Organometallic preparation and addition to carbonyls‚ Wittig reagent preparation and Wittig rxn‚ Wolff‚ H-based nucleophile carbonyl reduction‚ imine formation‚ reductive amination (rxn only)‚ ketal/acetal formation‚ dithiane chemistry (rxn only)‚ alpha-bromination of ketones‚ -COOH properties (the trends on HW4)‚ Fischer‚ acidic/basic hydrolysis of esters/amides/nitriles‚ CH2N2‚ acid chloride formation (rxn only)‚ acid chloride rxns with esters and amides. 2 Rxn of carboxyllic acid derivatives
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EXPERIMENT 2: SYNTHESIS OF ORANGE II (2-NAFTHOL ORANGE OBJECTIVE 1. To produce dye based to the coupling of diazonium. 2. To understand the characteristic of dye orange II. INTRODUCTION The first dye was introduced by William Henry Perkin on 1856. It can be produced by the coupling of diazonium sulfanilic acid with nafthol in alkaline solution.. This was the common method used to produce dye nowadays. In this experiment‚ dye produced was the orange II. Azo compound is compound that contain
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|Faculty of Engineering & Science | |Unit Code |: |UEMK1013 | |Course |: |Chemical Engineering | |Unit Title |: |Chemistry for Engineering | |Year/ Semester |: |Year 1/ Trimester 1 | |Lecturer |: |Dr. Loh Han Chern | |Session |: |201101
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CHEM 301 LECTURE Unit 1 0 . COORDINATION CHEMISTRY Factors t hat affect solubility: Common ion: decrease in solubility Complex ion: increase in solubility How does complex ion formation increase solubility? Consider the complex ion formation between silver and ammonia: + Ag + 2NH3 A g(NH3 )2 + Kf = 1 .5 x 10 7 where Kf i s the formation constant (always >1 ‚ formation of the complex is highly favorable) Complex ion formation increases the solubility of sol ids in water
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Gas Chromatography (GC) Definition: Gas chromatography is a physical method of separation in which the components to be separated are distributed between two phases‚ one being a stationary bed of large surface area‚ and the other a gas that percolates through the stationary bed. When the stationary phase is a solid‚ the separation process is more precisely called gas-solid chromatography. Introduction: Gas Chromatography is a technique widely used to separate complex mixtures of substances. Compounds
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Chromatography (TLC) and Melting point. Introduction: There are only several compounds and molecules that are essential to the human body. Such molecule like D-glucose which is considers the second central substance in the maintenance and metabolite of human life after water. D-glucose is an important monosaccharide and has being subjected to many years of NMR analyses due to its anomeric properties of αand βusing deuterium1. Both anomers of D-glucose have a similar structure with a molecular formula of C6H12O6
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experimental techniques which can be used to tell us where the atoms are located in a molecule. Using advanced techniques‚ very complicated structures for proteins‚ enzymes‚ DNA‚ and RNA have been determined. Molecular geometry is associated with the chemistry of vision‚ smell and odors‚ taste‚ drug reactions and enzyme controlled reactions to name a few.
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Extraction of Aluminium Aluminium ore is called bauxite. Bauxite contains aluminium oxide‚ water‚ iron oxide and other impurities. The purified dry ore‚ called alumina‚ is aluminium oxide (Al2O3). The alumina must be molten for electrolysis to work‚ since the ions are not free to move in the solid state. Unfortunately‚ alumina has a high melting point (2040 °C) and it is not practical to do electrolysis at such a high temperature. In the middle of the nineteenth century it was found that alumina
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1 in vapour state sulphur partly exists as S2 molecule which has 2 unpaired electrons in the antibondind pi orbitals jus lyk oxygen and thus exhibits paramagnetism. 2 An interhalogen compound is a molecule whose atom contains two or more different halogen atoms (fluorine‚ chlorine‚ bromine‚ iodine or astatine). Most interhalogen compounds known are binary (composed of only two distinct elements). Their formulas are generally XYn‚ where n = 1‚ 3‚ 5 or 7‚ and X is the less electronegative
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JEET SCIENCE ACADEMY CHOWK AZAM (LAYYAH) TIME 2.5 Hr CHEMISTRY 1st YEAR CH # 1‚2‚9‚10 Marks: 85 G.Super . 1 Name…………………………………………...... Objective ROLL NO. ………………………………. Q.NO.1. Encircle the correct answer? (1×17=17) 1. Atoms of which one of the follelement have independent existance: (A) Flourine (B) Krypton (C ) Oxygen (D) Nitrogen 2.18g glucose is dissolved
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