SPECTROPHOTOMETRIC DETERMINATION OF EQUILIBRIUM CONSTANT OF A REACTION UNIVERSITY OF THE PHILIPPINES‚ DILIMAN QUEZON CITY‚ PHILIPPINES August 2‚ 2013 ABSTRACT The objective of this experiment is to determine the equilibrium constant‚ denoted Keq‚ for the formation of [Fe(SCN)]2+ complex which is a product of the reaction between the ions Fe3+ and SCN-. In performing this experiment‚ solutions containing FeCl3 and KSCN‚ diluted in HCl‚ were measured for their absorbance using a UV-Vis
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Determination of the Equilibrium Constant for Ferric Thiocyanate In this laboratory exercise‚ the equilibrium constant(Kc) for the reaction between the Ferric Ion (Fe3+) and the Thiocyanate Ion (SCN-) was determined. After measuring the absorbance of the Ferric Thiocyanate‚ and carrying out some calculations; it was determined that Kc=130.81M Introduction: Chemical equilibrium is established when a reaction exists in a state where the forward reaction rate is equal to its reverse reaction
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DATE PERFORMED: JULY 20‚ 2007 SPECTROPHOTOMETRIC DETERMINATION OF EQUILIBRIUM CONSTANT FOR A REACTION ABSTRACT UV-VIS spectrophotometry is one of the most widely-used methods for determining and identifying many inorganic species. During this experiment‚ this spectrophotometry was used to determine the equilibrium constant‚ Keq‚ of the Fe3+(aq)+SCN-(aq)↔ FeSCN2+(aq) reaction. By determining the amount of light absorbed‚ the concentration of the colored FeSCN2+ solution was also quantitatively
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of this experiment are to be able to define equilibrium‚ equilibrium position‚ equilibrium constant‚ reaction quotient and Le Chatelier’s Principle. Another objective is to explain how changes in temperature‚ pressure and concentration affect the equilibrium position of a reaction. Also‚ perform chemical equilibrium reactions and manipulate equilibrium positions through concentration and temperature and perform calculations to determine the equilibrium constant (K) and the reaction quotient (Q) of
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The Equilibrium Constant of an Ester Hydrolysis Reaction Julia Stanley CHM 152 LL Dr. Asmita Kane Budruk Goal of the lab: The purpose of this laboratory is to determine the equilibrium constant‚ Kc‚ for the acid-catalyzed reaction between an unknown ester and water to produce an unknown alcohol and an unknown carboxylic acid. I was using Unknown Ester #3 with a density of 0.9342 and Molar Mass of 74.08 g/mol; alcohol with density 0.7914 and Molar Mass 32.04 g/mol. Chemical
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Date Performed: January 10 & 15‚ 2013 Spectrophotometric Determination of the Equilibrium Constant of a Reaction R.J.V. Ortega and J.C.V. Gatdula Institute of Chemistry‚ College of Science University of the Philippines‚ Diliman‚ Quezon City‚ Philippines Received January 22‚ 2013 ------------------------------------------------- ------------------------------------------------- ------------------------------------------------- ABSTRACT -------------------------------------------------
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General Chemistry II Determining of the equilibrium constant for the formation of FeSCN2+ Introduction The objective of this experiment was to determine the equilibrium concentration and then determine Kc. A dilution calculation was formed to determine the concentration of SCN- and Fe(SCN)2+. Each cuvette was filled to the same volume and can be seen in table 1. Then the absorbances were recorded from each cuvette and can be seen in table 1. A Beer’s law plot was made from the data that was recorded
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AP* Chemistry CHEMICAL EQUILIBRIA: GENERAL CONCEPTS THE NATURE OF THE EQUILIBRIUM STATE: Equilibrium is the state where the rate of the forward reaction is equal to the rate of the reverse reaction. At these conditions‚ concentrations of all reactants and products remain constant with time once equilibrium has been established at constant temperature. (In stoichiometry‚ we dealt with equations that went to completion; often equilibrium equations are going to fall short of this goal.) Reactions are
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Experiment 19 - Determination of the equilibrium constant for the reaction Fe3+ (aq) + SCN( (aq) = FeSCN2+ (aq) Object: To determine the equilibrium constant by a colorimetric method Theory: Colorimetric methods of analysis are usually applied to the determination of small concentrations of either inorganic or organic materials in a solution. The constituent sought must be coloured or must be capable of reacting with a reagent to produce a substance having a suitable colour. Beers Law‚ which
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INTEGRATED CONCEPTS OF EQUILIBRIUM RESULTS AND DISCUSSION A system in equilibrium can be affected by the addition of another reagent leading to a change in chemical equation with a new equilibrium constant. An overall reaction is the sum of two or more reaction steps with different equilibrium constants. The overall equilibrium constant‚ Koverall‚ is the product of the equilibrium constants of the individual reaction step. If a reaction step is reversed‚ the equilibrium constant is set into its
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