is green‚ when an alcohol is oxidized by the reagent. A change in color of the reagent from orange to green represents a positive test. Primary alcohols are oxidized by the reagent to carboxylic aicds; secondary alcohols are oxidized to ketones. Tertiary alcohols are not oxidized at all by the reagent. Hence‚ this reaction can be used to distinguish tertiary alcohols form primary and secondary alcohols. Procedures: 1. Place ethanol‚ isopropyl alcohol and tert-butyl alcohol in three different
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Lecture No. 1 Chemical Kinetics 1.1 The Rate of a Reaction Chemical Kinetics is the area of Chemistry that is concerned with the speed‚ rate or mechanism at which a chemical reaction occurs. Reaction Rate is the change in the concentration of a reactant or product with time (i.e. M/s). It measures how fast a reactant is consumed and how fast a product is formed. 1.2 WRITING RATE EXPRESSIONS Consider the following hypothetical reaction. A + 2B ( 3C + D Rate = - rate
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Alcohol Facts and statistics ( www.niaaa.nih.gov-2012 ) Global Burden of alcohol abuse‚ In 2012‚ 3.3 million deaths‚ or 5.9 percent of all global deaths (7.6 percent for men and 4 percent for women)‚ were attributable to alcohol consumption.. Alcohol contributes to over 200 diseases and injury-related health conditions‚ most notably alcohol dependence‚ liver cirrhosis‚ cancers‚ and injuries. In 2012‚ alcohol accounted for 5.1 percent of disability adjusted life years (DALYs) worldwide. Globally‚
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Kinetic Molecular Theory Basic Concepts The gas laws developed by Boyle‚ Charles‚ and Gay-Lussac are based upon empirical observations and describe the behavior of a gas in macroscopic terms‚ that is‚ in terms of properties that a person can directly observe and experience. An alternative approach to understanding the behavior of a gas is to begin with the atomic theory‚ which states that all substances are composed of a large number of very small particles (molecules or atoms). In principle‚ the
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Part B Now‚ suppose that Zak’s younger cousin‚ Greta‚ sees him sliding and takes off her shoes so that she can slide as well (assume her socks have the same coefficient of kinetic friction as Zak’s). Instead of getting a running start‚ she asks Zak to give her a push. So‚ Zak pushes her with a force of 125 \rm N over a distance of 1.00 \rm m. If her mass is 20.0 \rm kg‚ what distance d_2 does she slide after Zak’s push ends? Remember that the frictional force acts on Greta during Zak’s push and
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Kinetic theory of gases Question: How does odor travel from one place to another? Kinetic theory of gases A gas is composed of atoms or molecules The gas particles are in constant random motion Kinetic energy is transferred between particles as they collide Pressure The force exerted per unit of area Formula: pressure/force area Measured by barometer A vacuum is empty space‚ with no particles or pressure. Atmospheric pressure is the collision air particles with objects Units of
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1 UNIT 9 CHEMICAL KINETICS 1. (c) mole 1–1 sec–1 The rate law for a reaction A + B →products‚ is rate = k [A]1[B]2. 7. Then‚ which one of the following statements is false ? (a) If [B] is held constant while [A] is doubled‚ the reaction will proceed twice as fast. (b) If [A] is held constant while [B] is reduced to one quarter‚ the rate will be halved (c) If [A] and [B] are both doubled‚ the reaction will proceed 8 times as fast. 2. Fro a first order reaction‚ a straight
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Static and Kinetic Friction Introduction The amount of friction force between two surfaces in contact depends on the type of the surfaces in contact and the amount of compression between the surfaces. Static friction is the force that is acting against your force before the object begins to move. If you exert a small push on the box‚ the box will not move because static friction is directly opposite to the push. If you apply a greater force than the static friction force‚ the friction increases
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Kinetics of an SN1 reaction: the effect of solvent on rate Object The purpose of this experiment is to determine the rate of hydrolysis in acetone/water (50/50 v/v and 60/40 v/v). Background and Theory An SN1 reaction of tert-butyl chloride takes place in two steps. First‚ the Alkyl Halide will leave the molecule. In this step the bond is breaking‚ which takes a longer amount of time‚ so it will determine the rate of the reaction. As a result‚ it forms a tertiary carbocation‚ since this
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