While experimenting with spectroscopy in his laboratory Crookes discovered a lime green band in the spectrum of selenium, a band that belongs to no known element at that time. After a few years he succeeded in isolating the element, which he named thallium. But at the same time a French scientist named C. A. Lamy discovered the element at the same time and people argue who to give the credit to.
He also invented the Crookes tubes which is an early experimental electrical discharge tube, with partial vacuum. He discovered cathode rays, and streams of electrons using the Crookes tubes. The Crookes tube was developed by the Geissler tube, and it consists of partially evacuated glass container of various shapes, with two metal electrodes, the cathode and the anode. Crookes tubes are now used only for demonstrating cathode rays. Crookes tubes also helped make the later development of X-rays