Heat of Combustion of Magnesium Background: The students were given full instructions on how to experimentally determine the enthalpy of reaction (ΔHrxn) for the combustion of magnesium ribbon‚ using Hess’s Law. Data Collection: | |Reaction 1 |Reaction 2 | | |(MgO) |(Mg)
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of 1 gram? 1 mole? (heat capacity = 11.66 kJ/C) Thermochemistry 1. What is the heat capacity of mercury if it requires 167 J to change the termperature of 15.0 g mercury from 25.0 oC to 33.0 o C? 2. Consider the reaction: C2H5OH (l) + 3O2 (g) 2CO2 (g) + H2O H = -1.37 x 103 kJ When a 15.1 g sample of ethanol is burned‚ how much energy is released as heat? 3. When 0.157 mole NH3 is reacted with excess HCl‚ 6.91 kJ of energy is released as heat. What is the
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(NH4)2CO3 Oxide All oxide not dissolve in water except; Na2O ‚ K2O ‚ CaO Hydroxide All hydroxide not dissolve in water except; NaOH‚ KOH‚ Ca(OH)2 ‚ Ba(OH)2 Formula to determine the heat change; Heat released/absorbed‚ H = mcӨ [unit = J or kJ] Symbol Description Unit m mass of solution 1cm3 = 1 g c specific heat capacity of solution 4.2 J g-1 oC-1 Ө temperature change oC To determine precipitation heat of silver chloride‚ AgCl In this experiment you must have the following
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been proceeding. The end result is solid magnesium oxide in the form of “white ball” and carbon solid in the form of coal. These products indicated that the coupling of the first two reactions was spontaneous with the theoretical value of ∆G= -372.2 kJ/mol. ------------------------------------------------- Introduction Coupled reactions are very essential in our daily lives. One example of a coupled reaction is the metabolism of glucose (C6H12O6) that converts adenosine diphosphate (ADP)
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= 241.8 kJ (a) Sketch the energy profile diagram of the above reaction. (b) Which enthalpy is larger‚ that of the reactants or the product? (c) For the reaction‚ 2H2O(g) 2H2(g) + O2(g) what is the enthalpy change under the same conditions? 4. (a) The following reaction occurs at room temperature and pressure: 2Cl(g) Cl2(g) ΔH = -ve State which has higher enthalpy under this condition‚ Cl(g) or Cl2(g)? 5. From the following data‚ 2Fe(s) + 3 2 O2(g) ΔHf = 822.2 kJ mol1
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SCH4U UNIT 3: Thermochemistry Assignment May 2‚ 2011 1. Upon the addition of potassium nitrate to liquid water‚ the beaker feels cold. Explain‚ using appropriate terms: system‚ surroundings‚ heat‚ temperature‚ endothermic or exothermic. The endothermic process whereby the system of KNO3 crystals dissolving in the water absorb energy from the surroundings and the measured temperature of the surroundings (beaker‚ air) drops. 2. The phase change from
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Hess’s Law and the Molar Enthalpy of Combustion for Magnesium Purpose: The purpose of the lab ultimately is to find the molar enthalpy of magnesium. This is done by finding the enthalpy changes of reactions (2) and (3). The enthalpy changes of reactions (2) and (3) along with the enthalpy change given for reaction (4) can be used to arrive at a value of the molar enthalpy of combustion of magnesium by using Hess’s Law. Hypothesis: By using Hess’s law to calculate the molar enthalpy of combustion
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Experiment 1 Calorimetry Chem 17 Univerity of the Philippines Diliman Discussion All chemical reactions involve energy. By understanding the behavior and connection of energy flow within a chemical reaction‚ we can understand and manipulate them to our advantage. The most common form of energy observed during chemical reactions is heat. The reaction may absorb (endothermic) or release (exothermic) heat‚ depending on the reacting substances. Calorimetry is the process of measuring the heat flow
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Coupled Reactions Louella Rose E. Tan‚ Frances May L. Coralde Institute of Chemistry‚ University of the Philippines‚ Diliman‚ Quezon City 1101 Philippines Results and Discussion A combustion reaction is a reaction that liberates heat and light. Magnesium is a stable element and reacts violently with evolution of much heat and light. The reason the magnesium burned in carbon dioxide was because it combined with the oxygen in the CO2 leaving elemental carbon behind. CO2(g) C(S) + O2(g)
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the reaction) Examples: (1) Calibration of the calorimeter given that: ΔHrxn = -55.8 kJ/mol and nLR = 0.005 mol qrxn = ΔHrxn x nlimiting reagent qrxn = -55.8 [kJ/mol] x 0.005 [mol] = -279 J qcal = -(219 J) = 279 J (2) Determining the qrxn of a given chemical reaction: NH3 (aq) + H+ (aq) NH4+ (aq) And given that: ΔT = 3.5 °C and Ccal=111.6 J/°C qrxn = - Ccal ΔT + mcsolid ΔT qrxn = -( 111.6 [kJ/°C] x 3.5 [°C]) = -390.6 J qcal = -(-390.6 J) = 390.6 Determining the Ccal. Ccal = qcal
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