Organometallic preparation and addition to carbonyls‚ Wittig reagent preparation and Wittig rxn‚ Wolff‚ H-based nucleophile carbonyl reduction‚ imine formation‚ reductive amination (rxn only)‚ ketal/acetal formation‚ dithiane chemistry (rxn only)‚ alpha-bromination of ketones‚ -COOH properties (the trends on HW4)‚ Fischer‚ acidic/basic hydrolysis of esters/amides/nitriles‚ CH2N2‚ acid chloride formation (rxn only)‚ acid chloride rxns with esters and amides. 2 Rxn of carboxyllic acid derivatives
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EXPERIMENT 2: SYNTHESIS OF ORANGE II (2-NAFTHOL ORANGE OBJECTIVE 1. To produce dye based to the coupling of diazonium. 2. To understand the characteristic of dye orange II. INTRODUCTION The first dye was introduced by William Henry Perkin on 1856. It can be produced by the coupling of diazonium sulfanilic acid with nafthol in alkaline solution.. This was the common method used to produce dye nowadays. In this experiment‚ dye produced was the orange II. Azo compound is compound that contain
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|Faculty of Engineering & Science | |Unit Code |: |UEMK1013 | |Course |: |Chemical Engineering | |Unit Title |: |Chemistry for Engineering | |Year/ Semester |: |Year 1/ Trimester 1 | |Lecturer |: |Dr. Loh Han Chern | |Session |: |201101
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Key Questions Lesson 1 1. One argument against continuing research on the atom is that the cost continues to increase at an alarming rate‚ and the benefits seem to be declining. Whereas quantum chemistry experiments as early as 80 years ago were very cheap and yielded considerable practical results‚ now very few if any practical results are emerging‚ but the costs of experiments continues to increase. On the other hand a common argument for the continued
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CHEM 301 LECTURE Unit 1 0 . COORDINATION CHEMISTRY Factors t hat affect solubility: Common ion: decrease in solubility Complex ion: increase in solubility How does complex ion formation increase solubility? Consider the complex ion formation between silver and ammonia: + Ag + 2NH3 A g(NH3 )2 + Kf = 1 .5 x 10 7 where Kf i s the formation constant (always >1 ‚ formation of the complex is highly favorable) Complex ion formation increases the solubility of sol ids in water
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N12/4/CHEMI/SPM/ENG/TZ0/XX 88126104 CHEMISTRY standard level Paper 1 Friday 9 November 2012 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES • Do not open this examination paper until instructed to do so. • Answer all the questions. • For each question‚ choose the answer you consider to be the best and indicate your choice on the answer sheet provided. • The periodic table is provided for reference on page 2 of this examination paper. • The maximum mark for this examination
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experimental techniques which can be used to tell us where the atoms are located in a molecule. Using advanced techniques‚ very complicated structures for proteins‚ enzymes‚ DNA‚ and RNA have been determined. Molecular geometry is associated with the chemistry of vision‚ smell and odors‚ taste‚ drug reactions and enzyme controlled reactions to name a few.
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ical Chemistry 1.which of the following pairs of compound will react? iC3H6+Br2 iiC3H6+Cl2 in sunlight iiiC3H6+H2O in the presence of sulphuric acid ivC3H6+H2O in the presence of concentrated sulphuric acid a.i b.i‚iii c.i‚ii‚iii d.all 2.liqiud y reacts with magnesium metal to produce a gas that burns with a pop sound when a flaming wooden splint is placed near it.liqiud y is most likely a compound that has the formula a.c2h5oh b.hcooh c.h3cooch3 d.c6h14 3.a compound p has the
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Extraction of Aluminium Aluminium ore is called bauxite. Bauxite contains aluminium oxide‚ water‚ iron oxide and other impurities. The purified dry ore‚ called alumina‚ is aluminium oxide (Al2O3). The alumina must be molten for electrolysis to work‚ since the ions are not free to move in the solid state. Unfortunately‚ alumina has a high melting point (2040 °C) and it is not practical to do electrolysis at such a high temperature. In the middle of the nineteenth century it was found that alumina
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1 in vapour state sulphur partly exists as S2 molecule which has 2 unpaired electrons in the antibondind pi orbitals jus lyk oxygen and thus exhibits paramagnetism. 2 An interhalogen compound is a molecule whose atom contains two or more different halogen atoms (fluorine‚ chlorine‚ bromine‚ iodine or astatine). Most interhalogen compounds known are binary (composed of only two distinct elements). Their formulas are generally XYn‚ where n = 1‚ 3‚ 5 or 7‚ and X is the less electronegative
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