It is less commonly encountered as a natural form of spontaneous radioactive decay (not requiring a neutron), occuring especially in very high-mass-number isotopes. The unpredictable composition of the products (which vary in a broad probabilistic and somewhat chaotic manner) distinguishes fission from purely quantum-tunnelling processes such as proton emission, alpha decay and cluster decay, which give the same products every time.
Fission of heavy elements is an exothermic reaction which can release large amounts of energy both as electromagnetic radiation and as kinetic energy of the fragments (heating the bulk material where fission takes place). In order for fission to produce energy, the total binding energy of the resulting elements must be greater than that of the starting element. Fission is a form of nuclear transmutation because the resulting fragments are not the same element as the original