Semester: fall 2011 Practice to Chapter 12 (Alkenes & Alkynes *1. Consider the following: CH3CH2CH=CHCH2CH3 CH3CH2CH2CH2CH=CH2 I II CH3CH=CHCH2CH2CH3 CH2=CHCH2CH2CH2CH3 III IV Which two structures represent the same compound? A) I and II B) II and III C) I and III D) II and IV E) None of these *2. Give the IUPAC name for A) 3-Methyl-4-hexyne B) 4-Methyl-2-hexyne C) 2-Ethyl-3-pentyne D) 4-Ethyl-2-pentyne E)
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uncontrollable environmental factors. Introduction An alkyl halide or haloalkane is composed of hydrocarbons with a halogen attached to a sp3-hybridized carbon. It resembles an alkane with a halogen attached to it. Halogens are fluorine‚ chlorine‚ bromine‚ and iodine. Any of these halogens seen to be attached to an alkane‚ could then be identified as alkyl halides. They are generally polar because of the electronegativity difference of carbon (2.5) with the halogen (2.5-4.0). However‚ most alkyl
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(9)‚ toluene (8)‚ methylcyclohexane (13)‚ cyclohexane (12)‚ and tert-butylbenzene (11). This hypothesis was a result of the fact that benzylic hydrogen atoms react faster than aliphatic hydrogen atoms and aliphatic hydrogen atoms react faster than aromatic hydrogen atom atoms. The hypothesis was in fact correct and the reaction times of each hydrocarbon with different hydrogen atoms in the bromination experiment support
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found that the product yielded 1‚2-epoxydihydronaphthalene as well as naphthalene. Introduction In 1990‚ professor E.N. Jacobsen reported that chiral manganese complexes had the ability to catalyze the asymmetric epoxidation of unfunctionalized alkenes‚ providing enantiomeric excesses that regularly reaching 90% and sometimes exceeding 98% . The chiral manganese complex Jacobsen utilized was [(R‚R)-N‚N’-Bis(3‚5-di-tert-butylsalicylidene)-1‚2- cyclohexanediaminato-(2-)]-manganese (III) chloride
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ONE-SCHOOL.NET Short Notes: Form 5 Chemistry Rate or Reaction Calculation Rate of Reaction (Average Rate) Rates of reaction = Quantity change of reactants/products Total time for the reaction If the quantity change is immeasurable Rates of reaction = 1 Total time for the reaction Find the Rate From a Graph Average Rate Rates At an Instant The rate of reaction is equal to the slope of the graph The rate of reaction at an instant‚ t‚ is equal to the of quantity against
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| |Structure and Preparation of Alkenes. | |Elimination Reactions | Summary Alkenes contain the C=C functional group which can be prepared by 1‚2-elimination reactions such as: • dehydration of alcohols (- H2O) or • dehydrohalogenation of alkyl halides (- HX). Zaitsev’s rule indicates that the preferred product is the more highly substituted‚ and therefore more stable alkene. But the rule is not always obeyed
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Name Lab Section GTA Station 1. Grignard Reaction Post-lab report Fill out the appropriate sections below. Show all work. Your calculated answers need to match the answers in the table. Also‚ attach the benzophenone and product spectra. Indicate appropriate stretches including differences in both spectra. Results | | Amounts and units | |Initial
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English Proficiency This test is designed to assess the test takers’ general proficiency in the use of English language as a means of self-expression in real life situations and specifically to test the test takers’ knowledge of basic grammar‚ their vocabulary‚ their ability to read fast and comprehend‚ and also their ability to apply the elements of effective writing. 1. Grammar 1. Agreement‚ Time and Tense‚ Parallel construction‚ Relative pronouns 2. Determiners‚ Prepositions‚ Modals
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a C-H bond‚ a C-D bond will vibrate where in the infrared spectrum? A. Higher molecular weight B. Lower molecular weight C. Lower wavenumbers D. Higher wavenumbers 5. Why does an alkyne carbon-carbon bond vibrate at a higher wavenumber
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GajendraUjjenia Rajiv Gandhi Institute of Petroleum Technology Catalysis in Hydrotreating and Hydrocracking
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