alpha carbon anion on the carbonyl carbon on the 3-nitrobenzaldehyde. Next‚ is the protonation of the oxygen from the 3-nitrobenzaldehyde‚ which is then followed by an elimination reaction where this acts as a leaving group. The product is the trans-alkene present in the product. Figure 2: Mechanism
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CONCEPTS IN ORGANIC CHEMISTRY • Inductive Effect : Inductive effect is defined as permanent displacement of shared electron pair in a carbon chain towards more electronegative atom or group. Types of Inductive effect : 1.Negative Inductive Effect : (—I effect‚ Electron withdrawing effect) when an electronegative atom or group (more electro negative than hydrogen)is attached to the terminal of the carbon chain in a compound‚ the electrons are displaced in the direction of the attached
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2012) In the first step‚ the mixture of water‚ concentrated sulphuric acid‚ and cyclohexene was shaken vigorously until it became a homogenous solution. Followed by‚ the addition of water‚ and the distillation process lead to the hydrolysis of the alkene. Finally‚ addition of diethyl ether to the mixture then distillation took place to be purified and to obtain the final product‚ cyclohexanol (McFadden‚ 2012). Diethyl ether was used to extract alcohol from salt-water mixture because diethyl ethers
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CHEMISTRY PART I PREPARED BY SYED ABDUL ILLAH ALYAHYA BIN SYED ABD KADIR 1 TOPICS PART I 1.1 1.2 1.3 1.4 1.5 Introduction to Hydrocarbon and Functional Groups Alkanes and Cycloalkanes Isomerism and Overview of Organic Reaction Alkenes and Alkynes Alkyl Halides 2 TOPIC INTRODUCTION TO HYDROCARBON AND FUNCTIONAL GROUPS 3 1.1 Introduction to Hydrocarbon and Functional Groups What is Organic Chemistry? • Organic chemistry is a branch of chemistry that focuses on
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chemistry? Carbon compounds. Methane CH4 Hexane C6 H14 Ethane C2H 6 Heptane C7 H16 Propane C3H 8 Octane C8 H18 Butane C4H10 Nonane C9H20 Pentane C 5 H12 Decane C1 0 H22 Alkanes: Saturated Hydrocarbons Rules: Cycloalkanes: Alkenes: Alkynes: General formula: Cn H2n General formula: Cn H2n General formula:Cn H2n -2 Haloalkanes: Alekanes: Alcohols: Alkylhalides CnH2n+n “OH” group F (Fluoro)‚ Cl (Chloro)‚ Br (Bromo)‚ I (Iodo) Other rules: “Anes” - No double
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Clays are one of the important natural materials‚ which have been examined for catalytic applications. Clays are characterized by a layered structure and hence they are slippery when wet. They are broadly classified as cationic or smectite type (having layer lattice structure in which two-dimensional oxyanions are separated by layers of hydrated cations) and anionic or brucite type (in which the charge on the layer and the gallery ion is reversed complimentary to smectite type). Anionic clays are
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UNIVERSITI TEKNOLOGI MARA COURSE INFORMATION Confidential Code Course Level Credit Hours Contact Hours : : : : : CHM 556 Organic Chemistry II Degree 4 3 hr (Lecture) 3 hr (Practical) 3 Core CHM 456 Part Course Status Pre-requisite : : : Course Outcomes : Upon completion of this course‚ students should be able to: 1. Determine functional groups present in organic compounds using Infrared Spectroscopy and interpret Nuclear Magnetic Resonance spectra and relate the information to structural
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1. A student neglected to add sodium carbonate when extracting the tea leaves with hot water. Yet a very high yield of caffeine was obtained. The crystals melted at 202-214°C. Explain. • The sodium carbonate is supposed to be added when extracting the tea leaves with hot water in order to help purify the caffeine. So since the student neglected to add sodium carbonate the caffeine won’t be pure but the student would still be able to recover a large amount of caffeine. The literature melting point
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temperature around 100C or less. The crude product was collected which contained water‚ 4-methylcyclohexene‚ and trace acid. D. Questions: 1. Outline a mechanism for the dehydration of 4-methylcyclohexanol catalyzed by phosphoric acid. 2. What major alkene product is produced by the dehydration of the following alcohols? a. Cyclohexanol Cyclohexene b. 1-Methylcyclohexanol methylcyclohexene c. 2-Methylcyclohexanol methylcyclohexne d. 2‚2-dimethylcyclohexanol 1‚2-dimethylcyclohexene 3. Compare
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63.08% Discussion This experiment involved the addition of trans-cinnamic acid to bromine for the production of 2‚3-dibromo-3-phenylpropanoic acid. This process depicted an electrophilic addition of a halogen to an asymmetrically substituted alkene. A result of this process was the presence of a stereospecific bromonium ion formed by the mechanism of the reaction. The mixing of 2.5g of trans-cinnamic acid with 14.6 ml of 10% bromine in dichloromethane over a low heat enable to increase the
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