this experiment equilibrium. Esterification is a slow and reversible reaction. The equation for the reaction between an acid RCOOH and an alcohol RẬᶦ can be the same or different; at equilibrium‚ the concentrations of both reactants and products are constant. In this experiment set up‚ the reaction between ethanoic acid and ethanol to produce ethyl ethanoate and water is a reversible reaction as shown by the following equation: CH₃COOH + CH₃CH₂OH↔CH₃COOCH₂CH₃ +H₂O The Equilibrium Law states that
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PERFORMED: JULY 20‚ 2007 SPECTROPHOTOMETRIC DETERMINATION OF EQUILIBRIUM CONSTANT FOR A REACTION ABSTRACT UV-VIS spectrophotometry is one of the most widely-used methods for determining and identifying many inorganic species. During this experiment‚ this spectrophotometry was used to determine the equilibrium constant‚ Keq‚ of the Fe3+(aq)+SCN-(aq)↔ FeSCN2+(aq) reaction. By determining the amount of light absorbed‚ the concentration of the colored FeSCN2+ solution was also quantitatively determined
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reaction and the rate of the reverse reaction equal each other. At this point‚ the concentrations do not change with time. These reactions are said to be in equilibrium. Equilibrium is depended on a particular temperature‚ and the concentrations of reactants and products have to follow a rule demonstrated by the equilibrium constant Kc. The equilibrium concentrations that will be studied is the reaction between iron (III) ion and thiocyanate ion: The mixture of Fe3+ and SCN- react to form a compound
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Experiment 19 - Determination of the equilibrium constant for the reaction Fe3+ (aq) + SCN( (aq) = FeSCN2+ (aq) Object: To determine the equilibrium constant by a colorimetric method Theory: Colorimetric methods of analysis are usually applied to the determination of small concentrations of either inorganic or organic materials in a solution. The constituent sought must be coloured or must be capable of reacting with a reagent to produce a substance having a suitable colour. Beers Law‚ which
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The Equilibrium Constant of an Ester Hydrolysis Reaction CHM 152LL Section 33263 March 28‚ 2014 John Weide Abstract: The purpose if this experiment is to determine the equilibrium constant of an unknown alcohol. In this experiment unknown alcohol number three and unknown ester number three were used. The equilibrium constant was found by titrating a series of reactions containing H2O‚ HCl‚ and the unknown ester with only the last solution containing the unknown alcohol
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Spectrophotometric Determination of the Equilibrium Constant of a Reaction DEPARTMENT OF MATERIALS‚ METALLURGICAL AND MINING ENGINEERING‚ COLLEGE OF ENGINEERING July 26‚ 2012 ------------------------------------------------- ABSTRACT ------------------------------------------------- Before proceeding to test the next solution‚ we must first clean the cuvette‚ using similar steps earlier. First‚ we rinse with water‚ then with the solution‚ and then we fill it up and test
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DATE PERFORMED: JANUARY 6‚ 2011 SPECTROPHOTOMETRIC DETERMINATION OF THE EQUILIBRIUM CONSTANT OF A REACTION ABSTRACT The objective of the experiment was to determine the equilibrium constant of the reaction forming ferric thiocyanate through the use of Spectrophotometry. For the calibration‚ five standard solutions were prepared‚ then their respective absorbance values that were obtained through the use of the spectrophotometer‚ were plotted versus the concentration of the analyte so that a calibration
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SPECTROPHOTOMETRIC DETERMINATION OF THE EQUILIBRIUM CONSTANT OF A REACTION Methodology The following stock solutions were prepared: 1.0 M HCl‚ 0.1 M HCl‚ 0.1 M KSCN‚ 0.002 M KSCN (in 0.1 M HCl)‚ 0.2 M FeCl3 (in 0.1 M HCl)‚ and 0.002 M FeCl3(in 0.1 M HCl). Using the prepared stock solutions‚ the standard (Table 1) and Unknown (Table 2) solutions were prepared. Table 2. Preparation of Standard Solutions 0.10 M KSCN 0.002 M FeCl3 0.1 M HCl Blank 2.0 ml 0.0 ml 8 ml S1 2.0 ml 0.1 ml 7
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CHM 096 TUTORIAL 2 (Chemical Equilibrium) Jan 2013 1. Write the equilibrium constant expression‚ Kc‚ for each of the following reactions: a) b) c) d) e) f) 2NO(g) + O2(g) ⇄ 2NO2(g) The decomposition of solid potassium chlorate to solid potassium chloride and oxygen gas. 4HCl(g) + O2(g) ⇄ 2H2O(g) + 2Cl2(g) 2NO2(g) + 7H2(g) ⇄ 4H2O(l) + 2NH3(g) H2O(g) + C(s) ⇄ CO(g) + H2(g) The reduction of solid copper (II) oxide with hydrogen gas to produce copper metal and water at o 500 C. 2H2(g) + O2(g)
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Chemical Equilibrium: Finding equilibrium constant‚ Kc 1 Abstract Chemical reactions are accompanied with formation of products. A reaction can be reversible or forward according to the rate of formation of product. However‚ they do not reach completion and the mixture remains in equilibrium. This theory help us the study the existence of equilibrium constant‚ Kc. This constant is temperature dependent‚ and it must be calculated at given temperature. This equilibrium constant is used
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