1 Haloalkanes and Haloarenes IIT-JEE Chemistry Siddhivinayaka Educational Academy Rajendra Nagar Chowk Link Road Bilaspur Ph-07752- 237799/238799 Website : www.bajpaigroup.com. e-mail - info@bajpaigroup.com CHAPTER 23 LEARNINg OBJECTIvES (i) Name haloalkanes and haloarenes according to the IUPAC system of nomenclature from their given structures. (ii) Describe the reactions involved in the preparation of haloalkanes and haloarenes and understand various reactions that they undergo.
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Experiment 1: Preparation of 1-Bromobutane and Reactivity of Alkyl Halides Objective: The purpose of this lab is to prepare 1-bromobutane from 1-butanol in an acid-catalyzed substitution reaction. While the reaction would be expected to occur as SN2 due to the primary nature of the substrate‚ because H2SO4 is used as a solvent‚ the conditions are very polar and the reaction can proceed via an SN1 reaction. The main objective is to obtain test results to determine the mechanism of the reaction
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layer is there to protect life from the ultraviolent rays from the sun. These layers become depleted due to high concentrations of chlorine or bromine atoms and include chlorofluorocarbons‚ or CFC’s‚ halons‚ methyl bromide‚ carbon tetrachloride and methyl chloroform (King & Media n.d.). Since the automobiles‚ emission gases contain few chlorine or bromine; therefore‚ they have little effect on depleting the ozone layers. However‚ the different gases and particles that automobiles emit affect our
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A Synthesis of Safrole and o-Safrole W.H. Perkin & V.M. Trikojus J. Chem. Soc. 1663 (1927) HTML by Rhodium No direct synthesis of safrole has been recorded‚ the most recent attempt being that of Baker and Robinson (JCS‚ 1925‚ 127‚ 1424)‚ who distilled the product of the action of silver oxide and water upon gamma-piperonylpropyltrimethylammonium iodide‚ but obtained isosafrole‚ the double bond moving into the position of greater stability. Kawai (Sci. Papers Inst. Phys. Chem. Res.‚ 1925‚ 3‚ 263)
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Synthesis of 7‚ 7- dichloronorcarane in Carbon Addition Reaction CHM 337 | Dr. Pettit Abstract: A solution of cyclohexene‚ aqueous sodium hydroxide‚ and benzyltriethylammonium was used to synthesize 7‚7 – dichloronorcarane by the following reaction: + CHCl3 + OH - H2O + + Cl - After completion of the experiment‚ the percent recovery was calculated to be 46.21% Introduction The purpose of this experiment was to form 7‚7-dichloronorcarane by means of carbene trapping
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chemicals such as chloroflourocarbons (CFCs)‚ halons‚ carbon tetrachloride‚ methyl chloroform‚ methyl bromide and hydrochloroflourocarbons (HCFCs) are the major contributors to the deterioration of the ozone layer. These chemicals have industrial halocarbons that break up into chlorine and bromine in the upper stratosphere when they react with the sun’s rays. Chlorine eats up the ozone layer while bromine acts as a catalyst and speeds up the process. Often found in Antarctica‚ there are frozen chemical
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PAHANG TRIAL 2009 EXAMINATION CHEMISTRY PAPER 2 MARKING SCHEMES SECTION A - Structural Questions: Question 1. (a) (i) The presence of isotopes 1M (ii) Let the abundance of 63X be a %. The % abundance of 65X. = ( 100 – a ) 1M Relative atomic mass = ( 62.93 x a) + ( 64.93 x ( 100 -a) ) 1M
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w w ap eP m e tr .X w om .c s er UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education *9505164189* 0653/03 COMBINED SCIENCE May/June 2007 Paper 3 (Extended) 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number‚ candidate number and name on all the work you hand in. Write in dark blue or black pen
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of anthropogenic pollutants. There are a number of chemical reactions that can deplete stratospheric ozone; however‚ some of the most significant depletion comes from the catalytic destruction of ozone by freed halogen radicals like chlorine and bromine. Overview of Ozone Depletion Ozone depletion is term used to describe occurrences regarding the Earth ’s ozone layer. One of these observable trends is the slow and constant deterioration of the ozone in the atmosphere of about three percent
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benzene‚ heptanol‚ sec-butanol‚ phenol‚ acetyl chloride‚ buteraldehyde‚ benzaldehyde‚ 2-butanone‚ propanoic acid‚ sucrose‚ diethyl ether‚ butyl bromide‚ acetonitrile‚ L-alanine‚ n-amyl acetate‚ benzene sulfonyl chloride and aniline were used as test compounds. Observations were noted‚ such as changes in color and product formation. Iodine test‚ bromine test‚ Baeyer Test‚ Chloroform and aluminum chloride‚ fuming sulfuric acid‚ acetyl chloride‚ chromic acid‚ iodoform‚ Lucas’ test‚ Anilide formation
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