Preparation of 4-bromoaniline Introduction Aromatic compounds tend to undergo electrophilic aromatic substitutions rather than addition reactions. Substitution of a new group for a hydrogen atom takes place via a resonance-stabilized carbocation. As the benzene ring is quite electron-rich‚ it almost always behaves as a nucleophile in a reaction which means the substitution on benzene occurs by the addition of an electrophile. Substituted benzenes tend to react at predictable positions. Alkyl groups
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their labels (Hudson‚ 1973). One of the most enduring characteristics of Angostura Aromatic Bitters was its secret ingredients which continued to remain a secret for its 200 years of existence‚ the product has survived even when other bitters existing around the time of its emergence faded away‚ recreating its identity from medicine to being a beverage and food flavour enhancer (Conaway‚ 2009). Angostura Aromatic Bitters has monopolized the bitters market for many years because of its branding evolution
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Objective: To perform an electrophilic aromatic substitution reaction‚ predict the effect on substituent orientation‚ and determine the identity of the product and mechanism for product. Procedure: Schoffstall‚ A.M.‚ Faddis‚ B.A.‚ and Durelinger‚ M.L. Microscale and Miniscale Organic Chemistry Laboratory Experiments‚ 2nd Ed.‚ McGraw-Hill‚ 2004‚ pages 215-218. Experiment 12.2 A Changes: Part A- No methanol recrystallization. Results and Observations
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Rossi/Kuwata Chemistry 222 Spring 2011 Experiment 2: Spectrophotometric Determination of Iron in Vitamin Tablets (Adapted from Daniel C. Harris’ Quantitative Chemical Analysis and R. C. Atkins‚ Journal of Chemical Education 1975‚ 52‚ 550.) Experimental work to be done on February 24 + one hour scheduled on your own Notebook due on March 4 (by 4:00 pm ⇒ 20% late penalty each 24 hour period thereafter) INTRODUCTION In this experiment‚ you will dissolve the iron in a vitamin supplement tablet‚
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Mechanism of chalcone formation Kinetic studies have been reported for the base-catalyzed formation of chalcone and its derivatives. [7‚ 8‚ 9] Two alternative mechanisms have been advanced for the reaction of benzaldehyde with acetophenone in the presence of a basic catalyst. 5 The formation of chalcone by the acid catalyzed condensation of acetophenone and benzaldehyde has been studied [10]. The following mechanism seems to be operating- 6 Importance of chalcones [1]They have close relationship
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The Sydney Tar Ponds are the most toxic hazardous waste site in North America‚ located in Cape Breton. These tar ponds were caused essentially from a century of steel making‚ polluting it with high levels of PCB‚ mercury‚ lead and polynuclear aromatic hydrocarbons. This was first discovered in 1980 by the Department of Fisheries and Oceans in Sydney Harbor‚ which resulted in a period of events and frustrations for both the government and residents. In1982 lobster fisheries were all closed down due
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HALIDES General formula: Ar–X where X = F‚ Cl‚ Br or I Examples Structure: C-X bonds are shorter and stronger Bond C-Cl C-Br Ar-X 1.69 A° 1.86 A° R-X 1.77 1.91 Dipole moments are unusually small. Bond C-Cl Preparation: 1. electrophilic aromatic substitution – useful only if one product is obtained C-Br Ar-X 1.7 D 1.7 D R-X 2.10 D 2.15 D Dipole moments may cancel out depending on the geometry of the molecule. 1 3/22/2012 PHYSICAL PROPERTIES: Boiling points – similar to those
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of Acetanilide Introduction: Bromination of acetanilide to 4-bromoaniline was studied in this experiment. One of the most important mechanism with the reaction of aromatic compounds is the electrophilic aromatic substitution reactions(wade‚2013). The electrophilic aromatic substitution enable scientists to make substituted aromatic compounds. However‚ substitution groups affect the electrophilic substitution mechanism. A nitrogen atom attached to hydrogen is learned to be a powerful activating
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Project Report – Herbal Processing Plant Sector: Forest‚ Environment and Herbal Project Title: Processing Plant for Wild Medicinal and Aromatic Plants Project Description Associated side effects and high cost of allopathic medicines are key reasons‚ herbal medications are being increasingly preferred over their synthetic counterpart. Around the world herbal industry is growing faster than the traditional pharmaceutical industry. India has a thriving herbal industry and there is a high potential for
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Rhodococcus SPECIES IN VARIOUS APPLICATIONS THROUGH FOUR MAIN MECHANISMS; CATABOLIZATION‚ BIOCONVERSION‚ BIODEGARDATION AND BIODESULPHURISATION. By ZAINAL ABIDIN BIN ABU BAKAR Thesis Submitted to the Faculty of Biotechnology and Life Sciences‚ Universiti Industri Selangor‚ in Partial Fulfillment of the Requirement for the Degree of Bachelor of Biotechnology Industry (Hons) May 2009 1 I hereby declare that the thesis is based on my original work except for quotations and citations
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