Kinetic and Thermodynamic Reaction Condition Brandon Bullock 2/10/15 Objective The purpose of this experiment is to test kinetic theory by running several reactions and determine which product are formed under kinetic conditions and which products are formed under thermodynamic conditions. Kinetically controlled products have low transition states. This makes it easy for the product to be formed at low temperatures
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determine the rate equation for the reaction between Hydrogen peroxide and iodide ions‚ and to investigate the effects of a catalyst and temperatures on the reaction and to derive the activation enthalpy. Background knowledge: 1Hydrogen peroxide reacts with iodide ions producing iodine‚ when in an aqueous acid solution. H2O2 (aq) + 2I- (aq) + 2H3O+(aq) I2 (aq) + 2H2O(l) To detect iodine you can look at the color shown by the addition of starch solution. Iodine also reacts with sodium thiosulphate
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Kinetics of Hydrogen Peroxide February 22‚ 2007 Chem. 1130 TA: Ms. Babcock Room 1830 Chemistry Annex PURPOSE OF THE EXPERIMENT Kinetics of Hydrogen Peroxide The major purpose of this experiment is to determine the rate law constant for the reaction of hydrogen peroxide and potassium iodide. In this experiment‚ the goal will be to try to measure the rate law constant at low acidity‚ since at low acidity‚ anything less than 1.0 x 10-3M‚ the effect of the hydrogen ion is negligible. To calculate
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Effect of Nature of Reactants to the reaction rate. B. Effect of Temperature to the reaction C. Effect of Concentration to the Reaction Rate D. Effect of Catalyst to the Reaction Rate E. Chromate-Dichromate Equilibrium F. Thiocyanatoiron (III) Complex Ion Equilibrium G. Weak Acid Equilibrium (Ionization of Acetic Acid) H. Weak Base Equilibrium Ionization of Ammonia I. Saturated Salt (Sodium Chloride) Equilibrium On part (A) we are to observe which reaction rate is faster‚ and doing the experiment
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Systems Biology Lecture 3: Enzyme kinetics Tue 17 Jan 2006 with the collaboration of Luna De Ferrari 1 Images from: D. L. Nelson‚ Lehninger Principles of Biochemistry‚ IV Edition‚ W. H. Freeman ed. A. Cornish-Bowden Fundamentals of Enzyme Kinetics‚ Portland Press‚ 2004 A. Cornish-Bowden Enzyme Kinetics‚ IRL Press‚ 1988 Computational Systems Biology Summary: • • • • • • 2 Simple enzyme kinetics Steady-state rate equations Reactions of two substrates Inhibition of enzyme
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F7 Essay Writing (Kinetics) Q. Write an essay on factors which affect the rate of reactions and discuss the uses of kinetic studies. Outlines: (I) Factors affecting the Rate of Reaction (a) temperature ---- collision of molecules with different velocities and kinetic energies ---- Collision Theory and Maxwell-Boltzmann distribution ---- Arrhenius equation and Activation energy (b) concentration ---- frequency of collisions and effective collisions
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Chloroform‚ Acetone and Methanol) for sequential extraction. First of all plant materials were soaked in Hexane for 2-3 days with regular stirring. The mixture was then filtered by using Whatman No. 4 filter paper in to a glass beaker. 300ml of other solvent‚ Chloroform‚ was then added in the residue for 2-3 days. Similarly the mixture was filtered by using whatman No. 4 filter paper. After chloroform‚ Acetone and Methanol were added in residue for sequential extraction. Solvents; Hexane‚ Chloroform
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this experiment was to use Iodine‚ Benedict and Biuret to test the reaction of the following 12 samples: 1% glucose‚ 0.3% glucose-1-phosphate‚ 1% maltose‚ honey‚ 1% sucrose‚ 1%lactose‚ 1% glycogen‚ 1% starch‚ protein‚ beer‚ distilled water and an unknown solution (test tube: 300). The iodine test for starch was to test how would starch reacted if we put iodine in it. The color of starch before the test was clear. The color of the iodine was brown. When you added iodine into starch‚ the result was
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1 for a pictoral representation of these definitions.) | Figure 1 Definitions | Torque is defined as = r x F = r F sin(). In other words‚ torque is the cross product between the distance vector (the distance from the pivot point to the point where force is applied) and the force vector‚ ’a ’ being the angle between r and F. Using the right hand rule‚ we can find the direction of the torque vector. If we put our fingers in the direction of r‚ and curl them to the direction of F‚ then the
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UNIT 9 CHEMICAL KINETICS 1. (c) mole 1–1 sec–1 The rate law for a reaction A + B →products‚ is rate = k [A]1[B]2. 7. Then‚ which one of the following statements is false ? (a) If [B] is held constant while [A] is doubled‚ the reaction will proceed twice as fast. (b) If [A] is held constant while [B] is reduced to one quarter‚ the rate will be halved (c) If [A] and [B] are both doubled‚ the reaction will proceed 8 times as fast. 2. Fro a first order reaction‚ a straight line
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