0 PANJAB UNIVERSITY CHANDIGARH- 160 014 (INDIA) (Estted. under the Panjab University Act VII of 1947-enacted by the Govt. of India) FACULTY OF SCIENCE SYLLABI FOR M.Sc. (TWO YEAR COURSE ) IN CHEMISTRY 1st & 2nd YEAR( Semester System) EXAMINATIONS 2013-2014 --:O:-- 1 OUTLINES OF TESTS‚ SYLLABI AND COURSES OF READING FOR M.Sc. FIRST YEAR (SEMESTER-I) EXAMINATION OF 2013 OBJECTIVE OF THE COURSE To teach the fundamental concepts of Chemistry and their applications. The syllabus pertaining
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work as a base by abstracting a proton or it can work as a good nucleophile. When it works as a base it can be added to water‚ alcohols‚ amines‚ acids‚ terminal alkynes and etc. When it works as a nucleophile‚ its nucleophilicity reacts with the electrophilic carbon in a carbonyl group forming a new carbon-carbon bond. Grignard reagents when synthesized are very reactive and thus must be made in an environment free of water or any other potential proton donor. Thus in order to synthesize the grignard
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Nucleophilic Substitution Introduction: The purpose of this lab is to investigate how different factors affect the rate of SN1 and SN2 reactions. SN2 reactions proceed via a one step mechanism in which the incoming nucleophile attacks the electrophilic carbon center from the opposite side of the leaving group. This reaction mechanism implies that the stereochemistry of a chiral center will be inverted. SN1 reactions proceed via two steps‚ slow dissociation of the C-X bonds to form an intermediate
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Thermochemistry IB questions 1. Ammonium nitrate‚ NH4NO3‚ dissolves readily in water according to the equation: NH4NO3(s) NH4+(aq) + NO3-(aq) H = 28kJ mol-1 Which of the following contribute(s) to the occurrence of this process? I. The system moves to lower enthalpy. II. The system becomes more disordered. a. I only b. II only c. Both I and II d. Neither I nor II 2. Which substance has the largest lattice energy? a. NaF b. KCl c. MgO d. CaS 3. A certain reaction is spontaneous
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Stereochemistry of Butenedioic Acid Objective: To study the interconversion of two geometric isomers‚ maleic acid (cis isomer) to fumaric acid (trans isomers)‚ the differences in physical properties between this pair of cis-trans isomers and determine the stereochemistry of addition of bromine to butenedioic acid. Chemicals and Apparatus: 2 grams of maleic acid‚ 10 cm3 of concentrated hydrochloric acid‚ 10 cm3 of bromine water[1]‚ one 50 cm3 beaker‚ one 100 cm3 beaker‚ one 250 cm3
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A. Goal and Purpose: Session 1: In this lab‚ we will achieve a simple Friedel-Crafts alkylation of anthracene. The choice of anthracene as an aromatic substrate stems from two considerations. First‚ there is a question of regioselectivity. Second‚ anthracene and its derivatives are highly visible under UV light. Session 2: In this lab‚ we will complete a partial conversion of 9-acetylanthracene using m-chloroperoxybenzoic acid (mCPBA). We will also determine by NMR‚ the regiochemistry of the
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are underlined can absorb infrared radiation as their vibrations give rise to oscillating dipoles. 15. Classify the following reactions: a) CH3CH 3 + Br2 → CH3CH2Br + HBr Free radical substitution b) CH2=CH2 + Br2 → CH2BrCH2Br Electrophilic
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English Proficiency This test is designed to assess the test takers’ general proficiency in the use of English language as a means of self-expression in real life situations and specifically to test the test takers’ knowledge of basic grammar‚ their vocabulary‚ their ability to read fast and comprehend‚ and also their ability to apply the elements of effective writing. 1. Grammar 1. Agreement‚ Time and Tense‚ Parallel construction‚ Relative pronouns 2. Determiners‚ Prepositions‚ Modals
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macromolecules‚ only a limited number of different side-chain chemical groups are available to function as catalysts. The myriad of enzyme-catalyzed reactions results from the ability of most of these groups to function either as nucleophilic‚ electrophilic‚ or general acid–base catalysts‚ and the key to their adapted chemical function lies in their states of protonation. Ionization is determined by the intrinsic pKa of the group and the microenvironment created around the group by the protein or
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Radical Bromination) (Reacts with alkanes) Reagent: Br2 in H2O Observation: decolorization‚ brown ( colorless Procedure: 2 drops of test compound in test tube+ 1 drop 0.05 M Br2 in H2O‚ shake well‚ record observations Bromination in Dark (Electrophilic Addition Halogenation) (Reacts with alkenes) Reagent: Br2 in H2O Observation: decolorization‚ brown ( colorless Procedure: 2 drops of test compound
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