the stochiometry of reactants to form products

AV28

Lecture 14

Chemical dynamics and Catalysis (Collision theory, Arrhenius concept,application of transition state theory (Energy profile diagram))

Collision theory and To explain how do factors affecting it,No various reactions takes Derivation Arhenius place equation terms Activation energy Energy profile diagrams including intermediate and transition state reaction mechanism and To explain the sequence AV29 its evidence of steps in a reaction and verification of proposed mechanism

Lecture 15

Chemical dynamics and Catalysis (Reaction mechanism)

T-1:Ch 6 Page 281286 289 Section 6.56.6 T-2:Ch 13 Page 571581 Section 13.4 and13.5 T-1:Ch 13 Page 581 and 586-588. Section 13.6 T-2:Ch 14 Page737738

Week 6

Lecture 16

Chemical dynamics and Catalysis (Enzyme catalysis)

enzyme catalysis, Protein To explain the increase AV30 chain peptidase in rate of reaction due Test 1 Allotment to substance without being consumed itself during the course of reaction taking enzyme catalysis Homework,Test 1 RW-6 Reduction amp oxidation To provide basics of Oxidizing and reducing electrochemistry To agents Oxidation number provide basics of electron transfer Balancing redox reaction reactions by ion electron method Galvanic cell Anode cathode Salt bridge and its significance Standard reduction potential and SHE Application of series Analytical numerical To explain how a chemical reaction is used to generate electricity and to provide possible combination of reactants in order to generate electricity AV31 32

Lecture 17 Lecture 18 Electrochemistry(Concept of Redox reaction,Balancing redox reaction) T-1:Ch 8 Page 330332 Section 8.2-8.3 T-2:Ch 19 Page 820 822 Section 19.1

Week 7

Lecture 19

Electrochemistry(Electrochemical T-1:Ch 8 Page 332cell,Application of electrochemical 335 Section 8.4 Ch 8 series) Page 335-342 345 347-352 Section 8.58.6 8.8 T-2:Ch 19 Page 823 825 Section 19.2 Ch 19 Page 827 - 830 Section 19.3

RW-7

Av33

Week 7

Lecture 20

Electrochemistry(Electrochemical T-1:Ch 8 Page 332cell,Application of electrochemical 335 Section 8.4 Ch 8 series) Page 335-342 345 347-352 Section 8.58.6 8.8 T-2:Ch 19 Page 823 825 Section 19.2 Ch 19 Page 827 - 830 Section 19.3 Electrochemistry(Nernst equation, corrosion) T-1:Ch 8 Page 335342 345 347-352 Section 8.5-8.6 8.8 Ch 19 Page 853-854 868 Section 19.119.7 T-2:Ch 19 Page 827 830 Section 19.3 Page 844 - 848 Section 19.7 T-1:Ch 8 Page 335342 345 347-352 Section 8.5-8.6 8.8 Ch 19 Page 853-854 868 Section 19.119.7 T-2:Ch 19 Page 827 830 Section 19.3 Page 844 - 848 Section 19.7

RW-7

Galvanic cell Anode cathode Salt bridge and its significance Standard reduction potential and SHE Application of series Analytical numerical

To explain how a chemical reaction is used to generate electricity and to provide possible combination of reactants in order to generate electricity

Av33

Nernst equation numerical General Type Dry and wet Rusting of iron Corrosion prevention including cathodic protection

Nernst equation and To explain deterioration of metals and its prevention

Lecture 21

Electrochemistry(Nernst equation, corrosion)

Nernst equation numerical General Type Dry and wet Rusting of iron Corrosion prevention including cathodic protection

Nernst equation and To explain deterioration of metals and its prevention

MID-TERM
Week 8 Lecture 22 Acid and bases(Classification of acid-bases, auto ionization of water, pH function, strength of acids and bases) T-2:Ch 15 Page 646 – 652 Section 15.1 15.2 15.3 15.4 RW-8 Different Concepts Arrhenius Bronsted Lowry and Lewis Autoionization of Water pH and Its measurement Strength of Acids and Bases Different Concepts Arrhenius Bronsted Lowry and Lewis Autoionization of Water pH and Its measurement Strength of Acids and Bases Equilibrium Involving Weak Acids and base To explain Different Concepts of Acid and bases pH AV 34 35

Lecture 23

Acid and bases(Classification of acid-bases, auto ionization of water, pH function, strength of acids and bases)

T-2:Ch 15 Page 646 – 652 Section 15.1 15.2 15.3 15.4

RW-8

To explain Different Concepts of Acid and bases pH

AV 34 35

Lecture 24

Acid and bases(Equilibrium T-2:Ch 15 Page 647– involving weak acids. equilibrium 663 Section15.5 15.6 involving weak bases)

Acid base equilibria understanding

AV 35

Week 9

Lecture 25

Acid and bases(Equilibrium T-2:Ch 15 Page 647– involving weak acids. equilibrium 663 Section15.5 15.6 involving weak bases) Acid and bases(pH of salt solutions,buffers) T-2:Ch 15 Page 674 – 679 Section 15.10 Ch 16 Page 698 – 716 Section 16.216.4 R-1:Ch 6Page259266 T-2:Ch 15 Page 674 – 679 Section 15.10 Ch 16 Page 698 – 716 Section 16.216.4 R-1:Ch 6Page259266 T-2:Ch 16 Page 698 – 716 Section 16.216.4 R-1:Ch 7 Page286314 T-1:Ch 4 Page 165170 Section 4.5-4.6

Equilibrium Involving Weak Acids and base pH of salt solutions and buffers

Acid base equilibria understanding buffer and salt pH determination

AV 35

Lecture 26

AV36

Lecture 27

Acid and bases(pH of salt solutions,buffers)

pH of salt solutions and buffers

buffer and salt pH determination

AV36

Acid and bases(Common ion effect,acid-base titration)

Common ion effect and Understanding pH acid base titration curves metric titration ex strong base vs weak acid

AV36

Week 10

Lecture 28

Transition Metal Chemistry (Introduction and nomenclature of coordination compounds)

Coordination compounds To explain the basics of AV 37 Ligands Donor atoms metalcomplexes coordination sphere Chelates oxidation state of central metal coordination number Nomenclature examples RW-9 Concept Splitting Energy Factors effecting Splitting Nature of ligands including Spectrochemical series oxidation state of metal and size of d orbitals CFSE in Tetrahedral complexes Splitting in square planar Comparision between Splitting energy of Octahedral and Tetrahedral complexes Effect of geometry on crystal field splitting To define the existence AV 38 39 and stability of different octahedral tetrahedral and square planar complexes of metals

Lecture 29

Transition Metal Chemistry (Crystal Field Theory)

T-1:Ch 4 Page 155160 Section 4.2

Week 10

Lecture 30

Transition Metal Chemistry (Crystal Field Theory)

T-1:Ch 4 Page 155160 Section 4.2

RW-9

Concept Splitting Energy Factors effecting Splitting Nature of ligands including Spectrochemical series oxidation state of metal and size of d orbitals CFSE in Tetrahedral complexes Splitting in square planar Comparision between Splitting energy of Octahedral and Tetrahedral complexes Effect of geometry on crystal field splitting Application of crystal field theory in magnetic properties and colour of the complex Application of crystal field theory in magnetic properties and colour of the complex

To define the existence AV 38 39 and stability of different octahedral tetrahedral and square planar complexes of metals

Week 11

Lecture 31

Transition Metal Chemistry T-1:Ch 4 Page 163(Application of crystal field theory 164 Section 4.4 in magnetic properties) T-2:Ch 22 Page 950955 Section 22.5 Transition Metal Chemistry(Colour T-1:Ch 4 Page 163of the complexes) 164 Section 4.4 T-2:Ch 22 Page 950955 Section 22.5

To explain the Av 40 properties magnetic character and colour of metal complexes To explain the AV 40 properties magnetic character and colour of metal complexes

Lecture 32

Organometallics(Introductory theory of organometallics and its application)

T-1:Ch C Page 187192 Section C.1

Introduction Example of To explain the basics of Grignard reagent metalcarbon complexes ZeiglerNatta catalyst Application In polymerization with reaction hemoglobin and chlorophyll molecule use of metal in biological system

Organometallics(Metals in biology) Lecture 33 Polymerization(Classification of polymers)

R-1:Ch 18 page 941945 T-1:Ch 14 Page 601605 Section 14.114.2

Terms Monomer To explain different Oligomers Polymers types of polymers polymerization Degree of polymerization Functionality Clasification on the basis of structure types of monomer units Including Types of Copolymers occurance method of synthesis stereochemistry and thermal behavior Uses Addition Condensation and Copolymerisation with examples To provide various Test 2 allotment methods of synthesis of polymers

Week 12

Lecture 34

Polymerization(Type of polymerisation)

T-1:Ch 14 Page 606607 Section 14.3

Week 12

Lecture 35

Polymerization(Application of polymers)

T-1:Ch 14 Page 601605 634-638 648-649 653-655 Section 14.1-14.2 14.5-14.6

Application of polymers To provide uses of polymers

Lecture 36 Week 13 Lecture 37 Photochemistry(Jablonskii diagram) Photochemistry(Concept of fluorescence) T-1:Ch 22 Page 984986 Section 22.3 T-1:Ch 22 Page 983989 Section 22.

Homework,Test 2 Jablonskii diagram Singlet triplet To explain different possibilities on absorption of radiation

Lecture 38

Concept of fluorescence To provide influence of rdiation on behavior of matter phosphorescence Quantum Yield Application of photochemistry in Photovoltaic solar cell To provide influence of rdiation on behavior of matter To use the principle of photochemistry in Photovoltaic solar cell

Photochemistry(Phosphorescence) T-1:Ch 22 Page 987989 Section 22.5 Lecture 39 Photochemistry(Application of photochemistry in photo voltaic cell /solar cell) T-1:Ch 22 Page 989991 Section 22.6

SPILL OVER
Week 14 Lecture 40 Lecture 41 Revision Revision revision of syllabi upto MTE revision of syllabi after MTE

Scheme for CA:
Component Homework,Test Frequency 2 Total :Out Of 3 Each Marks Total Marks 10 10 20 20

Details of Academic Task(s)
AT No. Objective Topic of the Academic Task Nature of Academic Task (group/individuals/field work Evaluation Mode Allottment / submission Week 2/4

Homework 1

To analyze comprehensive and analytical skills of students

Wave-particle duality of light and matter, Schrödinger equation, Individual Quantum numbers, Concept of wavefunction and orbitals, Mulitelectron atoms and electron configurations, covalent bonds, ionic bonds (Fajan’s rule) and electro-negativity concepts, hybridization and shapes of molecules, Molecular orbital theory, molecular orbital diagram for homonuclear diatomic molecule.

performance based

Homework,Test 1

To analyze the conceptual and analytical skills of students

Wave-particle duality of light and matter, Schrödinger Individual equation, Quantum numbers, Concept of wavefunction and orbitals, Mulitelectron atoms and electron configurations, covalent bonds, ionic bonds (Fajan's rule) and electro-negativity concepts, hybridization and shapes of molecules, Molecular orbital theory, molecular orbital diagram for homonuclear diatomic molecule.Concept of crystalinity and type of lattices, Band theory and its application in electrical properties of material like conductor, semiconductor and insulator Rate laws,Nuclear chemistry and elementary reaction, Collision theory, Arhenius concept, Application of Transition state theory (Energy profile diagram), Reaction mechanism . Concept of Redox reaction, Balancing redox reaction Individual Electrochemical cell, Nernst equation, Application of electrochemical series, Corrosion, Classification of Acid-Bases, Autoionization of Water, pH Function, Strength of Acids and Bases, Equilibrium Involving Weak Acids. Equilibrium involving weak bases, pH of salt solutions, and buffers,Common ion effect,Acid-base titration, Introduction of coordination compounds, Nomenclature, Crystal Field Theory and its application. Classification of polymers.

Performance based

6/6

Homework,Test 2

To analyze the knowledge of students which they gained from this course.

Performance based

11 / 11

Plan for Tutorial: (Please do not use these time slots for syllabus coverage)
Tutorial No. Lecture Topic Type of pedagogical tool(s) planned (case analysis,problem solving test,role play,business game etc)

Tutorial 1

Importance of chemical principles,Discovery of electron Problem solving and nucleus,Wave-particle duality of light and matter, Schrödinger equation, Quantum numbers Concept of wavefunction and orbitals, Mulitelectron atoms and electron configurations,electro-negativity concepts,Periodic properties Problem solving

Tutorial 2

Tutorial 3

Covalent bonds, ionic bonds (Fajan’s rule) and, Problem solving hybridization and shapes of molecules, Molecular orbital theory, molecular orbital diagram for homonuclear diatomic molecule. Idea of special Periodicity of lattices, Band theory and its application in electrical properties of material like conductor, semiconductor and insulator Rate laws,Nuclear chemistry and elementary reaction, Collision theory, Arhenius concept, Application of Transition state theory (Energy profile diagram), Reaction mechanism Concept of Redox reaction,Balancing redox reaction, Electrochemical cell Problem solving

Tutorial 4

Tutorial 5

Problem solving

Tutorial 6

Problem solving

Tutorial 7

Nernst equation, Application of electrochemical series, corrosion.

Problem solving

After Mid-Term
Tutorial 8 Classification of Acid-Bases, Autoionization of Water, pH Function, Strength of Acids and Bases, Equilibrium Involving Weak Acids. Equilibrium involving weak bases, pH of salt solutions, and buffers,Common ion effect,Acid-base titration. Problem solving

Tutorial 9 Tutorial 10

Problem solving

Introduction of coordination compounds, Nomenclature Problem solving ,Crystal Field Theory in octahedral, tetrahedral and square planar complexes application of crystal field theory in magnetic properties Problem solving and colour of the complex, Introductory theory of organometallics and its application, Metals in biology Classification of polymers, type of polymerization, application of polymers Jablonskii’s diagram, concept of fluorescence and phosphorescence, application of photochemistry in Photovoltaic cell/solar cell Problem solving Problem solving

Tutorial 11

Tutorial 12 Tutorial 13