Organometallic preparation and addition to carbonyls‚ Wittig reagent preparation and Wittig rxn‚ Wolff‚ H-based nucleophile carbonyl reduction‚ imine formation‚ reductive amination (rxn only)‚ ketal/acetal formation‚ dithiane chemistry (rxn only)‚ alpha-bromination of ketones‚ -COOH properties (the trends on HW4)‚ Fischer‚ acidic/basic hydrolysis of esters/amides/nitriles‚ CH2N2‚ acid chloride formation (rxn only)‚ acid chloride rxns with esters and amides. 2 Rxn of carboxyllic acid derivatives
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EXPERIMENT 2: SYNTHESIS OF ORANGE II (2-NAFTHOL ORANGE OBJECTIVE 1. To produce dye based to the coupling of diazonium. 2. To understand the characteristic of dye orange II. INTRODUCTION The first dye was introduced by William Henry Perkin on 1856. It can be produced by the coupling of diazonium sulfanilic acid with nafthol in alkaline solution.. This was the common method used to produce dye nowadays. In this experiment‚ dye produced was the orange II. Azo compound is compound that contain
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Key Questions Lesson 1 1. One argument against continuing research on the atom is that the cost continues to increase at an alarming rate‚ and the benefits seem to be declining. Whereas quantum chemistry experiments as early as 80 years ago were very cheap and yielded considerable practical results‚ now very few if any practical results are emerging‚ but the costs of experiments continues to increase. On the other hand a common argument for the continued
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experimental techniques which can be used to tell us where the atoms are located in a molecule. Using advanced techniques‚ very complicated structures for proteins‚ enzymes‚ DNA‚ and RNA have been determined. Molecular geometry is associated with the chemistry of vision‚ smell and odors‚ taste‚ drug reactions and enzyme controlled reactions to name a few.
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ical Chemistry 1.which of the following pairs of compound will react? iC3H6+Br2 iiC3H6+Cl2 in sunlight iiiC3H6+H2O in the presence of sulphuric acid ivC3H6+H2O in the presence of concentrated sulphuric acid a.i b.i‚iii c.i‚ii‚iii d.all 2.liqiud y reacts with magnesium metal to produce a gas that burns with a pop sound when a flaming wooden splint is placed near it.liqiud y is most likely a compound that has the formula a.c2h5oh b.hcooh c.h3cooch3 d.c6h14 3.a compound p has the
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Extraction of Aluminium Aluminium ore is called bauxite. Bauxite contains aluminium oxide‚ water‚ iron oxide and other impurities. The purified dry ore‚ called alumina‚ is aluminium oxide (Al2O3). The alumina must be molten for electrolysis to work‚ since the ions are not free to move in the solid state. Unfortunately‚ alumina has a high melting point (2040 °C) and it is not practical to do electrolysis at such a high temperature. In the middle of the nineteenth century it was found that alumina
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1 in vapour state sulphur partly exists as S2 molecule which has 2 unpaired electrons in the antibondind pi orbitals jus lyk oxygen and thus exhibits paramagnetism. 2 An interhalogen compound is a molecule whose atom contains two or more different halogen atoms (fluorine‚ chlorine‚ bromine‚ iodine or astatine). Most interhalogen compounds known are binary (composed of only two distinct elements). Their formulas are generally XYn‚ where n = 1‚ 3‚ 5 or 7‚ and X is the less electronegative
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2007) (3) William Bonner‚ A (4) Lemieux‚ R. U.; Pavia‚ A. A. Solvation Effects on Conformational Equilibria. Studies Related to the Conformational Properties of 2-Methoxytetrahydropyran and Related Methyl Glycopyranosides. Canadian Journal of Chemistry 1969‚ 1966–1968. (5) M. L. Wolfrom‚ Donald R. Husted; the Beta to Alpha Conversion of Fully Acetylated Sugars by Alkali. J. Am. Chem. Soc.‚ 1937‚ 59 (2)‚ pp 364–365 (6) Perles‚ C (9) Spectral Database for Organic Compounds (SDBS); mass spectrum;
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This is important for the students to appreciate the knowledge of chemistry that is still new for themselves. Personally‚ I think that this chapter is an interesting chapter as it revealed the way of scientist produces the material around me. It also gives me new knowledge of the uses of chemical substances that I usually found in the laboratories. I hope‚ by learning this chapter‚ I will be more interested in learning chemistry as it will help me in the future. All the equations from this chapter
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atoms can rotate and vibrate with respect to each other. These vibrations and rotations also have discrete energy levels‚ which can be considered as being packed on top of each electronic level. UV/Vis spectroscopy is routinely used in analytical chemistry for thequantitative determination of different analytes‚ such as transition metal ions‚ highly conjugated organic compounds‚ and biological macromolecules. Spectroscopic analysis is commonly carried out in solutions but solids and gases may also
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