The change in entropy is situation to the heat transfer at constant pressure. Enthalpy is a state function. Usually enthalpy change calculated in relationships of internal energy change and pressure- volume correlation. ∆H= ∆E+ ∆(PV) Spontaneity of the reaction. The standard for predicting spontaneity is founded on ΔG‚ the change in G‚ at constant temperature and pressure. If ΔG < 0‚ the process happens spontaneously
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The Enthalpy Change of the Decomposition of Calcium Carbonate _INTRODUCTION_ RESEARCH QUESTION: What is the enthalpy change of the decomposition of calcium carbonate? BACKGROUND: Enthalpy in chemistry can be thought of as the energy contained within the bonds‚ or the internal energy‚ but it is not heat and you can only measure changes in it. When bond bonds break in the reactants energy is given off‚ when bonds form‚ energy is absorbed. If the energy absorbed is less than the energy released
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Enthalpy of Displacement IB Topic: Energetics Assessment Criteria: DCP‚ CE DATA COLLECTION AND PROCESSING ASPECT MARKS AWARDED Recording raw data: Processing raw data: Presenting Proceeded data: TOTAL: CONCLUSION AND EVALUATION Conclusion Evaluation Improving the procedure TOTAL AIM: Experimentally determine the enthalpy change of the displacement reaction between zinc and copper sulphate. Zn (s) + CuSO4 (aq) Cu (s) + ZnSO4
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Design an experiment to investigate the stoichiometric mole ratio of a chemical reaction. Present your data in terms of the mass of one reactant compared to the mass of one product. Purpose: The experiment will be designed to find out the stoichiometric mole ratio of Barium Chloride and Silver Nitrate yielding a precipitate of Silver Chloride in a Barium Nitrate solution. (BaCl2 + 2AgNO3 -> Ba(NO3)2 + 2AgCl) Research Question: How will the amount of Barium Chloride and Silver Nitrate
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CALCULATIONS Determining the amount Limiting Reagent used. nlimiting reagent = Molarity x Volume or Mass / Molar Mass Example: Limiting reagent is 5mL of 1.0 M HCl nlimiting reagent = Molarity x Volume nlimiting reagent = (1.0 [mol/L]) x 0.005 [L]) = 0.005 mol Determining the qrxn and qcal. qrxn + qcal = 0 -qrxn = qcal qrxn = ΔHrxn x nlimiting reagent qcal = Ccal ΔT qrxn = - Ccal ΔT + mcsolid ΔT (note: only if there is a precipitate formed in the reaction)
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Data and Observations: Part I Table: Metal: | Aluminum | Zinc | Iron | Copper | Mass of metal: | 27.776 g | 41.664 g | 34.720 g | 41.664 g | Volume of water in the calorimeter: | 26.0 mL | 26.0 mL | 26.0 mL | 26.0 mL | Initial temperature of water in calorimeter: | 25.3 °C | 25.3 °C | 25.3 °C | 25.3 °C | Temperature of hot water and metal in hot water bath: | 100.5 °C | 100.5 °C | 100.5 °C | 100.5 °C | Final temperature reached in the calorimeter: | 38.9 °C | 34.8 °C | 34.2 °C | 34
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Calorimetry and Specific Heat Tessa Williams Chemistry 111 11/13/13 Abstract: In this experiment‚ the specific heat and the density of an unknown metal was determined in order to identify the unknown metal. The average specific heat of the unknown metal was 0.197˚C and was determined using a calorimeter. The density of the unknown metal was 6.57 g/mL and was determined using a cylinder and displacement. Using the specific heat value of the unknown metal and its density‚ it
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automatic titration device from Titralabs. The main issue with the volume used for the titrations is that the color change is highly subjective and may change by several mL between partners. These small variations can cause further changes in the calculations later on and could potentially change the results obtained. The automated titration devices use light sensors to notice the change in wavelength in the solution at a given temperature and will thus stop pouring the titrant into the solution when
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CHEMISTRY IA: Processing CALORIMETRY QUANTITATIVE DATA TAKEN (07.05.14 and 21.15.14) Initial Pringle Mass H20 Amount Final Pringle Mass Δ Pringle Mass Initial H2O Temp (± 0.5°C) Max H2O Temp (± 0.5°C) Δ H2O Temp (± 0.5°C) SAMPLE 1 10g 225mL 1.85g 10g-1.85g=8.85g 22.3°C 59.8°C 37.5°C SAMPLE 2 10g 225mL 0.95g 10g-0.95g=9.05g 21°C 61.1°C 40.1°C SAMPLE 3 10g 225mL 1.95g 10g-1.95g=8.05g 23°C 58°C 35°C SAMPLE 4 10g 225mL 1.85g 10g-1.85g=8.15g 50.5°C 83°C
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Experiment 3: Resonance Energy of Naphthalene by Bomb Calorimetry Cameron Fowler CHEM 457: Lab Section 4 Submitted: 11/4/10 Lab Group #3: Michael Hyle Neil Baranik Tim Riley Abstract: The enthalpy of combustion of naphthalene was experimentally determined to be -5030.44 ± 78.98 kJ/mol which was a 2.5% error from the literature value of -5160 ± 20 kJ/mol.2 The theoretical enthalpy of combustion of solid naphthalene was calculated to be -6862.68 kJ/mol using bond energies for the gaseous
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