Richard F. Daley and Sally J. Daley www.ochem4free.com Organic Chemistry Chapter 2 Introduction to Organic Nomenclature and Functional Groups 2.1 Drawing Organic Structures 73 2.2 Alkanes 77 2.3 Structural Isomerism 77 2.4 IUPAC Nomenclature 79 2.5 Naming Alkanes 80 2.6 Naming Cycloalkanes 87 2.7 Naming Complex Alkyl Groups 2.8 Functional Groups 97 2.9 Naming Alkenes and Alkynes 2.10 Naming Alkenes‚ Part II 108 2.11 Arenes 109 2.12 Organohalogens 113 2.13 Using Molecular
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Chapter 1 MULTIPLE CHOICE QUESTIONS Topic: Atomic Orbitals 1. A) B) C) D) E) In quantum mechanics a node (nodal surface or plane) is: a place where Ψ is negative. a place where Ψ is positive. a place where Ψ = 0. a place where Ψ2 is large. a place where Ψ2 is negative. Ans: C Topic: Atomic Orbitals‚ Molecular Orbitals 2. When the 1s orbitals of two hydrogen atoms combine to form a hydrogen molecule‚ how many molecular orbitals are formed? A) 1 B) 2 C) 3 D) 4 E) 5 Ans:
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in the box will be graded. _______________________________________________________________________ _ 1. (30) (a) Draw a stepwise mechanism for the following reaction. Use curved arrows to indicate the movement of electrons. O O H3 C H+ HO OH CH3 O H3 C O CH3 O . (b) Briefly explain the fact that‚ although hemiacetal formation between methanol and cyclohexanone is thermodynamically disfavored‚ addition of methanol to cyclopropane goes essentially to completion. O CH3OH HO OCH3 O
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pts) Indicate which of the following pairs do not constitute resonance structures by drawing an “X” in the space provided? O CH3C-O O - O and - CH3C O OH CH3C-OH O CH3CCH3 and CH3C O OH CH3C CH2 X X X X and and and - CH2CH CH 2 HOCN + CH2 CH CH2 HNCO 3. (8 pts) What is the hybridization of the Carbon indicated in bold in the following compounds? H2C=O sp2 C sp2 H C C Br sp CBr4 sp3 4. (10 pts) Malonic acid‚ HO2CCH2CO2H
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PCB NO: 1CH 06-C0771-C0 2Ch 06-C0885-00/10; 4Ch 06-C0886-00/10/20‚06-C0887-30; 5Ch 06-C0887-00/10/20/30 Rev: B1 65-C0317-MA R CONGRATULATIONS! You now own a Limited Edition LIL WONDER Amplifier‚ the product of an uncompromising design and engineering philosophy. T E C H N O L O G I E S To maximize the performance of your system‚ we recommend that you thoroughly acquaint yourself with its capabilities and features. Please retain this manual and your sales receipt for future reference
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General Papers ARKIVOC 2006 (i) 109-118 Synthesis and primary antiviral activity evaluation of 3-hydrazono-5-nitro-2-indolinone derivatives Nalan Terzioğlu *a‚ Nilgün Karalı a‚ Aysel Gürsoy a‚ Christophe Pannecouque b‚ Pieter Leysen b‚ Jan Paeshuyse b‚ Johan Neyts b‚ and Erik De Clercq b a Istanbul University‚ Faculty of Pharmacy‚ Department of Pharmaceutical Chemistry‚ 34116‚ Istanbul‚ Turkey b Rega Institue of Medical Research‚ Katholieke Universiteit Leuven‚ B-3000 Leuven‚ Belgium E-mail:
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Peptide synthesis – chemistry and modifications Peptides and proteins exhibit the largest structural and functional variation of all classes of biologically active macromolecules. Biological functions as diverse as sexual maturation and reproduction‚ enzyme inhibition‚ blood pressure regulation‚ glucose metabolism‚ thermal control‚ analgesia and learning and memory are now thought to be regulated by peptides. Peptide synthesis chemistry Synthetic peptides are valuable tools in analysis of
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Preparing Isopentyl Acetate by the Fischer Esterification Preparing Isopentyl Acetate by the Fischer Esterification Leah Monroe May 8‚ 2003 Organic Chemistry Lab II Experiment performed on April 29 and May 1‚ 2003 Abstract: The purpose of this experiment was to synthesize isopentyl acetate via an esterification reaction between acetic acid and isopentyl alcohol‚ using concentrated sulfuric acid as a catalyst. The product was washed with sodium hydrogen carbonate‚ as well as with water
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Topic Acid-Base Theory (Unit 1) Acid-Base Theory (Unit 2) Isomerism (Unit 1) Isomerism (Unit 2) Nomenclature Reaction Mechanism (Unit 1) - Introduction to Mechanism Reaction Mechanism (Unit 2) - Nucleophilic substitution Reaction Mechanism (Unit 3) - Nucleophilic substitution Reaction Mechanism (Unit 4) - Nucleophilic substitution Reaction Mechanism (Unit 5) - Nucleophilic substitution Reaction Mechanism (Unit 6) - Nucleophilic substitution Reaction Mechanism (Unit 7) - Elimination Reaction Mechanism
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DETAILED LESSON PLAN IN ADVANCED CHEMISTRY IV- Euler LEARNING OBJECTIVES At the end of the lesson‚ students are expected to: Write the IUPAC name of certain alcohol compounds; SUBJECT MATTER Topic: Nomenclature of Carboxylic Acid References: General‚ Organic and Biochemistry by Denniston‚ Topping and Caret. Page 283-289. Fundamentals of General‚ Organic and Biochemistry by John R. Holum. Page 418-425. Materials: Ball and stick model of compounds Overhead projector Textbooks Pictures of certain
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