Title: ACID BASE TITRATION. Objectives: 1. To determine the concentration of acid using titration. 2. Skills of titration techniques. Apparatus: 1. 250 volumetric flask 2. 10mL measuring cylinder 3. 25mL pipette 4. 50mL burette 5. 250mL beaker 6. 150mL conical flask 7. Retord stand 8. White tile 9. Stopwatch 10. Pipette bulb Chemicals: 1. HCl solution 2. 0.1M NaOH solution 3. H2SO4 solution 4. Distilled water 5. phenolphthalein Introduction
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18.1.4 – 18.1.6 CALCULATIONS INVOLVING ACIDS AND BASES Review of Important formulas pH = ‐ log10[H+] [H+] = 10‐pH pKa = ‐ log10 Ka Ka = 10‐pKa pOH = ‐ log10[OH‐] [OH‐] = 10‐pOH pKb = ‐ log10 Kb Kb = 10‐pKb The ionic product of water = Kw = [H+] x [OH‐] = 1.0 x 10‐14 mol2 dm‐6 at 298 K The expression varies with temperature
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Unknown weak acid‚ 1.5g Water‚ distilled or deionized * Equipment: Balance Stir bar Beaker‚ 250mL Oven Buret‚ 50 mL pH sensor Desiccator Rising stand and buret clamp Erlenmeyer flask‚ 125mL Wash bottle with distilled water Funnel Weighing dishes‚ 2 Procedure: Part 1: Standardization of a Sodium Hydroxide Solution 1. Obtain a sample of potassium hydrogen phthalate that has been previously dried in oven and stored in a desiccator. 2. On an analytical balance‚ accurately
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ACID/BASE You might need to know the following K values: CH3COOH Ka = 1.8 x 10–5 Benzoic Acid Ka = 6.5 x 10–5 HNO2 Ka = 4.5 x 10–4 NH3 Kb = 1.8 x 10–5 HF Ka = 7.2 x 10–4 H2S Ka = 5.7 x 10–8 HSO4– Ka = 1.2 x 10–2 HS– Ka = 1.2 x 10–13 HCOOH Ka = 1.8 x 10–4 HOCl Ka = 3.0 x 10–8 SIMPLE ACIDS AND BASES 1. According to the Brønsted–Lowry definition‚ which species can function both as an acid and as a base? (A) Cl– (B) SO42– (C) NH4+ (D) HCO3– (E) H3O+ 2. Which of the following
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Acid Base And Salt Acid Acids:- The word ‘Acid’ came from Latin word ‘Acidus or Acere’ which means sour. Sour taste is the most common characteristic of acid. Acid turns blue litmus paper red. There are many substances which contain acid and hence taste sour‚ such as curd‚ tamarind‚ lemon‚ etc. Types of Acids:- Acids are divided into two types on the basis of their occurrence – Natural acids and Mineral acids. Natural Acid:- Acids which are obtained from natural sources are called natural
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Anna Powell 2nd I.Title: Acid-Base Titrations AP Chemistry Laboratory #6 II.Purpose: The purpose of this experiment is to standardize a sodium hydroxide solution and use the standard solution to titrate an unknown solid acid. The equivalent mass of the solid acid will be determined from the volume of sodium hydroxide added at the equivalence point. The equilibrium constant‚ Ks‚ of the solid acid will be calculated from the titration curve obtained by plotting the pH of the solution versus
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Aqueous Acid/Base Chemistry Resources: Harris ‘Quantitative Chemical Analysis’ Review: Pure water has a pH = 7 Autodissociation: H2O (( H3O+ + OH- K = [H3O+][OH-]/[H2O] -log[H3O+] = 7 [H3O+] = 10-7 M = [OH-] [H2O] = 55.56 M K = 1.8 x 10-16 ; pKa = 15.74 pKa is the acid dissociation constant; low pKa (strong acid‚ high pKa (weak acid we can also write Kw = [H3O+][OH-] Kw = 10-14 In water‚ pH + pOH = 14 pH scale Strong
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Acid and Base Titrations: Preparing Standardized Solutions Introduction: This experiment focuses on titrations of acids and bases. A titration depends on addition of a known volume of solution and is a type of volumetric analysis. Many titrations involve either acid-base reactions or oxidation-reduction reactions. In this experiment we do one of each. We monitor the pH of the reaction with the use of a color indicator. We also learn about the standardization of bases (NaOH) and acids (HCl) which
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The acid-base titration curves help to find the pKa‚ Ka‚ and pH at equivalent point. At the beginning pH for HCl is 1.90 which is lower than the 3.28 for acetic acid; thus‚ strong acid (HCl) means lower pH and weak acid (acetic acid) means higher pH. Then at the equivalent point for the titration HCl-NaOH the pH is 7‚ which mans that is neutral‚ in other words there are enough NaOH mmol to neutralize the HCl mmol present; also‚ the solution contains only water and NaCl the salt derived from the titration
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Acids and Bases Q1.This question is about several Brønsted–Lowry acids and bases. (a) Define the term Brønsted–Lowry acid. ........................................................................................................................ ........................................................................................................................ (1) (b) Three equilibria are shown below. For each reaction‚ indicate whether the substance immediately above the box is acting
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