Readings from both official and unofficial monitoring stations suggested that Saturday's pollution has soared past danger levels outlined by the World Health Organization (WHO).
The air tastes of coal dust and car fumes, two of the main sources of pollution, says a BBC correspondent.
Economic growth has left air quality in many cities notoriously poor.
A heavy smog has smothered Beijing for many days, says the BBC's Damian Grammaticas, in the capital.
By Saturday afternoon it was so thick you could see just a few hundred metres in the city centre, our correspondent says, with tower blocks vanishing into the greyness.
Hazy view
Even indoors the air looked hazy, he says.
Some people are wearing masks
WHO guidelines say average concentrations of the tiniest pollution particles - called PM2.5 - should be no more than 25 microgrammes per cubic metre.
Air is unhealthy above 100 microgrammes. At 300, all children and elderly people should remain indoors.
Official Beijing city readings on Saturday suggested pollution levels over 400. An unofficial reading from a monitor at the US embassy recorded 800.
Once inhaled, the tiny particles can cause respiratory infections, as well as increased mortality from lung cancer and heart disease.
Last year Chinese authorities warned the US embassy not to publish its data. But the embassy said the measurements were for the benefit of embassy personnel and were not citywide.
The number of lung cancer cases in the Chinese capital Beijing has soared over the last decade.
According to figures published by the state-run Xinhua news agency, they have increased by more than 50%.
Beijing health officials say smoking is still the number one cause of lung cancer, but they admit air pollution is also a factor.
The World Health Organization (WHO) recently estimated that polluted air kills millions of people every year.
Pollution