2013 “Reaction Classes and Pericyclic Reactions” ● 4 Lectures ● Recommended Texts: (i) J. March “Advanced Organic Chemistry”‚ p 839‚ `---Edn.‚ Oxford (W); Warren (2) Ch 34‚ 35. Syllabus 1) General principles (a) Reaction classes (i) Heterolytic (ii) Homolytic (iii) Pericyclic (b) Pericyclic Reaction Types 2) Electrocyclic Reactions (a) Definition and examples (b) Stereochemical aspects and the Woodward and Hoffmann rules 3) Cycloaddition Reactions (a) Definition
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Name: Cindy Nguyen Date: 7/11/12 Classifying Acids and Bases Purpose: To observe the typical properties of acids and bases. Hypothesis: The typical properties of acids are identical to the typical properties of bases. Materials: * * Goggles * Well plate * 2 strips of magnesium ribbon * Sodium hydrogen carbonate (baking soda)‚ NAHCO3 * Red litmus paper * Blue litmus paper * Conductivity tester * Beakers of: * Tap water * Dilute
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energy and heat associated with chemical reactions and/or physical transformations. A reaction may release or absorb energy‚ and a phase may change‚ such as in melting and boiling. Thermochemistry focuses on these energy changes‚ particularly on the system ’s energy exchange with its surroundings. In combination with entropy determinations‚ it is used to predict whether a reaction is spontaneous or non-spontaneous‚ favourable or unfavourable. Chemical reactions can be divided into two based on the
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18.1.4 – 18.1.6 CALCULATIONS INVOLVING ACIDS AND BASES Review of Important formulas pH = ‐ log10[H+] [H+] = 10‐pH pKa = ‐ log10 Ka Ka = 10‐pKa pOH = ‐ log10[OH‐] [OH‐] = 10‐pOH pKb = ‐ log10 Kb Kb = 10‐pKb The ionic product of water = Kw = [H+] x [OH‐] = 1.0 x 10‐14 mol2 dm‐6 at 298 K The expression varies with temperature
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Chemical Reactions Lab Report Introduction: Chemical reactions is a process that involves rearrangement of the molecular or ionic structure of a substance. There are different types of reaction such synthesis‚ decomposition‚ single replacement‚ double replacement‚ and combustion. Synthesis is where two or more reactants combine to create a product. For Decomposition‚ it is the opposite where a product breaks down into reactants. In Single Replacement‚ reactants switches an element with another element
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Flowers and Acid Call them freaks‚ the underground‚ the counterculture‚ flower children‚ or just simply hippies‚ they are all loose labels for the youth culture of the 60’s that transformed life in the West as we knew it‚ introducing the spirit of freedom‚ of hope‚ of happiness‚ of change‚ and of revolution (Miles 9). The years that made up the 1960’s were some of the most exciting and turbulent years in American history. The post World War II baby boomers grew up. A president and
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find the rate equation of the reaction of hydrogen peroxide and iodide ions. This will be achieved by using an iodine clock method and colorimetric analysis. 2. Draw a graph of rate against concentration for each reactant (Hydrogen peroxide‚ potassium iodide and H+ ions). 3. Finding the order for each reactant 4. Finding the rate-determining step. 5. Proposing a mechanism for the reaction. 6. Using Arrhenius’ equation to find the activation enthalpy. Background The basic reaction for this
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August 28‚ 2009 [PROBLEM SET FROM R. CHANG TEST BANK] Chapter 16 Acid-Base Equilibria and Solubility Equilibria Student: ___________________________________________________________________________ NOTE: A table of ionization constants and Ka’s is required to work some of the problems in this chapter. 1. In which one of the following solutions will acetic acid have the greatest percent ionization? A. B. C. D. 2. Which one of the following is a buffer solution? A. B. C. D. E. 3. 0.40 M HCN and
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Reaction on Reaction Paper The first thing that came to my mind when I have heard about Reaction paper is “What exactly is it?” and before I get an understanding of that‚ I resisted that change. But later‚ when I have studied about it and understood its purpose‚ I have started thinking “Why people avoid change at the first look without an analysis?” The general human tendency is to live in a comfortable zone in which he has lived for quite some time. He draws a circle‚ thinks that circle is his
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MEMORANDUM From: To: Subject: Calcium Chloride Best Purchase for Deicing Enclosures: (1) Data Record (2) Data Treatment (3) Environment Impact Research After hours of vigorous examination‚ we have come to the conclusion that calcium chloride (CaCl2) would be the best deicer to use on a naval base over sodium chloride (NaCl) and ethylene glycol (C2H6O2). In order to melt ice‚ deicers lower the freezing point so that the ice melts at lower temperatures. CaCl2 has
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