Corrosion is defined as the involuntary destruction of substances such as metals and mineral building material by surrounding media, which are usually liquid (i.e. corrosive agents)." Most metals corrode. During corrosion, they change into metallic ions. In some cases, the product of corrosion itself forms a protective coating. "For example, aluminium forms a thin protective oxide layer which is impervious to air and water. In other cases (e.g. iron), however, the coating either flakes off or is pervious to both air and water. So the whole piece of metal can corrode right through."
The most common forms of metallic corrosion are caused by electrochemical reactions, wherein two metallic phases (e.g., iron oxide and iron) react in the presence of electrolytic solution. Another mechanism of metallic corrosion is caused by chemical reaction, which explains how the protective layer of the metal is formed.
Rusting is the corrosion of iron which is the most widely used structural metal. Most of it is used in making steel. The wide range of products made from steel includes all types of vehicles, machinery, pipelines, bridges, and reinforcing rods and girders for construction purposes. Therefore, rusting causes enormous economic problem and is the reason why extensive measures of corrosion protection have had to be developed.
Electrochemical corrosion reactions
This type of corrosion takes place when two metallic phases with different electrochemical potentials are connected to each other by means of an electric conductor.
Chemical corrosion reactions
Metals have a tendency to combine with oxygen to form oxides and this is one of the chemical reactions. This tendency is the stronger the less noble the metal. The layers of oxide on the metal surface which are formed even in dry air may be insoluble and stable against an aqueous medium in contact with them. Therefore, if the oxide layers are dense and adhere well to the metal, they prevent further attack