linking small molecules together‚ a type of addition reaction. 2. combining two molecules (of the same or different type) with the elimination of a stable small molecule such as water. This latter type of polymerization combines addition and elimination reactions and is called a condensation reaction . Types of polymerization reactions Addition Polymerization Chain Polymerization/ Free radical Polymerization Condensation Polymerization Addition Polymerization Also known as Chain-growth
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Organometallic preparation and addition to carbonyls‚ Wittig reagent preparation and Wittig rxn‚ Wolff‚ H-based nucleophile carbonyl reduction‚ imine formation‚ reductive amination (rxn only)‚ ketal/acetal formation‚ dithiane chemistry (rxn only)‚ alpha-bromination of ketones‚ -COOH properties (the trends on HW4)‚ Fischer‚ acidic/basic hydrolysis of esters/amides/nitriles‚ CH2N2‚ acid chloride formation (rxn only)‚ acid chloride rxns with esters and amides. 2 Rxn of carboxyllic acid derivatives
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Introduction Discovered by Georg Wittig in 1954‚ the Wittig reaction is a robust organic synthesis method for preparing stereospecific alkenes. In general‚ Wittig reactions involve an aldehyde or ketone and a Wittig reagent (triphenylphosphonium ylide) and result in the formation of an alkene product and triphenylphosphine oxide (side product). Stereospecific alkene products can be synthesized by adjusting the reaction reagents and conditions. In the 60 years since the Wittig reaction was discovered
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hydrocarbons (Greek for "fat") consist of alkanes (paraffins)‚ alkenes (double bonds) and alkynes (triple bonds). Aromatic hydrocarbons contain the benzene ring. 153 C C C alkane alkene C C C alkyne benzene Hydrocarbons can be further divided into saturated hydrocarbons that have only single carbon-carbon bonds (alkanes)‚ and unsaturated hydrocarbons that have multiple carbon-carbon bonds (alkenes‚ alkynes‚ aromatics). Most of the aliphatic compounds are named
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Alkanes This is the correct chemical term for compounds known as paraffins. They are considered the simplest organic compounds and are a family of chain hydrocarbons having the general formula C2H2n+2. All of the bonds are single bonds (-C-H-‚ and -C-C-). The chains can be straight or branched. The smaller members (less than 4 carbons) are gases‚ while larger ones (five to seventeen carbons) are liquids. Beyond seventeen carbons the alkanes are waxy solids. Structure: The simplest saturated acyclic
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R or S ? www.primaryrx.com/pdf/C-PHEN%20DM%20DROPS.pdf 1 Chapter 15: Benzene and Aromaticity Introduction: • All organic compounds can be derived into two broad classes 1. Aliphatic compounds Nonaromatic hydrocarbons such as alkanes‚ alkenes or alkynes 2. Aromatic compounds A series of cyclic unsaturated compounds with unusually high stability • The properties and reactions of aromatic compounds are exemplified / demonstrated by the properties and reactions of benzene (the “parent”
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ORGANIC CHEMISTRY Carbon atoms: * Carbon-carbon bonds are not easily broken * Each carbon atom forms 4 covalent bonds * The C-H bond is almost non-polar Classifying organic compounds: * Number of carbon atoms in longest chain: meth‚ eth‚ prop‚ but‚ pent‚ hex‚ hept‚ oct‚ non‚ dec * If it is a branch: -yl; di‚ tri or tetra means there is more than one branch‚ ethyl means there are 2 carbons coming off the branch * If it is a ring of carbons put cyclo at the front of the
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dehydrobromination of 1-bromobutane and 2-bromobutane to form the alkene products 1-butene‚ trans-2-butene‚ and cis-2-butene. The dehydration reactions react under and acid-catalysis which follows an E1 mechanism. It was found that dehydration of 1-butanol yielded 3.84% cis-2-butene‚ 81.83% trans-2-butene‚ and 14.33% 1-butene‚ while 2-butanol is unknown due to mechanical issues with the GC machine. For the dehydrobromination‚ with the addition of a strong base that can abstract a proton‚ which then pushes
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Diliman‚ Quezon City 1101 Philippines Date Performed: April 25‚ 2013; Date Submitted: April 30‚ 2013 Alkyl halides could be synthesized through several processes and using different compounds as reactants. One of the simplest method used is the addition of a hydrogen halide to an alcohol. In this research‚ tert-butyl alcohol was reacted with cold concentrated HCl to produce tert-butyl chloride. The crude product was distilled to yield a pure tert-butyl chloride. The tert-butyl alcohol‚ together
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PREPARING CYCLOHEXENE FROM CYCLOHEXANOL INTRODUCTION Alkenes can be prepared in the lab by dehydrating the corresponding alcohol. Concentrated sulphuric and phosphoric acids both act as dehydrating agents. Phosphoric acid is preferred because it gives a higher yield of the alkene. Concentrated H2SO4 reacts with alkenes. SAFETY Eye protection must be worn. Concentrated phosphoric acid is corrosive. Mop up spillages immediately with plenty of water. Cyclohexene and cyclohexanol are
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