Title: Experiment 28: Nitration of Methyl Benzoate Objective: The students will learn to nitrate methyl benzoate through electrophilic aromatic substitution reaction. They will learn the importance of regiochemistry in chemical reactions. They might experience disubstitution through a high temperature. Reactions: Observation: The crystals started to form when added 2 g of crushed ice. The addition of hot methanol dissociated the crystals. The crystals reappeared when cooled down in
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BENZOIC ACID & BENZOATES (210 –218) • Retards growth of bacteria and yeasts • Occurs naturally in many foods – a similar distribution to salicylate (but at a lower dose than as an additive) • Common food sources: Soft drink‚ cordial‚ fruit juice and cider Liquid essences and syrups Iceblocks‚ jelly‚ low joule jam‚ dips‚ pickles‚ olives Fish marinades and preserves • PABA (para-amino-benzoic-acid)
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solution containing benzoic acid‚ cellulose‚ and methyl orange involves many components pertaining to the fundamental ideas of solubility and polarity. Using the concepts of like dissolving like and acid base reactions‚ a solution of organic acid (benzoic acid)‚ a water soluble compound cellulose‚ and an organic soluble compound methyl orange‚ can be separated and benzoic acid can be isolated by a method of extraction. At the fundamental level‚ organic solvents separate from aqueous solutions
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Introduction Extraction is a purification technique used in organic chemistry to separate compounds from a mixture of two or more compounds. There are three different extraction techniques: liquid-liquid extraction‚ solid-liquid extraction and chemically active extraction. All three types of extraction follow the same principle. Organic molecules dissolve in organic solvents and polar molecules dissolve in aqueous solvents. This phenomenon is observed because of the intermolecular forces between
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EXPERIMENT 2: Recrystallization and Melting Point Recrystallization (or Crystallization) is a technique used to purify solids. This procedure relies on the fact that solubility increases as temperature increases (you can dissolve more sugar in hot water than in cold water). As a hot‚ saturated solution cools‚ it becomes supersaturated and the solute precipitates (crystallizes) out. In a recrystallization procedure‚ an impure (crude) solid is dissolved in a hot solvent. As this solution is cooled
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Lab 8- nitration of Methyl I Benzonate Date of experiment: INTRODUCTION: The nitration of methyl benzoate is an example of an electrophilic aromatic substation reaction. In the experiment the electrophile was the nitronium ion and the aromatic compound was methyl benzoate and with addition of nitrating solution Methyl 3-nitrobenzoate was the product. Methyl benzoate Methyl 3-nitrobenzoate MATERIALS AND METHODOLOGY: The procedures for this experiment
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Exp’t 84 Synthesis of Methyl Benzoate by Fisher Esterification from K. L. Williamson‚ Macroscale and Microscale Organic Experiments‚ 2nd Ed. 1994‚ Houghton Mifflin‚ Boston p385 Revised 10/15/03 Prelab Exercise: Give the detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate. Introduction: The ester group is an important functional group that can be synthesized in a number of different ways. The low-molecular-weight esters have very pleasant odors and indeed are the major components
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is to practice common organic laboratory techniques inside the lab to get one oriented to the basic methods of procedure that can be used for later experiments. This experiment involves the separation of benzoic acid from a more crude form‚ consisting of benzoic acid‚ methyl orange‚ a common acid/base indicator‚ and cellulose‚ a natural polymer of glucose (Huston‚ and Liu 17-24). The technique that is used to perform this separation is called extraction. Extraction is a systematic process of separating
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Title: Nitration of Methyl Benzoate Objective: To prepare methyl-3-nitrobenzene from nitration of methyl benzoate. Results and calculations: Density = 1.094 g/ml = Mass of methyl benzoate = 1.094 g/ml x 2.8 ml = 3.0632 g no. of mol of methyl benzoate = = 0.022499 mol 1 mol of methyl benzoate produced 1 mol of methyl m-nitrobenzene. Therefore‚ 0.022499 mol of methyl benzoate produced 0.022499 mol of methl
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Nitration of Methyl Benzoate to form Methyl-m-nitrobenzoate via Aromatic Substitution Linh Ngoc Thuy Nguyen Seattle Central Community College Professor: Dr. Esmaeel Naeemi Date: February 21st‚ 2012 Abstract In this experiment‚ methyl-m-nitrobenzoate‚ followed the electrophilic addition of aromatic ring‚ would be formed from the starting material methyl benzoate and nitric acid‚ under the catalysis of concentrated sulfuric acid. The reaction between nitric acid and sulfuric acid resulted in
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