Preparation of 4-bromoaniline Introduction Aromatic compounds tend to undergo electrophilic aromatic substitutions rather than addition reactions. Substitution of a new group for a hydrogen atom takes place via a resonance-stabilized carbocation. As the benzene ring is quite electron-rich‚ it almost always behaves as a nucleophile in a reaction which means the substitution on benzene occurs by the addition of an electrophile. Substituted benzenes tend to react at predictable positions. Alkyl groups
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Which of the following is vinyl halide? (a) CH2CL2 (b) CH2= CH-Cl (c) CH = C-Cl (d) 6) What is B in R-OH + PX5 R-X +B+ HX? (a) HPOX3 (b) H3PO3 (c) POX3 (d) H3PO2 7) Which catalyst is used in preparation of bromobenzene by bromination of benzene? (a)FeBr3 (b) HBr (c) AlBr3 (d) Br2 8) By which name the reaction CH3 - Br + Ag- F CH3F + AgBr is known? (a) Grignard (b) Wurtz (c) Fitting (d) Swartz 9) What are nucleophilic reagents according to Lewis theory
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electron density above and below the plane of the ring - making it nucleophilic‚ and the drive to regain the aromatic character by opting for substitution as opposed to a simple addition reaction. Preference towards addition reactions in the case of alkenes and substitution in the case of aromatic compounds becomes evident if we analyze the energy profiles of these reactions (Figures 1 and 2). Figure 1. Indian Institute of Technology Madras Engineering Chemistry III Prof. K. M. Muraleedharan
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MANGOSTEEN FRUIT | | | | The Mangosteen Fruit is by far the most exotic fruit in the world. It has been researched and studied so much that this site is dedicated to bring you all that information and research. | | The Mangosteen contains several classes of phytonutrient antioxidants and is the only place in nature to contain a broad spectrum of a new class of phytonutrients called Xanthones. The potent effects on human health of the Mangosteen have been observed for centuries in Southeast
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was then recrystallized from methanol‚ yielding 0.128g of pale yellow crystals with a melting point of 131-135 oC. This represents 0.33% of the original mass of the two yolks. The cholesterol was then dissolved in ether and further purified by bromination with a bromine/acetic acid reagent and debromination with zinc powder‚ a series of aqueous washes‚ and a final recrystallization from methanol. Here‚ a yield of 28% was recovered from an initial mass of 100 mg of recrystallized material. The melting
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1. Which of the following are the products of a homolytic cleavage of a C-C bond of ethane? A) 2 B) CH3 CH3 C) H D) 2 + + CH3 CH2H3 CH3 Ans: A Chapter 11 Topic: Radicals Section: 11.1 Difficulty Level: Easy 2. Which of the following is the most stable radical? A) B) C) D) E) Ans: B Chapter 11 Topic: Radicals Section: 11.1 Difficulty Level: Easy 3. In the molecule shown below‚ determine which of the labeled bonds is
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Introduction: For this lab‚ the main focused involved alkanes and hydrocarbons. Essentially‚ the free-radical chain of chlorination of 1-Chlorobutne. Free radical-chains occur because alkanes are chemically unreactive with most agents. However‚ the free-radical chain allows a pathway of certain functional groups like alkyl chloride or bromides. In addition‚ chlorine atoms can possibly be made from molecular chlorine under low to mild conditions with the usage of a catalytic amount of an initiator
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Comparative functional identification and analysis of Carica papaya promoter in the model system Arabidopsis thaliana revealed post-transcriptional regulation of gene expression INTRODUCTION a a CaMV35S Poly-A hptII b 5’ 3’ RB eGFP Promoter Construct b 1975 66 759 42 759 Cp29-eGFP 1796 36 759 75 759 759 Primer 3’ 5’ Transcribed mRNA chain 36 39 42 45 Cp45 WT 27 kDa 7 DAP 600bp 14 DAP 14
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1. List all Functional Groups 2. What is an alkane? List its properties. 3. Write the name and formula of simple alkanes 4. Consider this compound (CH3)2CHCH2C(CH3)3. Name this. a. redraw it clearing all brackets and parentheses. b. Find the longest chain. Check from all directions. If it is not horizontal‚ rewrite the compound that so that longest chain IS horizontal. c. Number the carbons of the longest chain backwards and forwards.
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Introduction to Alkane Nomenclature A. Determining the Priority of Functional Groups. What’s in a name? 3-ethyl-5-(1-methylpropyl)-4‚4-dimethylnonane Too big a subject to cover on one sheet! This paper will focus on alkanes. Determining functional group priority will be the subject of a subsequent sheet. suffix http://masterorganicchemistry.com D. Applying the Lowest Locator Rule F. Dealing With Branched Substituents (the IUPAC Way) Number the chain from one end so as
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