2013 “Reaction Classes and Pericyclic Reactions” ● 4 Lectures ● Recommended Texts: (i) J. March “Advanced Organic Chemistry”‚ p 839‚ `---Edn.‚ Oxford (W); Warren (2) Ch 34‚ 35. Syllabus 1) General principles (a) Reaction classes (i) Heterolytic (ii) Homolytic (iii) Pericyclic (b) Pericyclic Reaction Types 2) Electrocyclic Reactions (a) Definition and examples (b) Stereochemical aspects and the Woodward and Hoffmann rules 3) Cycloaddition Reactions (a) Definition
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vacuum for approximately one hour. Residual toluene was collected in one vial between 24–28 °C then a slight temperature drop was observed indicating all toluene had been removed. Pig was turned to allow collection of pure product into a separate flask from 78 °C. a clear liquid was collected as the product (C1) weighing 21.94g. Percentage yield was calculated and IR spectrum was run. Next‚ apparatus for Grignard reaction was placed in an oven for an hour to ensure no moisture was present then set
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Reaction on Reaction Paper The first thing that came to my mind when I have heard about Reaction paper is “What exactly is it?” and before I get an understanding of that‚ I resisted that change. But later‚ when I have studied about it and understood its purpose‚ I have started thinking “Why people avoid change at the first look without an analysis?” The general human tendency is to live in a comfortable zone in which he has lived for quite some time. He draws a circle‚ thinks that circle is his
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DETERMINATION OF SAPONIFICATION AND IODINE NUMBERS OF SOME LIPIDS A.L. ASCANO1 C.V. OPONDA1 1INSTITUTE OF BIOLOGY UNIVERSITY OF THE PHILIPPINES‚ DILIMAN‚ QUEZON CITY‚ PHILIPPINES DATE PERFORMED: FEBRUARY 19‚ 2013 INSTRUCTOR’S NAME: FRANCESCA N. BELTRAN _____________________________________________________________________________________ ABSTRACT _____________________________________________________________________________________ INTRODUCTION Lipids are long aliphatic hydrocarbon chains
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Properties and Reactions of Hydrocarbons Abstract Introduction Hydrocarbons are organic materials that contain only carbon and hydrogen atoms‚ these molecules can be saturated or unsaturated and acyclic‚ cyclic‚ or aromatic. In this experiment we used a variety of methods to examine the physical and chemical properties of hydrocarbons. The first experiment we tested a variety of solvents to see if they dissolved our alkane (Decalin). One would expect that non-polar solvents will dissolve
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calculated products are determined using the limiting reagent‚ (the substance that runs out first which stops the reaction) and are called the theoretical yield. The theoretical yield is the amount of product that should be acquired during the experiment if all aspects go perfectly. However‚ due to experimental errors‚ very few labs do so. These results are called actual yield. The percent ratio between the theoretical and actual yield is called the percentage yield. It is calculated by taking the actual yield
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PUTTING IT TOGETHER: Classifying Chemical Reactions Purpose: To observe and differentiate between the four different types of chemical reactions. Variables: The independent variables are the sodium chloride‚ sodium carbonate‚ magnesium‚copper‚ copper (11) sulfate‚ silver nitrate‚ oxygen‚ lead(11) nitrate‚ sodium carbonate‚ copper (11) sulfate pentahydrate. The dependent variables are the chemical reactions that are being looked for. For example decomposition‚ synthesis‚ single displacement or double
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IB CHEMISTRY Unit 6: KINETICS STANDARD LEVEL: Number Objective Rates of Reaction Define the term rate of reaction. Describe suitable experimental procedures for measuring rates of reactions. Analyze data from rate experiments. Students should be familiar with graphs of changes in concentration‚ volume and mass against time. Collision Theory Describe the kinetic theory in terms of the movement of particles whose average energy is proportional to the temperature in Kelvins. Define the term activation
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Module 3: Kinetics of Chemical Reactions Introduction to Kinetics Chemical thermodynamics has answered the question “can a specified chemical reaction take place?” (i.e. is the reaction thermodynamically favourable?). • However‚ chemical thermodynamics hasn‟t answered the question “HOW FAST will a specified chemical reaction occur?” o Many thermodynamically favourable reactions are so slow (ex: metamorphic transformation of rocks‚ corrosion of marble sculptures owing to weathering) that they can
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Inorganic Chemistry TOPIC 3: CHEMICAL KINETICS Lecturer and contacts Mr. Vincent Madadi Department of Chemistry‚ University of Nairobi P. O. Box 30197-00100‚ Nairobi‚ Kenya Chemistry Dept. Rm 114 Tel: 4446138 ext 2185 Email: vmadadi@uonbi.ac.ke‚ madadivin2002@yahoo.com Website: http://www.uonbi.ac.ke/staff/vmadadi 12/13/2011 mov 1 Introduction • Kinetics is the study of rates of chemical reactions and the mechanisms by which they occur. • The reaction rate is the increase in concentration of
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