CHM 3411 – Problem Set 6 Due date: Wednesday‚ March 23rd. Do all of the following problems. Show your work. 1) Consider the cyclic molecule C8H8‚ the eight carbon analogue to benzene. a) Write the secular detrerminant corresponding to the pi-bonding in C8H8. b) Using the secular determinant‚ the following energies are found for the pi-bonding molecular orbitals: 1 = + 2 2 = + 1.41 (two states) 3 = (two states) 4 = - 1.41 (two states) 5 = - 2 Give the electron
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Questions and Hypothesis: Seed germination‚ plant growth‚ and sprouting of leaves are affected by several factors: supply of nutrients‚ water‚ exposure to sunlight‚ and conditions of surroundings. Due to certain stimuli in the surroundings plant “hormones” cause plants to behave in ways that ensure the most efficient use of resources while preserving the most energy. One stimulus to consider‚ is the exposure of plants to sunlight; when plants are just sprouting and are underground‚ the sti
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of the lab is to prepare ferrocene from ferrous chloride and cyclopentadiene. Ferrocene‚ an organometallic‚ is a combination of two cyclopentadienide ions with a ferrous cation‚ such that the six pi electrons binds every carbon equally to the metal forming a sandwich type structure. Ferrocene has the properties of both an activated benzene (undergoes electrophilic substitution reactions) and a ferrous ion (oxidation reaction). Glyme and DMSO are used as solvents as they have moderate polarity so they
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The Effects of Osmosis and Diffusion The experimentation of last week’s lab was in order to test the many effects of diffusion and osmosis amongst four experiments. One such experiment was testing the effects of molecular weight on diffusion in relation to the use of Agar. The methods performed included the use of two acids‚ HCl and acetic acid. Both acids were placed into an Agar-filled dish and‚ over increments of 15 minutes‚ data collection was taken based off the diffusion rate and the
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Introduction In unit 7.3 the experiment tested the ability of lactase to specifically bind and interact with lactose compared to maltose. In unit 7.4 the experiment tested the role‚ if any‚ that metal ions have on the activity of lactase. My hypothesis for unit 7.3 was knowing that lactase is specific for lactose‚ lactose will separate into galactose and glucose‚ as maltose will not change (153-155). Lactase should like lactose. For unit 7.4 my hypothesis was that EDTA will remove the ions‚ and
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Limiting Reagent and Percent Yield Aim To determine the limiting reagent between the reaction of lead (II) nitrate and potassium iodide. To determine the percent yield of lead (II) iodide. Date Started: 13/4/12. Finished: 19/4/12. Data collection and processing Measurements: * Amount of distilled water: 75.0ml ± 0.5ml. * Mass of watch glass: 31.65g ± 0.01g. * Mass of watch glass + potassium iodide: 32.45g ± 0.01g. * Mass of potassium iodide: 0.8g ± 0.02g. * Mass of watch
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TABLE OF CONTENT NO. | CONTENT | PAGE | 1. | Title | 2 | 2. | Theory | 2 | 3. | Introduction | 2 | 4. | Objective | 3 | 5. | Apparatus | 3 | 6. | Procedure | 4 | 7. | Result | 6 | 8. | Calculation | 10 | 9. | Discussion | 13 | 10. | Conclusion | 14 | 11. | References | 14 | TITLE: H1 – Osborne Reynolds Demonstration INTRODUCTION: Osborne Reynold’s Demonstration has been designed for students experiment on the laminar‚ transition and turbulent flow. It consists of a transparent
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Tittle : Investigation of the Enzymatic Effects of Materials on Hydrogen Peroxide Solution Objective: To investigates the enzymatic effect of various materials in the hydrogen peroxide solution. Table 1 Test Tube Contents with 5 cm3 hydrogen peroxide Observations before and after using wood splint Observation of after Observation of after adding hydrogen using wooden glowing peroxide splinter 1 Fresh liver Moderate
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Inorganic Chemistry 1. A subatomic particle with a single positive electrical charge is protons. 2. A subatomic particle with a single negative electrical charge is electrons. 3. A subatomic particle which is electrically neutral is neutrons. 4. The nucleus of an atom is made up of _protons_ and _neutrons. 5. The number of electrons forming a charge cloud around the nucleus is (pick one of the following) greater than; equal to; smaller than the number of protons in the nucleus of the atom.
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EXPERIMENT I Photoreduction of Benzophenone Introduction The study of chemical reactions‚ isomerizations and physical behavior that may occur under the influence of visible and/or ultraviolet light is called Photochemistry. The fundamental principles for understanding photochemical transformations are that light must be absorbed by a compound in order for a photochemical reaction to take place‚ and that for each photon of light absorbed by a chemical system only one molecule is activated for
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