THEORY: The Diels-Alder cycloaddition reaction was discovered by Otto Diels and Kurt Alder and is very useful in the synthesis of polycyclic compounds. The Diels-Alder reaction can be described as: [4+2] cycloaddition- a diene with 4 π electrons + 2π electrons from the dienophile; a pericyclic concerted reaction- meaning the reaction occurs in a single step (no intermediates) and involves a cyclic redistribution of bonding electrons. In order for a Diels-Alder reaction to take place
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The Diels-Alder Reaction of Anthracene with Maleic Anhydride 1 The Diels-Alder Reaction of Anthracene with Maleic Anhydride Microscale Diels-Alder Reaction Leah Monroe March 6‚ 2003 Organic Chemistry Lab II Experiment performed on February 25 and 27‚ 2003 Abstract: This experiment involved a reaction between anthracene and maleic anhydride via a Diels Alder reaction to yield 9‚ 10-dihydroanthracene-9‚10-α‚ β-succinic anhydride. Anthracene was the diene and maleic anhydride was the
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EXPERIMENT OBJECTIVE The aim of this experiment is synthesize hexaphenylbenzene via an aldol condensation reaction‚ followed by a Diels-Alder [4+2] cycloaddtion. This is final step in the multistep synthesis pathway to form hexaphenylbenzene‚ and uses the products of the previous experiments: benzil and diphenylacetylene REACTION DIAGRAM TABLE OF REAGENTS BENZIL DIBENZYL KETONE TRITON B 40wt% IN METHANOL (1.79 M) TRIETHYLENE GLYCOL TETRAPHENYL-CYCLOPENTA-DIENONE DIPHENYL ACETYLENE
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Reminder: These notes are meant to supplement‚ not replace‚ the laboratory manual. A Diels-Alder Reaction History and Application: The 1950 Nobel prize in chemistry was awarded to Otto Paul Hermann Diels and Kurt Alder for their breakthrough work on the discovery and development of [4 + 2] cycloaddition reactions i. This set of reactions are enormously useful in the synthesis of six membered rings in a single stepii. These are used in many pharmaceutical applications. Tamiflu® is a drug which
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Lizz Radican Lab 4 2/24/14 The Diels-Alder Reaction: Results and Problems 1.) Table 1: Mass‚ Percent Yield and Melting Points for Diels-Alder Reaction Products. Product Mass (g) Percent Yield Melting Points (°C) Anhydride 8.87 88.2% 164.4-165.8 Dicarboxylic Acid 3.20 71.9% 176.6-180.1 Unknown 1.66 111% 168.7-176.0 2.) See attached calculations. 3.) Table 2: Anhydride Product IR Data: Functional Group or Bond Peak Location(s) (cm-1) Peak Intensity Symmetric
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cycloaddition reaction‚ also known as Diels-Alder. According to the lab manual‚ this reaction consists of the addition of a diene and a dienophile and that the Diels-Alder reaction builds stereospecific ring compounds with ease (Weldegirma 80). The reaction takes place between the two pi electrons from the dienophile and the 4 pi electrons from the diene; what happens is the bonds react together in order to form new single bonds because they are more stable‚ in terms of energetics (Diels-Alder Reaction). In
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Ronak Parikh U30682934 Experiment 2: Diels-Alder Reaction: Synthesis of cis-Norbornene-5‚6-endo-dicaroboxylic anhydride Introduction: The main goal of this experiment is to perform a Diels-Alder reaction between 2‚3-dimethyl-1‚3-butadiene and maleic anhydride‚ identify the product and hydrolyze to form the dicarboxylic acid. Diels alder reactions are classified as pericyclic reaction‚ which is a reaction which involves a cyclic rearrangement of bonding electrons‚ which means
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Diels-Alder Reaction: Synthesis of cis-Norbornene-5‚ 6-endo-dicarboxylic anhydride Introduction: The Diels-Alder reaction is a [4+2] cycloaddition of a conjugated diene and a dienophile. This type of reaction was named for Otto Diels and Kurt Alder who were the first to investigate this reaction (Weldegirma‚ 2012). The Diels- Alder reaction is one of the most important reactions in all of organic chemistry because of the applicability of it. This reaction can form
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Introduction: The Diels-Alder reaction is one of the most powerful tools used in the preparation of important organic molecules. When two carbon-carbon double bonds are positioned next to one another‚ a conjugated diene is formed. Conjugated dienes undergo a cycloaddition reaction (also called pericyclic addition) with certain double bonds to afford cyclohexenes and related compounds. The reaction of Cyclopentadiene with Maleic anhydride is an example of a Diels-Alder reaction. This reaction forms a six-membered
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Retro – modern design&style Every twenty to thirty years‚ the world of design seems to make a comeback‚ but in a slightly better way. Whether it’s is the world of fashion‚ colours or home decor‚ retro style is an eclectic mix of old styles and new forms‚ or new forms with old materials and finishes. From the psychedelic prints of the seventies to the fifties appeal of oversized light fixtures and bubbly forms. I like retro- modern style because it offers me the opportunity
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