CH 222 ANALYTICAL CHEMISTRY I SYLLABUS COURSE OUTLINE: a. Introduction (1.5 hours) Classification of types of analysis‚ role and importance of analytical chemistry in various aspects of life. b. Steps in a typical quantitative analysis (10 hours) Emphasis on sampling protocol‚ sample preparation‚ wet chemistry methods‚ statistical evaluation of data. c. Review of concepts of stoichiometry (2 hours) Mole concept‚ concentrations‚ dilution and aliquots d. Review of concepts of equilibria
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Enthalpy of Neutralization J. Smith M. Smith CHEM 1290-xx 10-31-06 TA Purpose: The purpose of the experiment is to determine the calorimeter constant for the calorimeter holding a specific solution based on the data of heat lost and heat gained. The purpose is to also be able to determine the enthalpy of neutralization for the reaction of a strong acid (phosphoric acid) and a strong base (sodium hydroxide). Experimental: Materials: The materials needed for this lab included; 2 large beakers‚
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Chemistry 101 Chapter 6 THERMOCHEMISTRY · Thermochemistry is the study of the quantity of heat energy released or absorbed in a chemical reaction. Example: the burning of fuel: is a heatevolving reaction · Heat : · Energy: is a form of energy the potential to do work (to move matter) exists in many different forms: Electrical energy Kinetic Energy (energy of motion) Light energy Heat energy Chemical energy (energy of substances) · Different forms of energy can be interconverted
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energy than the reactants Enthalpy changes are normally quoted at standard conditions. Standard conditions are : • 1 atm pressure • 298 K (room temperature or 25oC) • Solutions at 1mol dm-3 • all substances should have their normal state at 298K Standard enthalpy change of formation In an exothermic reaction the ∆H is negative In an endothermic reaction the ∆H is positive When an enthalpy change is measured at standard conditions the symbol is used Eg ∆H The enthalpy of formation of an element
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energy released during bond forming = 2(799) + 4(460) + 2(41) = 3520 kJ enthalpy change of reaction = +2632 + (-3520) = –888 kJ mol-1 Born-Haber Cycle &
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by Bomb Calorimetry Cameron Fowler CHEM 457: Lab Section 4 Submitted: 11/4/10 Lab Group #3: Michael Hyle Neil Baranik Tim Riley Abstract: The enthalpy of combustion of naphthalene was experimentally determined to be -5030.44 ± 78.98 kJ/mol which was a 2.5% error from the literature value of -5160 ± 20 kJ/mol.2 The theoretical enthalpy of combustion of solid naphthalene was calculated to be -6862.68 kJ/mol using bond energies for the gaseous molecules‚ the heat of vaporization of liquid
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Heats of Reaction Lab Report Purpose: To measure the heats of reaction for three related exothermic reactions and to verify Hess’s Law of Heat Summation. NaOH(s) ( Na+(aq) + OH-(aq) ΔH = -10.6kcal/mol NaOH(s) + H+(aq) + Cl-(aq) ( H2O + Na+(aq) + Cl-(aq) ΔH = -23.9kcal/mol Na+(aq) + OH-(aq) + H+(aq) + Cl-(aq) ( H2O + Na+(aq) + Cl-(aq) ΔH = -13.3kcal/mol Background: Energy changes occur in all chemical reactions; energy is either absorbed or released. If energy is released in
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from 15 mL 1 M CuSO4 went up to 31.5 °C upon addition of a 0.05-gram Zinc dust. Therefore‚ it is an exothermic process. All other neutralizations and reactions in the experiment have negative enthalpy values‚ so they are also exothermic. It is therefore concluded that the factors that determine the enthalpy values of reactions are the kinds of reaction that have occurred and the nature of reactants involved. REFERENCES [1] Silberberg‚ M.S. Principles of General Chemistry 2nd Ed. McGraw-Hill
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Thermodynamics of Borax C3C Justin Nevins Chemistry 200‚ Section M1A Introduction The purpose of the lab was to determine how the solubility of Borax (Na2B4(OH)4) and other thermodynamic quantities such as enthalpy‚ entropy‚ and Gibbs free energy depend on temperature. When Sodium borate octahydrate (Borax) dissociates in water it forms two sodium ions‚ one borate ion and eight water molecules. The chemical reaction is shown as: (reaction 1) A simple acid-base titration
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AS Chemistry Revision-Chemistry for Life 1. Avagadro constant‚ 6.02 x 10²³ number of particles in 1 mole of a substance 2. Empirical formula-simplest ratio of atoms of each element in a compound 3. 4. Model of an atom Particle Mass on relative atomic scale Charge Proton 1 1+ Neutron 1 0 Electron Very small (0.00055) 1- 5. Radioactive isotopes Radiation What is it? Relative charge How does the nucleus change? Stopped by? Deflection in electric field? Alpha α Helium nuclei ⁴₂He +2 2 fewer
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