EXPERIMENT 4 ANALYSIS OF HYDROCARBON IN COMMON FUELS BY SOLID-PHASE MICROEXTRACTION (SPME) AND GAS CHROMATOGRAPHY-MASS SPECTROMETRY (GC-MS) Abstract In the analysis the solid-phase microextraction (SPME) and capillary gas chromatography/mass spectrometry (GC/MS) was developed for the identification of volatile compounds (hydrocarbon) in fuel. The samples was used is (kerosene‚ diesel‚ thinner and petrol) and one unknown. After the analyte was extracted by SPME in 20min‚ it directly injected
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which is a type of benzene reaction. This reaction consists usually of benzene and an electrophile. The role of the nucleophile is played by the double bond on the benzene ring. IT will react will the electrophile and this reaction will form a carbon cation intermediate. With additional reactions with a base‚ the electrophile fundamentally replaces the hydrogen of the benzene. Benzene is classified as one of the countless aromatic molecules‚ and this is just a plain benzene molecule. A different
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Are Aromatic Hydrocarbons Carcinogenic Aromatic hydrocarbons or arenes are hydrocarbons characterized by alternating double and single bonds between carbons. Benzene is the most common aromatic hydrocarbon‚ but there are some non-benzene based compounds called heteroarenes‚ where a carbon is replaced by an oxygen‚ nitrogen‚ or sulfur‚ that are also aromatic compounds. Aromatic hydrocarbons exist in our daily lives regardless if we recognize them or not. Aromatic hydrocarbons are ingested or
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carbon atoms are joined together in straight chains‚ branched chains‚ or non-aromatic rings. Aliphatics undergo free-radical substitution reactions. The aromatic hydrocarbon or arene‚ are characterized byhaving molecular structures which are called benzene rings. They are characterized by ionic substitution reactions due to their opposition to addition reactions because of their aromacity‚ the possession of aclosed loop of electrons and a manifestation of cyclic delocalization and low reactivity of
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Abstract In the asymmetric synthesis of (S)-Ibuprofen‚ the compound is synthesized in nonracemic form directly from an achiral precursor. First‚ racemic ibuprofen was converted to aN achiral ketene via the acid chloride by adding thionyl chloride followed by triethylamine. Then‚ ketene was reacted with a chiral and nonracemic (S)-ethyl lactate produces a mixture of diasteromeric esters of ibuprofen derivatives where (S) configuration is predominantly. Finally‚ hydrolysis of the ester then provides
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Title: Experiment 28: Nitration of Methyl Benzoate Objective: The students will learn to nitrate methyl benzoate through electrophilic aromatic substitution reaction. They will learn the importance of regiochemistry in chemical reactions. They might experience disubstitution through a high temperature. Reactions: Observation: The crystals started to form when added 2 g of crushed ice. The addition of hot methanol dissociated the crystals. The crystals reappeared when cooled down in
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(stretch) 1599&1493 Benzene C=C (aromatic stretch) 1597&1493 Benzene C=C (aromatic stretch) 1293 Carboxylic acid C-O (stretch) 1267 Carboxylic acid C-O (stretch) 788 Alkene =C-H bending (stretch) 786-845 Alkene =C-H bending (stretch) Pure (E)-α-phenylcinnamic acid 3054 Aromatic =C-H (stretch) 5053 Aromatic =C-H (stretch) 2616-3054 Carboxylic acid O-H (stretch) 2516-2951 Carboxylic acid O-H (stretch) 1676 Carbonyl C=O (stretch) 1673 Carbonyl C=O (stretch) 1599&1493 Benzene C=C (aromatic stretch)
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Synthesis of 1‚4-Di-t-buytl-2‚5-dimethoxybenzene via Friedel-Crafts Alkylation Introduction: Friedel-Crafts alkylation of benzene (and substituted benzenes) involves substituting a hydrogen atom on a benzene ring with an alkyl group. In the reaction a new alkyl group becomes bonded to a carbon atom of the aromatic ring which occurs by treatment of benzene (or substituted benzene) with a stable carbocation. The purpose of this experiment is to synthesize 1‚ 4-Di-t-butyl-2‚ 5 – dimethoxybenzene via the
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163 CHAPTER 13 HYDROCARBON Hydrocarbons are composed of Carbon and hydrogen. The important fuels like Petrol‚ kerosene‚ coal gas‚ CNG‚ LPG etc. are all hydrocarbons or their mixture. Sources: Petroleum and natural gas are the major sources of aliphatic hydrocarbon while coal is an important source of aromatic hydrocarbons. The oil trapped inside the rocks is known as petroleum. PETRA – ROCK‚ OLEUM – OIL. The oil in the petroleum field is covered with a gaseous mixture known as natural
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to take place‚ we must verify that we can obtain a product through the following nucleophilic aromatic substitution reaction: When electron withdrawing groups are present on a benzene ring‚ the ring can more easily undergo a nucleophilic attack. In this reaction we are dealing with a halogen (Cl) placed on the benzene ring‚ and when the electron withdrawing group is present either in ortho or para positions the nucleophilic attack will attack with more ease than if the EWG is positioned on meta
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