CHEM 301 LECTURE Unit 1 0 . COORDINATION CHEMISTRY Factors t hat affect solubility: Common ion: decrease in solubility Complex ion: increase in solubility How does complex ion formation increase solubility? Consider the complex ion formation between silver and ammonia: + Ag + 2NH3 A g(NH3 )2 + Kf = 1 .5 x 10 7 where Kf i s the formation constant (always >1 ‚ formation of the complex is highly favorable) Complex ion formation increases the solubility of sol ids in water
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experimental techniques which can be used to tell us where the atoms are located in a molecule. Using advanced techniques‚ very complicated structures for proteins‚ enzymes‚ DNA‚ and RNA have been determined. Molecular geometry is associated with the chemistry of vision‚ smell and odors‚ taste‚ drug reactions and enzyme controlled reactions to name a few.
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Extraction of Aluminium Aluminium ore is called bauxite. Bauxite contains aluminium oxide‚ water‚ iron oxide and other impurities. The purified dry ore‚ called alumina‚ is aluminium oxide (Al2O3). The alumina must be molten for electrolysis to work‚ since the ions are not free to move in the solid state. Unfortunately‚ alumina has a high melting point (2040 °C) and it is not practical to do electrolysis at such a high temperature. In the middle of the nineteenth century it was found that alumina
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1 in vapour state sulphur partly exists as S2 molecule which has 2 unpaired electrons in the antibondind pi orbitals jus lyk oxygen and thus exhibits paramagnetism. 2 An interhalogen compound is a molecule whose atom contains two or more different halogen atoms (fluorine‚ chlorine‚ bromine‚ iodine or astatine). Most interhalogen compounds known are binary (composed of only two distinct elements). Their formulas are generally XYn‚ where n = 1‚ 3‚ 5 or 7‚ and X is the less electronegative
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carbon is toxic‚ targets liver and kidneys 4. Do not breathe any chemical‚ or get on skin 5. 12M HCl highly corrosive 6. All parts of experiment done under hood Experimental The procedure for this experiment appears on pages 4 and 5 on hand lab #6 Preparation of 2-chloro-2-methylbutane-An Sn1 Reaction [1]. In this experiment‚ the instructor requested that 4 ml diethyl ether be added to the solution in the conical vial after step 4 to help better see the difference between the organic and aqueous
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JEET SCIENCE ACADEMY CHOWK AZAM (LAYYAH) TIME 2.5 Hr CHEMISTRY 1st YEAR CH # 1‚2‚9‚10 Marks: 85 G.Super . 1 Name…………………………………………...... Objective ROLL NO. ………………………………. Q.NO.1. Encircle the correct answer? (1×17=17) 1. Atoms of which one of the follelement have independent existance: (A) Flourine (B) Krypton (C ) Oxygen (D) Nitrogen 2.18g glucose is dissolved
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2007) (3) William Bonner‚ A (4) Lemieux‚ R. U.; Pavia‚ A. A. Solvation Effects on Conformational Equilibria. Studies Related to the Conformational Properties of 2-Methoxytetrahydropyran and Related Methyl Glycopyranosides. Canadian Journal of Chemistry 1969‚ 1966–1968. (5) M. L. Wolfrom‚ Donald R. Husted; the Beta to Alpha Conversion of Fully Acetylated Sugars by Alkali. J. Am. Chem. Soc.‚ 1937‚ 59 (2)‚ pp 364–365 (6) Perles‚ C (9) Spectral Database for Organic Compounds (SDBS); mass spectrum;
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Determining an enthalpy change of a displacement reaction Aim: To determine the enthalpy change for the displacement reaction between zinc powder and copper (II) sulphate solution. Zn (s) + Cu2+ (aq) → Cu2+ (s) + Zn2+ (aq) Theory: For the displacement reaction‚ an excess amount of zinc powder is added to the measured amount of aqueous copper (II) sulphate. The temperature change over a period of time has to be measured and thus‚ the enthalpy change for the reaction can be measured. The equation
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Final temp in the calorimeter 27.5 degrees C 32.2 degrees C 28.0 degrees C Calculations: Show your work and write a short explanation with each calculation. Part I: 1. Calculate the energy change (q) of the surroundings (water) using the enthalpy equation qwater = m × c × ΔT. We can assume that the specific heat capacity of water is 4.18 J / (g × °C) and the density of water is 1.00 g/mL. The water has absorbed the heat of the metal. So‚ qwater = qmetal m=mass of water= density x volume
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This is important for the students to appreciate the knowledge of chemistry that is still new for themselves. Personally‚ I think that this chapter is an interesting chapter as it revealed the way of scientist produces the material around me. It also gives me new knowledge of the uses of chemical substances that I usually found in the laboratories. I hope‚ by learning this chapter‚ I will be more interested in learning chemistry as it will help me in the future. All the equations from this chapter
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