Introduction‚ aim and hypothesis Chemical reactions are accompanied by the release or absorption of energy. Reactions which release energy are described as exothermic and those which absorb energy are endothermic. The energy released in chemical reactions was previously stored as chemical potential energy in the reactants; this stored energy is called enthalpy. The aim of this practical is to observe and classify chemical processes as endothermic or exothermic‚ based on the changes in temperature
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The SN2 reaction requires three qualities: a strong nucleophile‚ a good‚ unhindered leaving group‚ and a polar‚ aprotic solvent. For our reaction‚ we have all three bases covered. The nucleophile is an alkoxide‚ a deprotonated alcohol. Technically‚ because our alcohol is a phenol‚ the conjugate base is called a phenoxide. Phenol itself has a pKa of about 10‚ but our alcohol has more resonance opportunities‚ so the pKa is down around 8. This is sufficiently acidic for use of weak base like K2CO3 for
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Grignard Reaction: Synthesis of Triphenylmethanol Hai Liu TA: Ara Austin Mondays: 11:30-2:20 Abstract: In this experiment‚ phenylmagnesium bromide‚ a Grignard reagent was synthesized from bromobenzene and magnesium strips in a diethyl ether solvent. The Grignard reagent was then converted to triphenylmethanol‚ a tertiary alcohol with HCl. The reaction for phenylmagnesium bromide was: The reaction for Grignard to triphenylmethanol was: In the formation of the Grignard reagent
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Link reaction The link reaction takes place in the mitochondrial matrix and its main function is to turn the pyruvate into acetate for the kerb cycle. During the link reaction the pyruvate molecule undergoes decarboxylation and dehydrogenation‚ the enzymes pyruvate decarboxylase and pyruvate dehydrogenase remove the carboxyl group (which becomes a carbon dioxide molecule) and removes the hydrogen atoms from the pyruvate molecule. The coenzyme NAD accepts the two hydrogen atoms and becomes reduced
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The Grignard Reaction Abstract Through the use of the Grignard reaction‚ a carbon-carbon bond was formed‚ thereby resulting in the formation of triphenylmethanol from phenyl magnesium bromide and benzophenone. A recrystallization was performed to purify the Grignard product by dissolving the product in methanol. From here‚ a melting point range of 147.0 °C to 150.8 °C was obtained. The purified product yielded an IR spectrum with major peaks of 3471.82 cm-1‚ 3060.90 cm-1‚ 1597.38 cm-1‚ and 1489
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In this laboratory voltmeters where utilized to take reading of three different electrochemical reactions: Pb/Zn‚ Pb/Cu‚ and Zn/Cu. A salt bridge was placed between two reactions containing metal strips in separate aq solutions. The salt bridge was placed in order to balance the reaction. The voltage measurements for Pb/Zn‚ Pb/Cu‚ and Zn/Cu where .595 V‚ .479 V‚ and 1.072 V accordingly. The values obtained where then used to determine the voltage value for the reduction half. The resulting cell potential
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the value of the sum for Reaction 1 and Reaction 2’s change in temperature‚ compared to Reaction 3’s change in temperature. Reaction 1 was the dissolution of solid sodium hydroxide in water with a ΔH°rxn of -47047 J/mol‚ Reaction 2 was the neutralization of liquid sodium hydroxide with HCl with a ΔH°rxn of -31289 J/mol and Reaction 3 was the dissolution and neutralization of solid NaOH with HCl with a ΔH°rxn of -91000 J/mol. Consequently‚ the sum of Reaction 1 and Reaction 2 was -78336 J/mol‚ similar
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affecting the rate of reaction‚ PNPP (p-nitrophenyl phosphate) + H20 ? PNP (p-nitrophenol) + H3P04. This reaction is catalyzed by the enzyme phosphatase. Different environments produced different reaction rates as environmental factors affect the efficiency of phosphatase. This is because environmental factors can change the tertiary structure of phosphatase‚ which alters its active site‚ and thus changes its efficiency to catalyze the reaction. We measured the rate of reaction‚ by using a chromogenic
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Examples of synthesis reactions: 1. Metal + oxygen → metal oxide EX. 2Mg(s) + O2(g) → 2MgO(s) 2. Nonmetal + oxygen → nonmetallic oxide EX. C(s) + O2(g) → CO2(g) 3. Metal oxide + water → metallic hydroxide EX. MgO(s) + H2O(l) → Mg(OH)2(s) 4. Nonmetallic oxide + water → acid EX. CO2(g) + H2O(l) → ; H2CO3(aq) 5. Metal + nonmetal → salt EX. 2 Na(s) + Cl2(g) → 2NaCl(s) 6. A few nonmetals combine with each other. EX. 2P(s) + 3Cl2(g) →
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observe how the change in solvent polarity affects the rate and to determine the kinetics of a solvolysis reaction. In this experiment‚ we used 1-chloro-1-phenylethane in acetone in one reaction with 50% ethanol-50% water and in another reaction with 40% ethanol-60% water. To monitor he rate of reaction‚ we would need the concentration of the alkyl chloride at the beginning of the reaction and at a time t‚ but since we did not determine the concentrations‚ we monitored the rate of formation of
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