7. Modelling Polyethylene As mentioned previously‚ PE is one of the most important polymers in the world. ADMET has been used to systematically model commercially relevant polymers‚ specifically PE and copolymers of ethylene and another monomer. ADMET is capable of producing PE with specific sequences of monomer units‚ as well as random copolymers via copolymerization with 1‚9-decadiene. The ability to precisely synthesize these polymers has opened the door to exploring the molecular origins of
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boiling points of two different substances are very different. Fractional distillation is the separation of a mixture of multiple components into its various fractions according to the difference in their boiling temperatures. a.) Hexyl acetate and butyl acetate- Simple distillation should be used for these two compounds because their boiling points are very different. b.) Hexanol and cyclopentanol- Fractional distillation should be used because there is a small difference of boiling points between
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Ind. Eng. Chem. Res. 1994‚33‚1687-1691 1687 Synthesis of Triphenyl Phosphate and Benzyl Benzoate with Phase-Transfer Catalyst in Heterogeneous Liquid-Liquid Reaction System S a t o r u Asai‚’ Hidemi Nakamura‚ Mitsunori Tanabe‚ and Kenji Sakamoto Department of Chemical Engineering‚ University of Osaka Prefecture‚ Sakai‚ Osaka 593‚Japan The synthetic reactions of triphenyl phosphate from diphenylphosphoryl chloride and sodium phenoxide and of benzyl benzoate from benzyl chloride and sodium
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benzaldehyde‚ 2-butanone‚ propanoic acid‚ sucrose‚ diethyl ether‚ butyl bromide‚ acetonitrile‚ L-alanine‚ n-amyl acetate‚ benzene sulfonyl chloride and aniline were used as test compounds. Observations were noted‚ such as changes in color and product formation. Iodine test‚ bromine test‚ Baeyer Test‚ Chloroform and aluminum chloride‚ fuming sulfuric acid‚ acetyl chloride‚ chromic acid‚ iodoform‚ Lucas’ test‚ Anilide formation‚ ester formation‚ hydrolysis‚ hydroxamic acid‚ Benedict’s test‚ Chromic test
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from the molecule by ionization: CH3CO2H → CH3CO2- + H+ Because of this release of the proton (H+)‚ acetic acid has acidic character. Acetic acid is a weak monoprotic acid. In aqueous solution‚ it has a pKa value of 4.75. Its conjugate base is acetate (CH3COO−). A 1.0 M solution (about the concentration of
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with the goal of synthesizing an alkyl halide from alcohol and a hydrogen halide. In order to do this‚ tert-butyl alcohol was mixed with HCl to form crude tert-butyl chloride. Solid NaHCO3 and CaCl2 were used to prevent possible hydrolysis of the product. It was then purified through distillation. Results confirm the successful production of 5.01 g (51.5% yield) of the alkyl halide‚ tert-butyl choride. ------------------------------------------------- INTRODUCTION The importance of alkyl halides
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a solution α-naphthol 1a‚ 4-methylbenzaldehyde 2a and tert-butyl isocyanide 3a in EtOH was magnetically stirred at 45 C for 12 hours under an oxygen atmosphere with an equimolar ratio of the three reactants. TLC monitoring of the reaction mixture exhibited formation of a new product‚ which was purified (Table 1‚ entry 1). Identification of its structure by NMR spectroscopy revealed that it was 2-(4-methylbenzoyl)-1-naphthyl N-(tert-butyl)carbamate (4a). Next‚ in order to improve the yield of 4a‚
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Organic Chemistry: CHP 225 Thomas Hsieh Experiment 2: Boiling Points o Date experiment was performed: September 16‚ 2011 o Objective: To determine the boiling point of organic compounds such as tert-butyl alcohol‚ sec-butyl alcohol‚ n-butyl alcohol‚ and an unknown. o Principle: Boiling point is the temperature at which gas and liquid phases coexist in equilibrium. At this temperature‚ the vaporization rate and the condensation rate are equal. The liquid and vapor reach a state of dynamic
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simultaneous estimation of of ellagic acid‚ chlorogenic acid‚ gallic acid and quercetin in the leaf extract of Terminalia tomentosa and its Formulation. The stationary phase used was precoated silica gel 60F254.The mobile phase used was a mixture of Butyl acetate: Formic Acid: Distilled Water 14:5:5 (v/v). The detection of spots were carried out at 254 nm. This HPTLC method was validated statistically and recovery study was performed to confirm the accuracy of the method. It can be used for routine quality
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------------------------------------------------- How to make own Sodium Acetate ------------------------------------------------- 1. Add 6 tablespoons of baking soda to a pot. Do not use baking powder. 2. Add 2 liters of white vinegar to the baking soda until it stops fizzing. Do this bit by bit to avoid spills and stir often. When the fizzing stops‚ the reaction is complete‚ leaving you a diluted solution of sodium acetate. The solution should be clear. 3. Boil the solution until around
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