by : Directorate of Education‚ Delhi SOME IMPORTANT REASONING BASED QUESTIONS OF ORGANIC CHEMISTRY 1. Chlorobenzene is less reactive than chloromethane. Ans. In chlorobenzene‚ each carbon atom of benzenering is sp2 hyridised and is electron withdrawing. Chlorine atom donates a lone pair of electron and acquire positive charge. The negative charge is delocalised on ortho and para position by resonance. C-Cl bond acquires partial double bond character and is 169 pm as compared to 17.0 pm in chloromethane
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Synthesis of Aspirin and Oil of Wintergreen Janelle Alyssa P. Prudente De La Salle University-Dasmariñas Dasmariñas City‚ Cavite‚ Philippines ABSTRACT In this experiment‚ acetylsalicylic acid commonly known as aspirin and methyl salicylate‚ commonly known as oil of wintergreen‚ was synthesized from salicylic acid. This study will show that it is possible to show two very different organic compounds from the same common starting material. For the synthesis of aspirin‚ salicylic acid
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groups Structure determination (Unit 1) Structure determination (Unit 2) Structure determination (Unit 3) Structure determination (Unit 4) Organic synthesis Organic Laboratory Technique (Unit 1) Organic Laboratory Technique (Unit 2) Organic Laboratory Technique (Unit 3) Organic Laboratory Technique (Unit 4) Reference Reading from Solomons‚ Organic Chemistry 6th edition 90-93‚ 96-101 102-118‚ 320‚ 433-434‚ 795-796‚ 903-905‚ 970-972 59-61 178-185‚ 188‚ 193-198‚ 200 41-47‚ 65-75‚ 128-137‚ 284-286
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Nucleophilic Substitution Reactions of Alkyl Halides 1. Summary of Experiment In this experiment we will be comparing the both SN1 and SN2 reactions using various compounds and sodium iodide and silver nitrate. We will be comparing the nature of the leaving group (Cl vs Br) in the 1-halobutanes as well as the effect of the structure
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Part 1. Hydrocarbon Nomenclature From International Union of Pure and Applied Chemistry (IUPAC) General Form of IUPAC Nomenclature [branching substituent(s)] Root [Suffix] Rules: 1. Identify the longest continuous chain of carbon atoms. This chain determines the parent name (root) of the alkane. The parent suffix for alkanes is‚ not surprisingly‚ -ane. For chains of equal length‚ pick the one with the most substituents. (Note: I number all possibilities going from left to right
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relieve stuffy nose symptoms. H HO OH H N CH3 . HCl What is the configuration at this chirality center? R or S ? www.primaryrx.com/pdf/C-PHEN%20DM%20DROPS.pdf 1 Chapter 15: Benzene and Aromaticity Introduction: • All organic compounds can be derived into two broad classes 1. Aliphatic compounds Nonaromatic hydrocarbons such as alkanes‚ alkenes or alkynes 2. Aromatic compounds A series of cyclic unsaturated compounds with unusually high stability • The properties
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Organic Chemistry II Laboratory (ABCT357) Although studying fundamental theories of chemistry in the class is important to understand the concept of chemistry‚ carrying out experiments to corroborate the theories is also important. It is very important for students to get used to experiments in order to speed up their experiments. Expt.1. Acetylation of α-D-glucopyranose Add slowly 2.5 g (0.014 mol) of powdered D-glucose in small portions (roughly in 7-10 portions and 5 min for each addition)
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Chemistry 3373F Lab Manual 2008 Modified 11/07 Table of Contents Chem 3373 Laboratory Schedule for Fall 2008.............................................................................2 The Benzoin Condensation of Benzaldehyde ..............................................................................3 Synthesis of Dilantin and Related Compounds (two weeks).........................................................6 Synthesis of an Alkaloid: Pseudopelletierine (two weeks) .............
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1.1 CHEMISTRY 2213a ORGANIC CHEMISTRY FOR THE LIFE SCIENCES - organic chemistry is the study of life at the molecular level; to many it is the key to understanding life “The language of chemistry- an international language‚ a language without dialects‚ a language for all of time‚ and a language that explains where we came from‚ what we are‚ and where the physical world will allow us to go” (Nobelist Arthur Kornberg‚ a biochemist‚ 2000) - but its study has been challenging for students for
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Name__________________________ Chemistry 190: Organic Chemistry EXAM 3 Thursday April 21‚ 2011 1. (12) ______ 2. (14) ______ 3. (20) ______ 4. (12) ______ 5. (54) ______ 6. (16) ______ 7. (12) ______ 8. (10) ______ Total (150) ______ The exam consists of twelve numbered pages and an unnumbered cover sheet. Make certain that you have a complete exam. You will have two hours to work on the exam. No books or notes are allowed; however‚ you may use a molecular model set and a calculator
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