by : Directorate of Education‚ Delhi SOME IMPORTANT REASONING BASED QUESTIONS OF ORGANIC CHEMISTRY 1. Chlorobenzene is less reactive than chloromethane. Ans. In chlorobenzene‚ each carbon atom of benzenering is sp2 hyridised and is electron withdrawing. Chlorine atom donates a lone pair of electron and acquire positive charge. The negative charge is delocalised on ortho and para position by resonance. C-Cl bond acquires partial double bond character and is 169 pm as compared to 17.0 pm in chloromethane
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HKDSE CHEMISTRY – A Modern View (Chemistry) Experiment Workbook 5 Suggested answers Chapter 52 Importance of industrial processes Chapter 53 Rate equation Experiment 53.1 Determining the rate equation of a reaction using method of initial rate (A microscale experiment) 1 Chapter 54 Activation energy Experiment 54.1 Determining the activation energy of a chemical reaction 3 Chapter 55 Catalysis and industrial processes Experiment 55.1 Investigating the action of a catalyst 6 Experiment
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sebacoyl chloride with the loss of HCl via nucleophilic substitution. Cellulose triacetate was generated by mixing cotton balls and acetic anhydride with acidic condition under heating. Materials: Styrene‚ 1 M NaOH solution‚ CaCl2(s)‚ xylene‚ t-butyl peroxybenzoate‚ methanol‚ 5% aqueous solution of 1‚ 6-hexanediamine‚ NaOH(s)‚ 5% sebacoyl chloride in hexane‚ glacial acetic acid‚ concentrated H2SO4‚ cotton balls‚ acetic anhydride‚ CH2Cl2 Procedure: For the synthesis of polystyrene‚ 10 ml styrene
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on the Heinemann website. 2. Read Section 13.5 in your Chemical Ideas book which deals with naming and making esters. Chemical Ideas 1. While doing Chemical Ideas 13.5 there is no need to cover polyesters (page 318) or ester hydrolysis (page 319). These will be covered in Designer Polymers (DP). As a result there is no need to do Problems 4‚ 6 (parts d & e) or 8 (parts d & e). 2. Add Esters from salicylic acid (page 315). 3. Note that the anhydride reactions on pages 318–319 do not need to be learned
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SYNTHETIC EXPLOITATION OF ENZYMES: BIOCATALYSIS IN ORGANIC SOLVENTS: FUNDAMENTALS ENZYMES IN ORGANIC SYNTHESIS 1. Enzymes catalyze a broad spectrum of reactions with high turnover numbers. Rate enhancements approach 1012 fold. 2. Enzymes may accept a wide range of substrates. 3. Enzymes are highly regio and stereoselective. 4. Enzyme reactions take place under mild conditions; this minimizes problems of isomerization and racemization. 5. Enzymatic processes are less hazardous and polluting
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South Africa. b. Department of Pharmacy and Pharmacology‚ University of Bath‚ United Kingdom. Abstract Synthesis of sodium butyldithiocarbamate pentahydrate‚ C5H20NNaO5S2‚ entailed a one-pot synthesis. The process of synthesis involved the use of butyl amine‚ carbon(IV) sulfide and sodium hydroxide at a temperature < 0oC. Crystals were obtained and the compound was characterized with elemental analysis‚ Fourier infra-red spectroscopy (FT-IR)‚ Ultra-violet visible (UV-VIS)
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1. Identify the natural sources of sulphur dioxide and oxides of nitrogen. SO2‚ natural: - Geothermal hot springs and volcanic activity are natural sources of SO2. - In the process of decaying of organic matter some bacteria will produces hydrogen sulphide as a waste product which will oxidise‚ forming so2. - Phytoplankton release dimethyl sulphide (DMS) into the atmosphere‚ when this is oxidised it forms sulphuric acid. NOx‚ natural: - Lightning activity generates high temperatures to allow
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bonds between ethanol molecules. B. To measure the strength of hydrogen bond formed between ethanol molecules C. To investigate the formation of hydrogen bonds between molecules of ethyl ethanoate and trichloromethane. D. To measure the strength of hydrogen bond formed between molecules of ethyl ethanoate and trichloromethane. Procedure A. 1. 10 cm3 of ethanol was added into an insulated 50 cm3 beaker by using a measuring cylinder. The temperature of the liquid was measured.
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MATERIALS REVOLUTION UNIT REVISION BOOKLET Vikram Mahal How To Use this Booklet: This booklet has been created by addressing all the points on the OCR B salters specification for the section‚ what’s in medicine. I advise reading through the Book‚ highlighting or underlining words written in ALL CAPITALS. I also suggest making a spider diagram or mind map to summarise key points and help the information here stick in your mind. You could also draw your own images by points on this
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SERANGOON JUNIOR COLLEGE General Certificate of Education Advanced Level Higher 2 CHEMISTRY JC2 Preliminary Examination Paper 1 Multiple Choice Additional Materials: Data Booklet Optical Mark Sheet (OMS) 9647/01 23 August 2011 1 hour READ THESE INSTRUCTIONS FIRST On the separate multiple choice OMS given‚ write your name‚ FIN/NRIC and class in the spaces provided. Shade correctly your class and FIN/NRIC number. Eg. If your NRIC is S9306660Z‚ shade S9306660Z for the item “index number”. There
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