catalyst free reaction by stirring reaction mixture of a and b in ethanol at room temperature. Additionally‚ several reactions were performed using various catalysts in different reaction conditions and results are summarized in Table 1. The catalyst free reaction fails to produce selective benzimidazole and conversion of reactants in long reaction time and obtained only 21 % conversion with 13 % selective yield of c after 48 h reaction time (Table I‚ Entry 1). Later on‚ the same reaction performed at
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Lab Techniques & Measurements Pre Lab Questions: (4pts) 1. What will you learn after completing the lab? -The experiment will introduce different level of precision and measuring to the appropriate decimal place and will be familiar with measurements and weight. 2. Write the symbols and equation used to make a dilute solution from concentrated or stock solution. - The concentration of substance is described as molarity and this can be expressed as – Molarity
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affecting the rate of reaction‚ PNPP (p-nitrophenyl phosphate) + H20 ? PNP (p-nitrophenol) + H3P04. This reaction is catalyzed by the enzyme phosphatase. Different environments produced different reaction rates as environmental factors affect the efficiency of phosphatase. This is because environmental factors can change the tertiary structure of phosphatase‚ which alters its active site‚ and thus changes its efficiency to catalyze the reaction. We measured the rate of reaction‚ by using a chromogenic
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Replacement Reactions (Data and Calculations) Objective: Classify the chemical reaction through observation‚ which each reagent produce when mixed with another reagent. After careful observation‚ be able to prove each observation using the net ionic equation. Background: First‚ a double-replacement reaction is when two cations in different compound switch anions‚ AX + BZ → BY. If either compounds are insoluble a precipitate occurs‚ and if there is no precipitate formed there is no reaction. Also‚
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Experiment 5: Shifting Equilibrium A solution is in equilibrium when the rate of forward reaction and the rate of reverse reaction are equal. This equilibrium may be disturbed when the concentration of the reactants‚ the concentration of the products or the temperature is changed. If the process involves gases‚ a change in pressure can also affect the position of equilibrium. The concept behind this is Le Chatelier ’s Principle which states that when a system is disturbed through application
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EXPERIMENT # 14: Exothermic and endothermic reactions Date: 25/06/2012 Name: Meagen Reyes Year 11 PARTS A‚ B and C * For the procedures and equipment needed in these experiments‚ refer to page 73-74 in the STAWA Exploring chemistry stage 2 book Part A: solution process (dissociation) Solutions and their chemical equations | Initial temperature (in Celsius) | Final temperature (in Celsius) | Classification(exothermic or endothermic) | Sodium hydroxide NaOH(s) Na+(aq) + OH-(aq) + Energy
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If pH > pI‚ then the protein will have a negative charge and if pH < pI‚ the protein will have a positive charge. Buffer I has a pH >5‚ meaning both proteins carry a negative charge and bind to the DEAE (a positively charged resin). (b) pH = pKa + log10(Base/Acid) [Base = mM of sodium acetate; Acid = mM of acetic acid] = 4.7 + log10 (40/40) = 4.7 In order for the catalase to elute from the column‚ it must have lost its negative charge and stopped binding to the DEAE. Lowering the pH
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Introduction DNA‚ or deoxyribonucleic acid‚ is a double stranded helical structure used to store genetic information in cellular organisms. DNA usually consists of two strands made up of nucleotides‚ each with a backbone of repeating units of phosphate groups and the sugar‚ deoxyribose‚ bonded by phosphodiester linkages. Since the deoxyribose has a specific orientation‚ DNA molecules have directionality so that DNA sequences are read 5’ to 3’. The 5’ end of DNA is characterized by the deoxyribose
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Title: Study of Solubility Equilibrium Abstract The effect of temperature on the solubility product constant‚ Ksp‚ of potassium hydrogen tartrate in water was investigated in the temperature range of 285K to 318K at normal atmospheric pressure. It was found that the solubility of potassium hydrogen tartrate decreases with a decrease in temperature and consequently a smaller volume of sodium hydroxide is needed to neutralize it. The molar solubility of potassium hydrogen tartrate was calculated
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Purpose Determine which kinds of reactions involve electron transfer as the driving force. Background Redox (reduction-oxidation) reactions include all chemical reactions in which atoms have their oxidation state changed. So‚ when a metal and a nonmetal react‚ there is an ionic bond formed‚ which means one of them loses electrons while the other gains them. Since this reaction involves the exchange of electrons it is termed as a redox reaction. The oxidation states in a metal- nonmetal are simple
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