with a rate equation based on autocatalysis by total products. The values of rate constants and activation energy were determined. Recognising the fact that the industrial route to cyclohexene from benzene hydrogenation yields a mixture of cyclohexene and cyclohexane which are di$cult to separate‚ some experiments on oxidation of the mixture of cyclohexene and cyclohexane were also conducted. The values of rate constants remain unchanged in the presence of cyclohexane. The reaction was also studied
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being kept at a constant level. Every buffer that is made has a certain buffer capacity‚ and buffer range. The buffer capacity is the amount of acid or base that can be added before the pH begins to change significantly. It can also be defined as the quantity of strong acid or base that must be added to change the pH of one liter of solution by one pH unit. The buffer range is the pH range where a buffer effectively neutralizes added acids and bases‚ while maintaining a relatively constant pH. The pH
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determine the constant equilibrium of an acid‚ Ka? How to evaluate the concentration (M) of an acid? In “part A” experiment‚ we would test the PH of different concentration of acetic acid (a weak acid which partially dissociated in water) with a PH probe. After we got the PH‚ we could find out the concentration of H+ by applying the relationship pH = -log [H+]. Having the determined value of [H+] of a weak acid with a known molar concentration [HA]‚ The acid dissociation constant‚ Ka‚ can be determined
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Chemical Analysis’ Review: Pure water has a pH = 7 Autodissociation: H2O (( H3O+ + OH- K = [H3O+][OH-]/[H2O] -log[H3O+] = 7 [H3O+] = 10-7 M = [OH-] [H2O] = 55.56 M K = 1.8 x 10-16 ; pKa = 15.74 pKa is the acid dissociation constant; low pKa (strong acid‚ high pKa (weak acid we can also write Kw = [H3O+][OH-] Kw = 10-14 In water‚ pH + pOH = 14 pH scale Strong Acids: Complete dissociation of the acid in water: HA (
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Experiment 1: "A cis to trans conversion" Saturday‚ June 25‚ 2005 4:19 PM Notes on Theory • Alkenes o They are hydrocarbons with a C=C double bond • Double bonds are stronger and more reactive than single bonds o Hydrocarbons with double bonds used to be known as "olefins"‚ because they had an oily appearance • "Oleum" means oil • "Ficare" means make • Isomers o Geometric isomers have the same molecular formula‚ but a different geometric arrangement • They also have different physical properties
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Application of linear algebraic equation for chemical engineering problem The chemical engineering system models often outcome of set of linear algebraic equations. These problems may range in complexity from a set of two simultaneous linear algebraic equations to a set involving 1000 or even 10‚000 equations. The solution of a set two or three linear algebraic equations can be obtained easily by the algebraic elimination of variables or by the application of cramer’s rule. However for systems involving
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Experiment #6: Colorimetric Determination of pH Almira‚ Faerie Carleen Lucile L. Gallardo‚ Charlotte O. Group #6‚ Chemistry 18.1‚ MHEG1‚ Ma’am Arlou Angeles September 23‚ 2013 I. Abstract The acidity of the four unknown solutions were determined with the use of colorimetry using McIlvaine’s buffer solutions varying in proportion of its constituents (disodium phosphate and citric acid). These buffer solutions were subjected to the addition of corresponding pH indicators and the variation of
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ACID/BASE You might need to know the following K values: CH3COOH Ka = 1.8 x 10–5 Benzoic Acid Ka = 6.5 x 10–5 HNO2 Ka = 4.5 x 10–4 NH3 Kb = 1.8 x 10–5 HF Ka = 7.2 x 10–4 H2S Ka = 5.7 x 10–8 HSO4– Ka = 1.2 x 10–2 HS– Ka = 1.2 x 10–13 HCOOH Ka = 1.8 x 10–4 HOCl Ka = 3.0 x 10–8 SIMPLE ACIDS AND BASES 1. According to the Brønsted–Lowry definition‚ which species can function both as an acid and as a base? (A) Cl– (B) SO42– (C) NH4+ (D) HCO3– (E) H3O+ 2. Which of the following
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Stephen G. Abelada BS ChE IV Date Submitted: January 4‚ 2012 ChE 171 Assignment 1. Essential and Non-essential Amino acids Amino acids are organic compounds which contain both an amino group and a carboxyl group and may be divided into two groups basing on whether they are produced internally by the human body or not: essential and non-essential amino acids (hyperphysics.phy-astr.gsu.edu‚ 2012). An essential amino acid (indispensable amino acid) is an amino
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Research Question: To investigate how varying the pH of bromothymol blue affects the absorbance value of the solution which determines the equilibrium constant (pKa) of the indicator. Variables: Variables Variables Measured Method of measurement Independent pH of the six buffer solution A pH probe attached to a data-logger will be used to measure pH Dependent Absorption of the buffer solutions at wavelength 435.0nm and 617.0 nm A spectrophotometer (±0.001) will be used to measure absorbance
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