Preview

Solubility Product Determination Lab

Powerful Essays
Open Document
Open Document
922 Words
Grammar
Grammar
Plagiarism
Plagiarism
Writing
Writing
Score
Score
Solubility Product Determination Lab
Solubility Product Determination

Purpose • To determine the solubility product constant, Ksp, of an ionic compound.

Introduction The solubility product constant, Ksp, is a particular type of equilibrium constant. The equilibrium is formed when an ionic solid dissolves in water to form a saturated solution. The equilibrium exists between the aqueous ions and the undissolved solid. A saturated solution contains the maximum concentration of ions of the substance that can dissolve at the solution’s temperature. The equilibrium equation showing the ionic solid lead chloride dissolving in water is:

PbCl2(s) ( Pb2+(aq) + 2Cl-(aq)

The solubility product expression is:

Ksp = [Pb2+][Cl-]2

A knowledge of the Ksp
…show more content…
Place 5 drops of 0.10 M sodium hydroxide in each of the wells #1 through #12. Stir thoroughly with a toothpick. 7. Allow three or four minutes for the precipitates to form. Observe the pattern of precipitation. Record.

Part II Ksp by dilution of hydroxide ions. 1. Repeat the procedure in Part I, but use a serial dilution of NaOH followed by 5 drops of calcium nitrate in each well.

Data Analysis

Part I 1. Determine the concentration of the calcium ion in each well after the serial dilution but before the sodium hydroxide has been added. 2. Determine the concentration of the calcium ion in each well after the sodium hydroxide has been added. 3. Determine the concentration of the hydroxide ion in each well. 4. Assume that the first well with no precipitate contains a saturated solution. Calculate the solubility product of calcium hydroxide using the concentrations in this well.

Part II 1. Determine the concentration of the hydroxide ion in each well after the serial dilution but before the calcium nitrate has been added. 2. Determine the concentration of the hydroxide ion in each well after the calcium nitrate has been added. 3. Determine the concentration of the calcium ion in each
…show more content…
Again calculate the solubility product of calcium hydroxide using the concentrations in the first well that has no precipitate. 4. Average the two values of Ksp determined in Parts I and II. 5. Look up the accepted value for the Ksp of calcium hydroxide and calculate percent error.

Data and Results

Part I

| Well # | [Ca2+] | [Ca2+] | [OH-] |Precipitate? |
| |before NaOH |after NaOH | | |

1
| | | | | |

2
| | | | |

You May Also Find These Documents Helpful

  • Good Essays

    6.03 Calorimetry Lab

    • 446 Words
    • 2 Pages

    The calcium dissolved really quickly and there were bubbles and foams formed. We then heated the beaker with a hot plate for 2 to 3 minutes, equally distributed the supernatant solution into two test tubes, but avoid pouring the solid. After centrifuging the samples, we added extra HCl solution into the test tubes, there wasn’t any bubbling occurs, so we could continue and put the mixtures into the centrifuge again. And then put the NaCO3 solution into the beaker and wait to allow the CaCO3 precipitate to form. We then tested whether the supernatant solution is still acidic with a piece of red litmus paper, filter the liquid and we had some CaCO3. Dried the filter paper and CaCO3 in the oven, then we broke the CaCO3 into small particles with a glass rod, and dried it one more time. Let it cool and repeat heating, cooling and weighing it until the masses differ between two results are less than…

    • 446 Words
    • 2 Pages
    Good Essays
  • Satisfactory Essays

    Chapter 15 16 Worksheet

    • 379 Words
    • 2 Pages

    (b) Write the correctly balanced net ionic equation for the reaction that occurs when NaOCl is dissolved in water and calculate the numerical value of the equilibrium constant for the reaction. (2 points)…

    • 379 Words
    • 2 Pages
    Satisfactory Essays
  • Satisfactory Essays

    1. What is the concentration of each ion in a 10.5 M sodium silicate solution?…

    • 907 Words
    • 5 Pages
    Satisfactory Essays
  • Satisfactory Essays

    Halide Ions Lab

    • 618 Words
    • 3 Pages

    1. Place the 4 solutions in separate test tubes with about 2.5 mL in each. (NaF, NaCl, KBr, KI) Use a dropper or you can use a pipette. Add 1 Ml ( 20 drops) of 0.5 M Ca ( NO3h) to each test tubes. Observe…

    • 618 Words
    • 3 Pages
    Satisfactory Essays
  • Good Essays

    Lifesaver Lab

    • 836 Words
    • 4 Pages

    In the first cup we add 20 ml of salt. In the second cup we add 20 ml of baking soda. In the third cup we add 20 ml of room temperature clear water. We obtained 100ml of solution in #1 and #2 and 100ml of only solvent water in cup #3.…

    • 836 Words
    • 4 Pages
    Good Essays
  • Satisfactory Essays

    Ionic Reactions

    • 354 Words
    • 2 Pages

    a. Place 2 drops of cobalt (II) nitrate solution into seven of the A row wells.…

    • 354 Words
    • 2 Pages
    Satisfactory Essays
  • Good Essays

    Weigh out your 1.0g of CaCl2-2H20 and put it into the 100mL beaker, Add your 25mL of distilled water and stir to form the calcium chloride solution. Next, use stoichiometry to determine how much Na2CO3 and put it into a small paper cup. Then add the 25mL of distilled water to make the sodium carbonate solution. Mix the two solutions in the beaker and a precipitate of calcium carbonate will form instantly. Next set up your filtration assembly. After the filtration assembly is ready, swirl the contents of the beaker to dislodge any precipitate from the sides. Then, pour the content of the beaker into the filter paper-lined funnel carefully. After that you will need to measure out 2 to 5mL of distilled water into a graduated cylinder. Pour it down the sides of the beaker, swirl, and pour into the filter paper-lined funnel. Once all the liquid has drained from the funnel, lay the filter paper containing the precipitate on folded layers of paper towels and set it somewhere to air-dry. Once the filter paper and the precipitated calcium carbonate are completely dry, weigh them, subtract the original weight of the empty filter paper, and record the net weight of the calcium carbonate. That is your actual yield of calcium carbonate. After that you can calculate the percent yield, using your theoretical yield and actual yield. Be sure to clean up properly, rinse any remaining chemicals down the sink and throw paper cups and towels in the garbage. Clean and dry all equipment you used.…

    • 555 Words
    • 3 Pages
    Good Essays
  • Good Essays

    In this experiment, you will react a known amount of sodium carbonate solution with a known amount of…

    • 1310 Words
    • 6 Pages
    Good Essays
  • Satisfactory Essays

    How many moles of Fe(OH)2 [Ksp = 1.8 10-15] will dissolve in 1.0 liter of water buffered at pH = 11.52?…

    • 4214 Words
    • 17 Pages
    Satisfactory Essays
  • Good Essays

    Lab Report Essay Example

    • 857 Words
    • 4 Pages

    5 ml of NaOH is added. 5 | 10 | 15 | 20 | 25…

    • 857 Words
    • 4 Pages
    Good Essays
  • Good Essays

    1. What is the pH of a solution that has a hydronium ion concentration of 8.26 10–5 M?…

    • 1144 Words
    • 5 Pages
    Good Essays
  • Satisfactory Essays

    Equilibrium constant

    • 738 Words
    • 4 Pages

    Part B: Prepare a NaOH solution by dissolving 14g of NaOH pellets in 500mL of deionized water.…

    • 738 Words
    • 4 Pages
    Satisfactory Essays
  • Powerful Essays

    Vitamin C Lab

    • 1739 Words
    • 7 Pages

    To analyze the Vitamin C from a rival company and compare with that of my company and find out the best value for the money spent by the consumer.…

    • 1739 Words
    • 7 Pages
    Powerful Essays
  • Better Essays

    Experiment 5

    • 2128 Words
    • 9 Pages

    By measuring the concentration of the hydroxide ion from a solution saturated with Ca(OH)2 titration analysis against HCl, the experiment’s objective is to determine the solubility constant of calcium hydroxide. But, there are few limitations in solubility constant concept, like the Diverse Ion effect and the Common ion effect. Sources of error probably were the assumptions made throughout the experiment and can be explained further by the limitations of the solubility constant.…

    • 2128 Words
    • 9 Pages
    Better Essays
  • Good Essays

    Profects

    • 6922 Words
    • 28 Pages

    Aim:- You are provided with two solutions as follows. Container A: -----------------M/N Stock Solution of Hydrated Mohr’s Salt. Container B: - KMnO4 Solution. Using the Stock Solution from container A Prepare 100 ml of ______________ M/N Solution of Mohr’s Salt in the given standard measuring flask C. Using the solution in flask C determine the 1. Molarity/Normality of the solution in container B. 2. Strength of less /more concentrated solution in container B/C in terms of gms/______ ml. 3. % Purity of Solution in Container B (-----Gms of which have been dissolved per-------ml) Apparatus & Chemical Required:-Burette, Pipette, Burette Stand, White tile, conical flask, KMnO4 Solution & stock solution of Mohr’s Salt. Theory:-(Write ionic equation given on page-7) Procedure: 1. Rinse the pipette with the _____ N/M Mohr’s Salt solution and pipette out 10 ml of it in a washed titration flask. 2. Rinse and fill the burette with the given KMn04 solution. 3. Add one test-tube (15 ml) full of dilute sulphuric acid (2 N) to the solution in the titration flask. 4. Note the initial reading of the burette. 5. Add KMn04 solution from the burette till a permanent light pink colour is imparted to the solution in the titration flask on addition of the last single drop of KMn04 solution. 6. Note the final reading of the burette. 7. Repeat the above steps to get three concordant readings.…

    • 6922 Words
    • 28 Pages
    Good Essays