The purpose of this experiment is to determine the rate equation for the “Iodine Clock Reaction” experiment. The experiment will consider the equations 〖2I〗^-+S_2 O_8→2〖〖SO〗_4〗^(2-)+I_2 and I_2+2〖S_2 O_3〗^(2-)→2I^-+S_4 O_6 in order to determine the rate law of Rate=k[〖〖S_2 O_8〗^(2-)]〗^a 〖[I^-]〗^b by using the experimental data to calculate the values of exponents a and b as well as the rate constant k.
Experimental
Supplies Needed: 250 mL Erlenmeyer flask, 100 mL beaker, graduated cylinders for each reagent distributed, digital timer.
Reagents Needed: 0.4 mol 〖Na〗_2 S_2 O_3 / Liter, starch solution (freshly prepared), 0.2 mol 〖KNO〗_3 / Liter, 0.1 mol EDTA / Liter (in a dropping bottle), 0.2 mol (〖〖NH〗_4)〗_2 S_2 O_8 / Liter (prepared fresh), 0.2 mol KI / Liter.
Safety Precautions: Wear long pants, closed toed shoes, safety goggles, and gloves. Ingesting potassium nitrate or iodine is dangerous. …show more content…
The steps involve adding a given amount of (〖〖NH〗_4)〗_2 S_2 O_8 to the initial solution in order to induce the first reaction mentioned in the above introduction. Then in succession with the reaction (appearance of blue color), you add a given amount of 〖Na〗_2 S_2 O_3 to begin the second reaction mentioned in the above introduction. You alternate these steps seven different times while recording on a digital timer the times between adding the 〖Na〗_2 S_2 O_3 and the appearance of color (the reaction