“greener” compared to the original bromination procedures. In order to create the alkyl halides‚ which are able to undergo chemical transformations more readily than the carbon-carbon double bond‚ onto the trans-stilbene the addition process of halogenation in needed. The typical reagents that are used‚ such as elemental bromine and liquid bromine‚ are dangerous and highly corrosive‚ so this experiment used an alternative method of bromination.
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CONCEPTS IN ORGANIC CHEMISTRY • Inductive Effect : Inductive effect is defined as permanent displacement of shared electron pair in a carbon chain towards more electronegative atom or group. Types of Inductive effect : 1.Negative Inductive Effect : (—I effect‚ Electron withdrawing effect) when an electronegative atom or group (more electro negative than hydrogen)is attached to the terminal of the carbon chain in a compound‚ the electrons are displaced in the direction of the attached
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Lab: Comparison of Three Isomers of Butanol Pre-lab: 1. Write the general reaction of an alcohol and HCl. 2. What would the solubility be of an alcohol in water. 3. What would the solubility be of an alkyl halide in water? 4. What is the purpose of KMnO4 in the reactions? Safety: Concentrated hydrochloric acid is corrosive and the vapour is very irritating to the respiratory system. Avoid contact with skin‚ eyes‚ clothing‚ and the lab bench. Wear eye protection and a lab apron.
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ORGANIC CHEMISTRY Carbon atoms: * Carbon-carbon bonds are not easily broken * Each carbon atom forms 4 covalent bonds * The C-H bond is almost non-polar Classifying organic compounds: * Number of carbon atoms in longest chain: meth‚ eth‚ prop‚ but‚ pent‚ hex‚ hept‚ oct‚ non‚ dec * If it is a branch: -yl; di‚ tri or tetra means there is more than one branch‚ ethyl means there are 2 carbons coming off the branch * If it is a ring of carbons put cyclo at the front of the
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163 CHAPTER 13 HYDROCARBON Hydrocarbons are composed of Carbon and hydrogen. The important fuels like Petrol‚ kerosene‚ coal gas‚ CNG‚ LPG etc. are all hydrocarbons or their mixture. Sources: Petroleum and natural gas are the major sources of aliphatic hydrocarbon while coal is an important source of aromatic hydrocarbons. The oil trapped inside the rocks is known as petroleum. PETRA – ROCK‚ OLEUM – OIL. The oil in the petroleum field is covered with a gaseous mixture known as natural
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UNIVERSITI MALAYSIA SABAH SCHOOL OF FOOD SCIENCE & NUTRITION LABORATORY REPORT NT20903 FOOD CHEMISTRY AND BIOCHEMISTRY Determination of free fatty acid(FFA) and iodine value (IV)in oil LECTURER NAME : MOHD NAZRI BIN ABDUL RAHMAN LAB SESSION : 3 OCTOBER 2011 (GROUP 4‚ MONDAY) Group Member Title: Determination of free fatty acid (FFA) in oil and determination of iodine value (IV) in oil Introduction Acid value or free fatty acid content is an important characteristic commonly
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Chemistry (the etymology of the word has been much disputed)[1] is the science of matter and the changes it undergoes. The science of matter is also addressed by physics‚ but while physics takes a more general and fundamental approach‚ chemistry is more specialized‚ being concerned with the composition‚ behavior (or reaction)‚ structure‚ and properties of matter‚ as well as the changes it undergoes during chemical reactions.[2] It is a physical science which studies various substances‚ atoms‚ molecules
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SYNT 0719 – Brominating Alkenes OBJECTIVE The purpose of this lab will be to brominate trans-stilbene by using acetic acid and pyrimidium tribromide by refluxing the mixture. To test the purity of product I will take the melting point which should be around 240 ºC along with a flame test which should be green-blue. CHEMICAL PROPERTIES TABLE See Attached Lab Notebook Copies REACTION MECHANISM In this lab we used multiple techniques to complete and verify the bromination of trans-stilbene
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reaction is when the pi bond of a molecule is removed to make two covalent bonds that are bonded to two new molecules. A nucleophillic addition is a reaction that removed the pi bond from a molecule and adds covalent bonds with two new compounds. Halogenation or most commonly known as bromination is a reaction that breaks a pi bond and adds a halogen or in this case‚ a bromine to the molecule. This addition of the bromine can be very steroselective. Stereoselectivity can come from steric and electronic
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In the IUPAC system of nomenclature‚ functional groups are normally designated in one of two ways. The presence of the function may be indicated by a characteristic suffix and a location number. This is common for the carbon-carbon double and triple bonds which have the respective suffixes ene and yne. Halogens‚ on the other hand‚ do not have a suffix and are named as substituents‚ for example: (CH3)2C=CHCHClCH3 is 4-chloro-2-methyl-2-pentene. If you are uncertain about the IUPAC rules for nomenclature
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