moles/1000 mL = .0005 moles/10 mL = moles of hydroxylammonium chloride Ratio of Fe+2 to NH3OH+ = 2:1 2e- + 2Fe+3 --> 2Fe+2 so transfer of 2 electrons NH3OH+ --> something + 2e- Oxidation number of N in NH3OH+ is -1‚ therefore the oxidation number for N on the product side must be +1 because it gains 2 electrons. N2O has an oxidation number of +1 for N‚ so that would work. Data:Equation 1: NH3OH+ + 2Fe+3 --> something + 2Fe+2 Equation 2: 8H+ + 5Fe+2 + MnO4- --> 5Fe+3 + Mn+2 + 4H2O Equation 3: 6H+ +
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Experiment 39 Oxidation – Reduction Titrations II : Analysis of Bleach A. Standardization of 0.05 M Na2S2O3 Solution KIO3 concentration 0.01 M Volume of KIO3 Trial #1 Trial #2 Final burette reading 15.01 mL 30.00 mL Initial burette reading 0.00 mL 15.01 mL Milliliters of KIO3 used 15.01 mL 14.99 mL Volume of Na2S2O3 Trial #1 Trial #2 Final burette reading 13.40 mL 25.78 mL Initial burette reading 0.03 mL 13.37 mL Milliliters of Na2S2O3 used
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YOUR NAME: Erin Alston‚ Kennedy Stuart‚ Amber Lamb and Stephonya Williams EXPERIMENT TITLE: Oxidation: Cyclohexanone from Cyclohexanol by Hypochlorite Oxidation and Adipic Acid from Cyclohexanone DATE: 4/18/2014 INTRODUCTION: In experiment 4‚ alcohol is oxidized to a ketone with household bleach. The product is then isolated by steam distillation and is extracted into the distillate with ether. After the removal of ether‚ it leaves the product cyclohexanone. In experiment 6‚ cyclohexanone is
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College Chemistry 1 Lab 16 Oxidation Reduction Lab 16 Introduction: I will learn about redox reactions. Materials and Methods: I placed ten drops of each substance into different wells. Then I took Magnesium and put it in the first one. I put Zinc into the second one. I placed lead into the third and fourth one‚ and put iron into the fifth one. Results: See Table Below. Discussion: I learned about different redox reactions. Questions: A. Sodium
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potassium permanganate solution was titrated thrice to give clear Mn2+ with an analyte of acidified FeSO4 until all the Fe2+ in the solution was oxidized to Fe3+. The color of the MnO4-/Mn2+ was used as the indicator for the titration. A balanced oxidation-reduction‚ the molarity/normality of the standards potassium permanganate‚ and the volume of potassium permanganate used allowed the determination of the concentration of the FeSO4. Equipment and Chemicals: Chemicals: * Iron (II) ammonium sulfate solution
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Module 16 Notes Reduction/Oxidation Reactions • Oxidation number: The charge that an atom in a molecule would develop if the most electronegative atoms in the molecule took the shared electrons from the less electronegative atoms. • Oxidation numbers are not real; they are only based on assumptions. They are useful bookkeeping tools though‚ and can help us keep track of electrons during a reaction. • The sum of all oxidation numbers in a molecule must equal the charge of that molecule. • Rules
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1. Mechanism of oxidation process In an oxidation process of silicon that usually takes place at very high temperature (thermal oxidation)‚ silicon (Si) reacts with either water vapor (H20) or oxygen (O2) to form silicon dioxide‚SiO2 on the silicon surface. The reaction is represented by following equations: Dry oxidation: Si + O2 → SiO2 Wet oxidation: Si + 2H2O → SiO2 + 2H2 The oxidation process can be implemented through diffusion
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OIXDATION(AND(REDUCTION(–(REDOX(CHEM(1( ( KEY(REDOX(CONCEPTS( •! Oxidation)and)reduction)are)electron(transfer(processes)(reactions).)) o! Oxidation(–(Loss)of)electrons)) !! Reductant((reducing)agent))–)undergoes)oxidation.)) o! Reduction(–(Gain)of)electrons)) !! Oxidant((oxidising)agent))–)undergoes)reduction.)) ! Example:(((((((((((Mg(s)(+(2H+(aq)( (Mg2+(aq)(+(H2(g)( o! This!reaction!can!be!broken!up!into!two!halfEreactions(( !! Oxidation:)Mg(s))")Mg2+)+)2e:)(lost)electrons))( !! Reduction:)2H+)+)2e:)")H2)(gained)electrons))(
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OXIDATION AND REDUCTION Oxygen makes up only about 20% of the air‚ yet is the essential component for so many reactions. Without it fuels would not burn‚ iron would not rust and we would be unable to obtain energy from our food molecules through respiration. Indeed animal life on the planet did not evolve until a certain concentration of oxygen had built up in the atmosphere over 600 million years ago. The term oxidation has been in use for a long time to describe these and other reactions where
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Oxidation of Cyclohexanol Introduction: The oxidation of cyclohexanol involves using household bleach to oxidize this secondary alcohol and produce a ketone product‚ cyclohexanone. Oxidation-reduction (redox) reactions occur when the oxidation state of atoms change due to a transfer of electrons. Oxidation occurs when electrons are ‘lost’ to the formation of bonds and reduction occurs when electrons are ‘gained’ in the braking of bonds (Levine). Using this reaction and its product‚ a redox experiment
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