pubs.acs.org/joc Mechanism and Regioselectivity of the Osmium-Catalyzed Aminohydroxylation of Olefins Dominik Munz and Thomas Strassner* Physikalische Organische Chemie‚ Technische Universit€t Dresden‚ Mommsenstrasse 13‚ 01062 Dresden‚ a Germany thomas.strassner@chemie.tu-dresden.de Received November 12‚ 2009 The mechanism and regioselectivity of the osmium-catalyzed aminohydroxylation of olefins was investigated in detail by density functional theory (B3LYP/6-31G(d)) calculations in
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cancer prevention or as punishment related to sex crimes. Chemical and Surgical Castration Chemical Castration Under medical supervision anti-androgen drugs are injected under a multi-week treatment. With lower testosterone levels most men will experience a reduced sex drive‚ arousal and sexual thoughts. On sexual offenders Depo-Provera a progestin shot is used this chemical castration does not remove the testicles and if the chemical treatment is used to discontinued his testosterone and sperm
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Aim: To determine the rate law of chemical reactions Introduction: The aqueous solution of potassium peroxydisulphate can oxidize potassium iodide as follow: Equation: K S 0 (aq) + 2KI (aq)->2K S0 (aq)+I (aq) 2 2 8 2 4 2 KI(aq) +I (aq) -> KI (aq) 2 3 _________________________________________________ K S 0 (aq) +3KI(aq) -> 2K S0 (aq)+ KI (aq) 2 2 8 2 4 2 The rate law of this reaction can be represented as follow: Rate=k[S208 2-]^a [I-]^b When the concentration of peroxydisulphate ions
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CHEMICAL REACTIONS OF COPPER AND PERCENT YIELD Objective To gain familiarity with basic laboratory procedures‚ some chemistry of a typical transition element‚ and the concept of percent yield. Apparatus and Chemicals |0.5 g piece of no. 16 or no. 18 copper wire |evaporating dish | |250 mL beaker (2) |weighing paper | |concentrated HNO3 (4 – 6 mL)
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Chemical Kenetics A. B. C. Doloiras Department of Chemical Engineering‚ College of Engineering University of the Philippines‚ Diliman‚ Quezon City‚ Philippines DATE PERFORMED: June 28‚ 2013 INSTRUCTOR’S NAME: Ms. Irina Diane Castanos ______________________________________________________________________________________________________________________________ ABSTRACT This experiment aims to determine the influences of varying factors: temperature‚ concentration of reactants‚ and presence
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Background Victoria Chemicals‚ a major player in the global chemical industry that supplies polypropylene‚ polymer that used to manufacture carpet fibers‚ packaging‚ automobile parts to the customers in Europe and the Middle East. Apart from numerous small producers‚ the company also receives the threats from the other seven major competitors. The company owns two plants in Europe‚ one being Merseyside Works‚ England and Rotterdam Facility‚ Holland. Both plants were built in 1967 and are identical
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3.1.1 Identify that matter is made of particles that are continuously moving and interacting The particle theory states that all matter is made up of tiny particles and they are constantly moving/continual state of motion. 1.1.2 Identify the difference between elements‚ compounds and mixtures in terms of particle theory Elements are simplest form substance meaning cannot be decomposed further physically or chemically. They are made up of same type of atoms only e.g. helium‚ oxygen. Compounds
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Although when you first hear the word Krypton you just might automatically think of the planet in the Superman comics. Krypton is a chemical element of the periodic table. The periodic table has about one hundred and eighteen elements. Krypton is number thirty six in the periodic table it is in group eighteen period four. It is a part of the noble gas series. Its atomic number is thirty six and its atomic mass is eighty three point seven nine eight. It has forty eight neutrons in its most sufficient
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13/12/2011 Course Title: General and Inorganic Chemistry TOPIC 3: CHEMICAL KINETICS Lecturer and contacts Mr. Vincent Madadi Department of Chemistry‚ University of Nairobi P. O. Box 30197-00100‚ Nairobi‚ Kenya Chemistry Dept. Rm 114 Tel: 4446138 ext 2185 Email: vmadadi@uonbi.ac.ke‚ madadivin2002@yahoo.com Website: http://www.uonbi.ac.ke/staff/vmadadi 12/13/2011 mov 1 Introduction • Kinetics is the study of rates of chemical reactions and the mechanisms by which they occur. • The reaction rate
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Chemical Equilibrium- Le Chatelier’s Principle; Chemistry 0993 By Amanuel asgodom For Dharinee Doobur-Choytun Partner cherry November 28‚ 2013 Purpose: To observe and record Le Chatelier’s Principle on how temperature & concentration change affects in a reaction. Apparatus and materials; See on chemistry lab manual 0993e chan henry j johnstone- g pawelchack Vancouver community college. Page 52… le chateliers principle. See the detail from the le chateliers principle
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