"Aromatic nitration" Essays and Research Papers

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    Nomenclature of Aromatic Compounds Aromatic Compounds- possess a ring shaped structure Benzene (C6H6)- aka. naphtha - unsaturated cyclic compound - simplest aromatic HC - all C to C bonds are identical; each C has a H atom - substitution reactions occur instead of addition reaction - delocalized pi bonding in benzene imparts stability (aromaticity); responsible for resistance to addition reactions (involve breaking delocalized bonding) Benzene Derivatives- produced when one or more H atoms on benzene

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    Chapter 28: Nitration of Methyl Benzoate I. General Information: A.) Microscale Nitration of Methyl Benzoate B.) C.) May 17‚ 2008 D.) Reaction(s)‚ including molar masses and all relevant physical data E.) Mechanism for the nitration of chlorobenzene: II. Purpose: In this experiment we are to take a cold solution of an aromatic ester that is first dissolved in sulfuric acid and is then reacted with nitric acid. This is a highly exothermic reaction and is kept under control by means

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    Carcinogenic Hydrocarbons

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    Are Aromatic Hydrocarbons Carcinogenic Aromatic hydrocarbons or arenes are hydrocarbons characterized by alternating double and single bonds between carbons. Benzene is the most common aromatic hydrocarbon‚ but there are some non-benzene based compounds called heteroarenes‚ where a carbon is replaced by an oxygen‚ nitrogen‚ or sulfur‚ that are also aromatic compounds. Aromatic hydrocarbons exist in our daily lives regardless if we recognize them or not. Aromatic hydrocarbons are ingested or

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    (9)‚ toluene (8)‚ methylcyclohexane (13)‚ cyclohexane (12)‚ and tert-butylbenzene (11). This hypothesis was a result of the fact that benzylic hydrogen atoms react faster than aliphatic hydrogen atoms and aliphatic hydrogen atoms react faster than aromatic hydrogen atom atoms. The hypothesis was in fact correct and the reaction times of each hydrocarbon with different hydrogen atoms in the bromination experiment support

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    Multistep Synthesis of Tetraphenylcyclopentadienone In this laboratory experiment a synthesis was performed through several separate steps. The purpose of the experiment was to synthesize tetraphenylcyclopentadienone from benzaldehyde and to run reactions on carbonyl containing compounds. There was a total of three steps that led up to the synthesis of the final product‚ tetraphenylcyclopentadienone. The first step of the experiment was the condensation of benzaldehyde to yield

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    (E)-α-phenylcinnamic acid 3054 Aromatic =C-H (stretch) 5053 Aromatic =C-H (stretch) 2616-3054 Carboxylic acid O-H (stretch) 2498-3053 Carboxylic acid O-H (stretch) 1676 Carbonyl C=O (stretch) 1670 Carbonyl C=O (stretch) 1599&1493 Benzene C=C (aromatic stretch) 1597&1493 Benzene C=C (aromatic stretch) 1293 Carboxylic acid C-O (stretch) 1267 Carboxylic acid C-O (stretch) 788 Alkene =C-H bending (stretch) 786-845 Alkene =C-H bending (stretch) Pure (E)-α-phenylcinnamic acid 3054 Aromatic =C-H (stretch) 5053

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    NITRATION
OF
METHYL
BENZOATE
 
 Purpose:
The main objective of this experiment was to synthesize methyl nitrobenzoate from methyl benzoate‚ using the mixture of nitric and sulfuric acid by performing the process of electrophillic aromatic substitution. During this reaction‚ the combination of HNO3 and H2SO4 made a nitrating solution. The crystallization was done to accomplish pure product. The melting point and Thin Layer Chromatography (TLC) were performed to test the purity of the product. Using

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    Friedel-Crafts Reactions

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    Compounds containing aromatic groups are widespread in nature‚ and for this reason chemists who aim to synthesize naturally occurring compounds in the laboratory often need to introduce substituents to aromatic rings. In the organic synthesis laboratory‚ electrophilic aromatic substitutions which result in the formation of new carbon-carbon bonds are called ‘Friedel-Crafts’ alkylations and acylations‚ named for Charles Friedel of France and James Crafts of the United States‚ who together developed

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    of methyl m-nitrobenzoate by nitration using methyl benzoate‚ nitric acid‚ and sulfuric acid Aileen Quintana TA: Sijie Tues/Thurs 11:50 42067 Introduction: The purpose of this lab was to explore the concepts of electrophilic aromatic substitution‚ specifically nitration by synthesizing methyl m-nitrobenzoate using methyl benzoate‚ nitric acid and sulfuric acid. This nitration is a type of electrophilic aromatic substitution. A strongly charged

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    Experiment B10- Photocromism and Piezochromism Reece Harms 4320288 Introduction This experiment investigates an oxidative coupling reaction in an to synthesise triphenylimidazole dimer from 2‚4‚5-triphenyl-1H-imidazole. The resulting compound was investigated for both photochromic and piezochromic properties by way of formation of a stable radical‚ utilizing visual observations and UV-Vis as a means of distinction. Both the oxidative coupling reaction and the dimers interaction with light

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