Number Surname Other Names Candidate Signature Candidate Number For Examiner’s Use Examiner’s Initials Question Mark General Certificate of Education Advanced Level Examination January 2011 1 2 3 Chemistry Unit 4 Kinetics‚ Equilibria and Organic Chemistry 9.00 am to 10.45 am Wednesday 26 January 2011 CHEM4 4 5 6 7 For this paper you must have: ● the Periodic Table/Data Sheet‚ provided as an insert (enclosed) ● a calculator. TOTAL Time allowed ● 1 hour 45 minutes
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When it comes to organic chemistry and the synthesis of specific products there is an abundant amount of routes that can be taken and still get you the same result. For the following experiment‚ the main focus is the use of a cycloaddition reaction‚ also known as Diels-Alder. According to the lab manual‚ this reaction consists of the addition of a diene and a dienophile and that the Diels-Alder reaction builds stereospecific ring compounds with ease (Weldegirma 80). The reaction takes place between
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Objective To compare the relative reactivities of different alkyl halides with two different reagents; sodium iodide in acetone and silver nitrate in ethanol. Below the reaction equations 1. RX+NAIRI+NAX (X=Cl or Br) in the presence of acetone 2. RX+AgNO3+EtOHROEt+AgX+HNO3 We used three substrates primary secondary and tertiary compounds are 1-bromobutane‚ 2-bromobutane and 2-bromo-2-methylpropane respectively to react with the two nucleophiles that are sodium iodide with acetone solvent and
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Chem 51LC Experiment 6 Lab Report Aldol Reaction Purpose: The purpose of this experiment is to be able to conduct an aldol condensation reaction using an unknown aldehyde and an unknown ketone. H NMR is used to identify the unknown aldehyde and ketone. Melting point is used to identify the aldol condensation reaction. Theory: Condensation reaction is also known as a dehydration reaction. In the mechanism of condensation reaction‚ a bond is formed between two molecules and creates water as a
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Experiment 11: Reactivities of Some Alkyl Halides in Substitution Reactions Materials & Methods: Materials used: 1-bromobutane 1-chlorobutane bromocyclopentane Bromocylcohexane 2-chlorobutane 2-bromobutane 2-chloro2-metylpropane 2-bromo-2-methylpropane Crotyl chloride Bromobenzene Benzyl chloride 1-chloroadamantene Methods/Techniques: Physiochemical Research: Reagent | Formula Weight | Density | Boiling Point | Melting Point | Color | 1-bromobutane | 137.023 g/mol |
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1. The following compound A‚ is used as an artificial sweetener. Compound A (April 2009) (a) Name all functional groups in A (b) For each of the carbon X‚ Y and Z in compound A‚ determine (i) the type of hybridization (ii) the bond angle (c) A is optically active. Mark on the structure the chiral centre(s) in A. 2. (a) Draw structural formula of (i) a haloalkane
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In this experiment‚ the stereochemistry of 2‚3-dibromo-3-phenylpropanoic was found to determine syn or anti addition of bromines. The melting point was 199-203°C and the NMR J values angle is at 167 which both prove the erythro-2‚3-dibromo-3-phenylpropanoic. Determination of the Stereochemistry of 2‚3-dibromo-3-phenylpropanoic acid. Introduction The purpose of this experiment was to determine the mechanism of the reaction of trans-cinnamic acid with the addition of bromines to 2‚3-dibromo-3-phenylpropanoic
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Anthony Young Partner: Nick Dale TA: Alekhya 6/15/15 The SN2 Reaction: Factors Affecting SN2 Reaction. Introduction In the substitution reactions‚ the leaving group from the substrate is replaced with the nucleophile. Because of the nucleophile it is called nucleophilic substitution. The lone pair of electrons‚ present on the nucleophile is used to create a new bond with the carbon atom‚ from which the leaving group was separated. There are two different mechanisms of nucleophilic substitution: SN1
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AS Applied Science Luke O’Reilly Aim/background- Test soil from an area that previously had heavy industry on it to check for contaminants. Procedure- I will first visit a site that has previously has heavy industry located on it. Using protective clothing‚ goggles and gloves I will extract several samples of the soil from the site and then take several other samples from different points on the site. This ensures variety of soil to ensure that all the site is safe‚ not just a small area where you
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Chemistry 2: Organic and Inorganic Chemistry Activity 1 PROPERTIES OF ORGANIC COMPOUNDS (Sugar) Rainbow Density Column Introduction As a chemical term‚ “sugar” usually refers to all carbohydrates of the general formula Cn(H 2O)n‚ an organic compound. This exercise is focus on sugar as an organic compound and its properties. Objectives: 1. To identify the properties of organic compound - sugar. 2. To observe some physical properties and changes on an organic compound during the actual conduct of
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