Diels-Alder cycloaddition reaction was discovered by Otto Diels and Kurt Alder and is very useful in the synthesis of polycyclic compounds. The Diels-Alder reaction can be described as: [4+2] cycloaddition- a diene with 4 π electrons + 2π electrons from the dienophile; a pericyclic concerted reaction- meaning the reaction occurs in a single step (no intermediates) and involves a cyclic redistribution of bonding electrons. In order for a Diels-Alder reaction to take place the diene must
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In order to first perform the reaction‚ 1.5 mL of 4-methylcyclohexanol was added to a pre-weighed 5mL conical vial. The conical vial was then weighed to find the actual mass of 4-methylcycloheaxanol. Then‚ 0.4mL of 85% phosphoric acid was added to the conical vial using a plastic pipet. Six drops of concentrated sulfuric acid was then added to the vial using a glass pipet. A spin vane was then added before adding the Hickman head‚ water condenser and a drying tube packed with calcium chloride to
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this reaction at 25(C. A. 1020 kJ/mol B. -1.22 ( 103 kJ/mol C. 2.00 ( 103 kJ/mol D. -1.42 ( 103 kJ/mol E. -198 kJ/mol 2. For the reaction H2(g) + S(s) ( H2S(g)‚ (H( = -20.2 kJ/mol and (S( = +43.1 J/K·mol. Which of these statements is true? A. The reaction is only spontaneous at low temperatures. B. The reaction is spontaneous at all temperatures. C. (G( becomes less favorable as temperature increases. D. The reaction is spontaneous
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From the results recorded it was identified that activity A and C had exothermic reactions‚ whilst activity B had an endothermic reaction. Each of the activities had initially begun with 23.4/8/9oC‚ however‚ within one minute of adding the 2nd reactants‚ the results began showing‚ as seen from the graph. Activity A and C had risen in temperature‚ with A gaining 4oC and in total of 2 minutes having the temperature of 27.9oC along with C increasing by 2.2oC and within 2 minutes of the experiment having
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Concentration‚ Along with Varying Temperature and pH-Balanced Environments on the Enzyme-Catalyzed Reaction of pNPP Abstract: Introduction: Many of the chemical reactions‚ which take place in in living things are controlled by enzymes. In such cases‚ the enzyme is a protein in the cell which lowers the activation energy of a catalyzed reaction‚ which serves to increase the rate of the reaction. Alkaline phosphatase is made throughout the body. Its function is to remove phosphate groups
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Exercise 1: Alcohol Dehydrogenase (ADH) Reaction Bich 413 section 508 Abstract The Alcohol Dehydrogenase Reaction in Oxidized Nicotinamide Adenine Dinucleotide. The oxidation-reduction of Nicotinamide adenine Dinucleotides (NADH) are very Important reaction in the biological system. When the Oxidized Nicotinamide Adenine Dinucleotide (NAD+) is react with a alcohol‚ catalyze by Alcohol Dehydrogenase (ADH)‚ the result products are NADH‚ H+‚ and aldehyde.In the biological system‚ the
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Chemical Reactions Lab Introduction Four different types of chemical reactions were observed in this lab. Synthesis reactions occur when two different elements or compounds form a more complex compound as shown by equation (1). Single replacement occurs when one element replaces another to form a new compound as shown in equation (2). Double replacement occurs when two different atoms in different compounds trade places with one another to form two new compounds as shown in equation (3).Combustion
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Lab 5: The SN2 Reaction: 1-Bromobutane From K. L. Williamson‚ Macroscale and Microscale Organic Experiments‚ 2nd Ed. 1994‚ Houghton Mifflin‚ Boston. p247; revised 2/22/02 Prelab Exercise: Write a detailed flow sheet/ flow chart for the isolation and purification of 1-bromobutane. Designate how each minor-product is removed from the major product and which layer holds the product in each experimental step performed. [pic] Introduction This experiment utilizes SN2 chemistry
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Title: Surface Area vs. Rate of Reaction Research question: How can different temperatures affect the rate of reaction‚ when the reactant is in powder form? Hypothesis: If the temperature of the water is increased‚ the rate of reaction will also increase as the heat given off to the particles will increase leading to more movement and frequent collisions. Background information: Chemical reactions occur when two or more molecules interact with each other‚ but that can only occur when they
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Step 1: Pb (NO3) 2 (aq) + CaCl2 (aq) PbCl2 (aq) + Ca (NO3) 2 (aq) (double displacement reaction) According to the solubility guidelines lead (II) chloride (PbCl2) is a possible precipitate. This is because even though most chlorides are soluble‚ lead chloride is considered insoluble (p.2‚ Lesson 17). Step 2: PbCl2 ↔ Pb2+ + 2Cl- Q = [Pb2+] [Cl-] 2 Step 3: Ksp = 1.2 x 10-5 (from table 17.1‚ p.5) Step 4: V2 = 20.0 mL (volume of Pb (NO3)2) + 45.0 mL (volume of CaCl2) = 65.0
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