Monosaccharides Trioses Glyceraldyhyde‚ dihydroxyacetone Pentoses Ribose‚ ribulose Hexoses Glucose‚ galactose‚ mannose‚ fructose Dr. Jeelan Moghraby Termed according to location of oxidized functional group; aldose if aldehyde‚ and ketose if ketone Ketose named after the equivalent aldose; with addition of ‘ul’ Dr. Jeelan Moghraby Monosaccharides are Chiral Stereoisomers around asymmetric carbon Enantiomers are isomers that are mirror images of each
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Use this packet and your book to answer the questions throughout this packet. Organic Nomenclature - Alkanes‚ Alkenes‚ Alkynes Naming organic compounds can be a challenge to any chemist at any level. Historically‚ chemists developed names for new compounds without any systematic guidelines. In this century‚ the need for standardization was recognized. For simple molecules‚ the nomenclature system worked out by the International Union of Pure and Applied Chemists (IUPAC) works well. For complex
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Chapter 7: Carbohydrates I. Carbohydrates A. Most abundant organic molecule in nature a) 3 major classes: Monosaccharides – simple sugar – polyhydroxy aldehyde or ketone; represent individual sugar Oligosaccharides – consist of short chains of monosaccharide units joined together by covalent bonds; 2-10 strings of sugar Polysaccharides – long chains having hundreds or thousands of monosaccharide units b) Functions: Provide energy thru oxidation – glucose oxidized for energy Supply carbon
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Module II Lecture 14 Reduction Reactions 2.1.1 Lithium Aluminum Hydride (LAH) 2.1.1.1 Introduction Lithium aluminum hydride (LAH) is a strong reducing agent with chemical formula LiAlH4. It can reduce a variety of functional groups such as aldehydes‚ esters‚ acids‚ ketones‚ nitriles‚ epoxides and azides. It vigorously reacts with water and all the reactions are performed in polar aprotic solvents. 2.1.1.2 Preparation It was first prepared by treating lithium hydride (LiH) with aluminum chloride
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Classification for Functional Groups Alcohols Lucas test (Differentiates primary‚ secondary‚ and tertiary alcohols) Reagent: ZnCl2 in conc. HCl Observation: Rate of reaction (tertiary alcohol> secondary alcohol> primary alcohol) Procedure: 2mL Lucas Reagent in test tube+ 3-4 drops of alcohol‚ stopper‚ shake vigorously‚ NOTE time required (less than 10m mins only) to form an emulsion or separate layers. Oxidation (Confirms if alcohol is oxidizable: presence of H in C-OH bond) Reagent:
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Abstract: The targeted trisubstituted ethylene compound Butyl 2-Cyano-(3‚5 dichloro-phenyl)-2-propenoate and its copolymer with styrene was prepared in this lab. The base catalyzed Knoevengael condensation of butyl cyanoacetate and corresponding aldehyde led to the forming Butyl 2-Cyano-(3‚5 dichloro-phenyl)-2-propenoate. The analyses that were used to prove its composition and structure include; IR spectroscopy‚ thin layer chromatography (TLC)‚ and CHN analysis. A radical copolymerization reaction
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Abstract Pyrorle-2-aldehyde and 1‚3-diaminopropane react under reflux to form a transition metal ion of Nickel(II)‚ that further more react with nickel acetate to form red crystals through condensation‚ the colour being constituded by the congugated bonds. These series of reactions synthesize the Schiff Base ligand and Nickel(II) complex of the Schiff base ligand. 0.36g of the Schiff base ligand is yielded and 0.1g of the nickel complex is yielded from the 0.36g Schiff base ligand and 0.5g nickel
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nucleophiles and electrophiles Presence of C=O TEST FOR ALDEHYDES AND KETONES - - Reaction with 2‚4-DNP (Dinitrophenylhydrazine) Positive: Formation of yellow precipitate IODOFORM TEST - Carbonyl compounds: Methyl ketones will give a positive result Postive: Yellow precipitate (CHI3) MOLISCH’S TEST for carbohydrates - TOLLEN’S TEST – for aldehydes - - Test for easily oxidizable compounds (ex. Aldehydes) Positive: Silver mirror deposit - - Polyhydroxyaldehydes
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CHAPTER ONE 1.0 INTRODUCTION Starch is one of the most abundant substances in nature‚ a renewable and almost unlimited resource. Starch is produced from grain or root crops. It is mainly used as food‚ but is also readily converted chemically‚ physically and biologically into many useful products to date; starch is used to produce such diverse products as food‚ paper‚ textiles‚ adhesives‚ beverages; confectioning‚ pharmaceuticals‚ and building materials. Cassava starch has many remarkable characteristics
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Since the Grignard reagent can easily react with water‚ all glassware including the 25 ml round bottom flask‚ magnetic stir bar‚ 3 and 5 ml conical vial‚ 50 mL Erlenmeyer flask‚ claisen adapter‚ drying tube and 5 glass pasteur pipets were first added to a 250mL beaker and placed in the oven for 30 minutes. After the completion of the thirty minutes‚ 0.150 g of shiny magnesium turnings and a stir bar was first added to the round bottom flask and the claisen adapter along with the drying tube packed
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