Determination of Equilibrium Constants Introduction Bromothymol blue is an indicator for many acid-base titrations. When adding different solutions within the indicator it is to react and change colors‚ in this experiment the different colors were blue‚ green‚ and yellow. In the following experiment‚ obtaining the absorbance levels for each one makes it possible to calculate the equilibrium constant. Materials and Methods For this specific experiment there are a few materials that are crucial
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Determination of an Equilibrium Constant Abstract: In this experiment‚ two reactions were run to determine the molar absorptivity and the equilibrium constant of FeSCN2+. The main principles used in this lab are equilibrium‚ LeChatlier’s Principle‚ Beer’s Law and Spectrocopy. The first reaction was run to completion using LeChatier’s Principle and the second reaction was run to equilibrium. A spectrophotometer was used to measure absorbances. Using a graph of absorbance versus concentration
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1 Solutions and Solubility Chapters 4+13 2 The Solution Process • A solution is a homogeneous mixture of solute (present in the smallest amount) and solvent (present in the largest amount) State of Solution State of Solvent State of Solute Example Gas Gas Gas Air Liquid Liquid Gas O2 in water Liquid Liquid Liquid Alcohol in water Liquid Liquid Solid Salt in water Solid Solid Gas H2 in Pd Solid Solid Liquid Hg in Ag Solid Solid Solid Ag in Au 3 The Solution Process
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Determination of the Rate Constant for a Chemical Reaction Department of Chemistry Abstract This experiment was performed to determine the rate constant k‚ for hydrolysis of tertiary butyl chloride to tertiary butanol. The solvent system for this reaction is 45% isopropyl alcohol and 55% water. The rate of hydrolysis of t-butyl chloride is measured by the decrease in the concentration of this reagent with time. The rate of decomposition of t-butyl chloride must be equal to the rate of formation
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reaction where the concentration of all the reactants and all the products remain constant over time. Equilibrium as used in chemical systems means that all the chemical forces in a reaction are in balance and that all physical properties of the system (color‚ density and concentration) of all chemicals species involved remains constant. The equilibrium state can be characterized by quantitatively defining its equilibrium constant‚ Keq. In this experiment the Keq for the reaction between iron (lll)
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Dioxide Solubility in Ionic Liquids Mark J. Muldoon‚† Sudhir N. V. K. Aki‚‡ Jessica L. Anderson‚ JaNeille K. Dixon‚ and Joan F. Brennecke* Department of Chemical and Biomolecular Engineering‚ UniVersity of Notre Dame‚ Notre Dame‚ Indiana 46556 ReceiVed: March 8‚ 2007; In Final Form: May 4‚ 2007 Previously we showed that CO2 could be used to extract organic molecules from ionic liquids without contamination of the ionic liquid. Consequently a number of other groups demonstrated that ionic liquid/CO2
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Mishra UMN ID Number: 4585009 The Photoelectric Effect: A Determination of Planck’s constant Ian E. Jaeger School of Physics and Astronomy‚ University of Minnesota – Twin Cities 116 Church St. S.E.‚ Minneapolis‚ MN 55455 Abstract The photoelectric effect was explored to determine an experimental value of Planck’s constant‚ h. Included is a brief introduction to the history leading up to Einstein’s discovery of the photoelectric effect as well as the theory behind it. To determine h‚ multiple
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molecules (or atoms) in a gas are separated by large distances and are in constant‚ random motion. When dealing with gases‚ the Ideal Gas Law equation is the most famous equation used to relate all the factors in dealing and solving the problem. The four factors or variables for gas are: pressure (P)‚ volume (V)‚ number of mole of gas (n)‚ and temperature (T)‚ and the constant in the equation is R‚ known as the gas constant. The Ideal Gas law equation which is pV=nRT is obtained by combining the
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Spectrophotometric Determination of an Equilibrium Constant Introduction: In this experiment‚ you will study the reaction between aqueous iron (III) nitrate‚ Fe(NO3)3‚ and potassium thiocyanate‚ KSCN. They react to produce the blood-red complex [Fe(SCN)]2+. Fe3+ + SCN- ( [Fe(SCN)]2+ The equilibrium constant expression may be expressed as: K = [pic] You will prepare a series of standard solutions that contain known concentrations of [Fe(SCN)]2+ and will determine
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affecting solubility 1. Effect of Temperature For some substances to dissolve in a given solvent‚ heat is absorbed. The reaction is endothermic. In this case‚ an increase in temperature increases solubility. For some substances‚ heat is released when they dissolve in a given solvent. The reaction is called exothermic. In this case‚ an increase in temperature decreases solubility. Generally‚ an increase in temperature in the solubility of solids in liquids increases solubility. But for solubility of gas
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